ベンザインの分子内反応を拡張するプラットフォーム分子を活用した新奇反応開発

• 資料種別: 記事
• タイトル: ベンザインの分子内反応を拡張するプラットフォーム分子を活用した新奇反応開発
• 著者標目: 瀧川 紘
• 出版年月日等: 2025-02-01
• 出版年（W3CDTF）: 2025-02-01
• タイトル（掲載誌）: 有合化
• 巻号年月日等（掲載誌）: 83 2
• 掲載巻: 83
• 掲載号: 2
• 掲載ページ: 131-141
• 掲載年月日（W3CDTF）: 2025-02-01
• ISSN（掲載誌）: 00379980
• 出版事項（掲載誌）: The Society of Synthetic Organic Chemistry, Japan
• 本文の言語コード: ja
• 件名標目: benzyne; silicon tether; intramolecular reaction; pericyclic reaction; mechanistic studies
• 対象利用者: 一般
• DOI: 10.5059/yukigoseikyokaishi.83.131
• 関連情報（URI）: https://www.jstage.jst.go.jp/article/yukigoseikyokaishi/83/2/83_131/_pdf
• 参照: Intramolecular Ynamide–Benzyne (3+2) Cycloadditions; https://cir.nii.ac.jp/crid/1050014481143312384; Construction of Condensed Polycyclic Aromatic Frameworks through Intramolecular Cycloaddition Reactions Involving Arynes Bearing an Internal Alkyne Moiety; https://cir.nii.ac.jp/crid/1360002214467534592; The temporary silicon connection in the control of the regiochemistry of 4 + 2 cycloadditions; https://cir.nii.ac.jp/crid/1360011144454279936; Silicon-Tethered Strategies for C–H Functionalization Reactions; https://cir.nii.ac.jp/crid/1360011144609774848; 2-(Chlorodiisopropylsilyl)-6-(trimethylsilyl)phenyl triflate: a modified platform for intramolecular benzyne cycloadditions; https://cir.nii.ac.jp/crid/1360016870451267584; Intramolecular Propargylic Ene Reaction of Benzyne En Route to Highly Functionalized Allenes and Allenamides; https://cir.nii.ac.jp/crid/1360017282463046272; Transition-metal free umpolung carbon–nitrogen versus carbon–chlorine bond formation; https://cir.nii.ac.jp/crid/1360017286458537856; 1.3-Dipolare additionen der azomethin-imine; https://cir.nii.ac.jp/crid/1360017286844564096; Ene Reaction of Arynes with Alkynes; https://cir.nii.ac.jp/crid/1360017290010165888; Aryne Chemistry: Generation Methods and Reactions Incorporating Multiple Arynes; https://cir.nii.ac.jp/crid/1360022497405794304; Nucleophilic Substitution Reaction at the Nitrogen of Arylsulfonamides with Phosphide Anion; https://cir.nii.ac.jp/crid/1360285708190112768; Intramolecular Benzyne–Phenolate [4+2] Cycloadditions; https://cir.nii.ac.jp/crid/1360286989472912000; Ynamides as Three-Atom Components in Cycloadditions: An Unexplored Chemical Reaction Space; https://cir.nii.ac.jp/crid/1360298763918433792; FLUORIDE-INDUCED 1,2-ELIMINATION OF <i>O</i>-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONS; https://cir.nii.ac.jp/crid/1360565169060698624; General and Convenient Approach to Flavan-3-ols: Stereoselective Synthesis of (−)-Gallocatechin; https://cir.nii.ac.jp/crid/1360565169064158208; 2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloaddition; https://cir.nii.ac.jp/crid/1360567183585205504; One-step synthesis of benzo[<i>b</i>]thiophenes by aryne reaction with alkynyl sulfides; https://cir.nii.ac.jp/crid/1360572092625335040; Synthesis and Determination of the Absolute Configuration of Cavicularin by a Symmetrization/Asymmetrization Approach; https://cir.nii.ac.jp/crid/1360574093923516288; Development of Synthetic Phenol from Benzene Halides¹; https://cir.nii.ac.jp/crid/1360574096491095808; Recent progress in transition-metal-free functionalization of allenamides; https://cir.nii.ac.jp/crid/1360580234554990848; An Alternative Method for Generating Arynes from ortho-Silylaryl Triflates: Activation by Cesium Carbonate in the Presence of a Crown Ether; https://cir.nii.ac.jp/crid/1360846645614463616; Allenamides: A Powerful and Versatile Building Block in Organic