Me3SiCl/HMPA accelerated conjugate addition of catalytic copper reagent. Stereoselective synthesis of enol silyl ether of aldehyde

• 資料種別: 記事
• タイトル: Me3SiCl/HMPA accelerated conjugate addition of catalytic copper reagent. Stereoselective synthesis of enol silyl ether of aldehyde
• 著者標目: Yoshiaki Horiguchi; Satoshi Matsuzawa; Eiichi Nakamura; Isao Kuwajima
• 出版年月日等: 1986-01
• 出版年（W3CDTF）: 1986-01
• タイトル（掲載誌）: Tetrahedron Letters
• 巻号年月日等（掲載誌）: 27 34
• 掲載巻: 27
• 掲載号: 34
• 掲載ページ: 4025-4028
• 掲載年月日（W3CDTF）: 1986-01
• ISSN（掲載誌）: 00404039; 09317597
• 出版事項（掲載誌）: Elsevier BV
• 対象利用者: 一般
• DOI: 10.1016/s0040-4039(00)84901-1; 10.1002/chin.198704216
• 作成日（W3CDTF）: 2002-07-25
• 著作権情報: https://www.elsevier.com/tdm/userlicense/1.0/
• 関連情報（URI）: https://api.elsevier.com/content/article/PII:S0040403900849011?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0040403900849011?httpAccept=text/plain
• 参照: Conjugate Addition to Acylketene Acetals Derived from 1,8-Dihydroxynaphthalene and Its Application To Synthesize the Proposed Structure of Spiropreussione A; https://cir.nii.ac.jp/crid/1360004233142626304; New Possibilities in the Michael Reaction by the Use of Tin(II) Enolates; https://cir.nii.ac.jp/crid/1360283694084655104; 1,4‐Addition of Bis(iodozincio)methane to α,β‐Unsaturated Ketones: Chemical and Theoretical/Computational Studies; https://cir.nii.ac.jp/crid/1360285704963823616; Regio- and stereoselective preparation of (Z)-silyl enol ethers by three-component coupling using α,β-unsaturated acylsilanes as core building blocks; https://cir.nii.ac.jp/crid/1360285707504101120; Copper-catalyzed 1,4-Addition Reaction of Grignard Reagent to Enones Using Microflow System; https://cir.nii.ac.jp/crid/1360565169058785024; Synthesis of (<i>R</i>)-(+)-4-Butyl-2,6-cycloheptadienone, a Constituent of Marine Algae; https://cir.nii.ac.jp/crid/1360565169061509632; 1,2-Asymmetric Induction on Conjugate Addition to Chiral γ-Sukstituted-α,β-unsaturated Aldehyde; https://cir.nii.ac.jp/crid/1360565169061609088; Preparation of (+)-Tricyclo[6.2.1.02,7]undec-2(7)-en-3-one and Its Conversion into (+)-<i>epi</i>-<i>β</i>-Santalene; https://cir.nii.ac.jp/crid/1360565169062551680; Synthetic Study of Zoanthamine Alkaloids: The C-ring Model Possessing Three Consecutive Quaternary Carbons; https://cir.nii.ac.jp/crid/1360565169063051648; Activation of Marginally Reactive Boron Enolates by MeLi for the Formation of Enol Phosphates and Synthesis of the Δ⁹-THC Intermediate; https://cir.nii.ac.jp/crid/1360848658060656640; Concise Synthesis of an Antifeedant Sesquiterpene against<i>Locusta migratoria</i>; https://cir.nii.ac.jp/crid/1390282681456774656; Chemistry: A Bridge between Molecular World and Real World; https://cir.nii.ac.jp/crid/1390845713023820800
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• 提供元機関・データベース: Crossref; https://www.crossref.org

• 要約等: Abstract Copper-catalyzed conjugate addition of the Grignard reagents in the presence of Me 3 SiCl and HMPA proceeds in much higher yield than the r...