Synthesis; https://cir.nii.ac.jp/crid/1360855569891293440; Silylmethyl radical cyclization: new stereoselective method for 1,3-diol synthesis from allylic alcohols; https://cir.nii.ac.jp/crid/1360855570025372288; Transition-Metal-Free Electrophilic Amination between Aryl Grignard Reagents and<i>N</i>-Chloroamines; https://cir.nii.ac.jp/crid/1360855571437868160; Recent Advances on Transition-Metal-Catalyzed Allenamides Cyclization; https://cir.nii.ac.jp/crid/1360861709594718336; Metal-free dearomative [5+2]/[2+2] cycloaddition of 1<i>H</i>-indoles with <i>ortho</i>-(trimethylsilyl)aryl triflates; https://cir.nii.ac.jp/crid/1360866925430963456; Synthesis of Functionalized Medium‐Sized <i>trans</i>‐Cycloalkenes by 4π Electrocyclic Ring Opening/Alkylation Sequence; https://cir.nii.ac.jp/crid/1361412889379227392; Novel reactions of benzyne with acetylenic ethers; https://cir.nii.ac.jp/crid/1361418519194644096; An Interesting Benzyne-Mediated Annulation Leading to Benzo[<i>a</i>]pyrene; https://cir.nii.ac.jp/crid/1361699993650977024; Neuer Zugang zu Dehydrobenzol‐Reaktionen; https://cir.nii.ac.jp/crid/1361699996063035776; Intramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and Dienes; https://cir.nii.ac.jp/crid/1361981469967554048; Disposable tethers in synthetic organic chemistry; https://cir.nii.ac.jp/crid/1362262944481270656; Benz-in als Dipolarophil; https://cir.nii.ac.jp/crid/1362262945724483072; A novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular diels-alder reaction of a sllyl acetal triene; https://cir.nii.ac.jp/crid/1362262946194621312; Silicon-Tethered Reactions; https://cir.nii.ac.jp/crid/1362544418844867328; Control of ring junction stereochemistry via radical cyclization; https://cir.nii.ac.jp/crid/1362544420916929408; The Huisgen Reaction: Milestones of the 1,3‐Dipolar Cycloaddition; https://cir.nii.ac.jp/crid/1362544421226294528; Crown ether metal complex fluoride salt as a facile and low hygroscopic fluoride source for nucleophilic fluorination; https://cir.nii.ac.jp/crid/1362825893980069248; Halogen-Magnesium Exchange via Trialkylmagnesates for the Preparation of Aryl- and Alkenylmagnesium Reagents; https://cir.nii.ac.jp/crid/1362825895212874752; Intramolecular Reactions of Temporarily Silicon-Tethered Molecules; https://cir.nii.ac.jp/crid/1362825895997159936; The Emergence of Allenamides in Organic Synthesis; https://cir.nii.ac.jp/crid/1363388844322897280; Total synthesis of pseudopterosin A and E aglycon; https://cir.nii.ac.jp/crid/1363388845774142720; Arylnaphthalene Lignans through Pd‐Catalyzed [2+2+2] Cocyclization of Arynes and Diynes: Total Synthesis of Taiwanins C and E; https://cir.nii.ac.jp/crid/1363388846271384576; Synthesis of 2,3-, 2,5-, and 2,6-disubstituted-benzobarrelenes high temperature bromination II; https://cir.nii.ac.jp/crid/1363951794367346688; Domino Aryne Precursor: Efficient Construction of 2,4-Disubstituted Benzothiazoles; https://cir.nii.ac.jp/crid/1363951794493214336; First intramolecular benzyne diels-alder reaction with an acyclic diene. Unusual effect of diene geometry on the course of the reaction; https://cir.nii.ac.jp/crid/1364233269992510208; 脱芳香化された多環性芳香族ポリケチド天然物の合成戦略; https://cir.nii.ac.jp/crid/1390282763084793856
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• 提供元機関・データベース: Japan Link Center; https://japanlinkcenter.org/top; Crossref; https://www.crossref.org

• 要約等: <p>This paper describes the development of novel “benzyne platform” molecules and their applications in discovering unique intramolecular reactions. T...