環状ニッケル化合物を反応中間体とする分子変換反応

• 資料種別: 記事
• タイトル: 環状ニッケル化合物を反応中間体とする分子変換反応
• 著者標目: 生越 専介; https://orcid.org/0000-0003-4188-8555
• 出版年月日等: 2013
• 出版年（W3CDTF）: 2013
• タイトル（掲載誌）: 有合化
• 巻号年月日等（掲載誌）: 71 1
• 掲載巻: 71
• 掲載号: 1
• 掲載ページ: 14-24
• 掲載年月日（W3CDTF）: 2013
• ISSN（掲載誌）: 00379980
• 出版事項（掲載誌）: The Society of Synthetic Organic Chemistry, Japan
• 本文の言語コード: ja
• 件名標目: nickel; oxidative cyclization; oxidative addition; nickelacycle; hetero-nickelacycle; oxa-nickelacycle; aza-nickelacycle; [2+2+2] cycloaddition; [2+2] cycloaddition; [4+2] cycloaddition; [3+2] cycloaddition
• 対象利用者: 一般
• 標準番号（その他）: COI : 1:CAS:528:DC%2BC3sXitFyqurw%3D
• DOI: 10.5059/yukigoseikyokaishi.71.14
• 参照: Nickel‐Catalyzed Synthesis of <i>N</i>‐Aryl‐1,2‐dihydropyridines by [2+2+2] Cycloaddition of Imines with Alkynes through T‐Shaped 14‐Electron Aza‐Nickelacycle Key Intermediates; https://cir.nii.ac.jp/crid/1360002214466226560; Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene; https://cir.nii.ac.jp/crid/1360004233216978944; Nickel(0)-Catalyzed [2 + 2 + 1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to γ-Lactams; https://cir.nii.ac.jp/crid/1360565166612302336; 2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C–C Bond-Forming Reactions; https://cir.nii.ac.jp/crid/1360848658071170816; Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions; https://cir.nii.ac.jp/crid/1360848658525534080; Vol. 90 Commemorative Account : Fascinating Molecules and Reactions : Award Account : The Chemical Society of Japan Award for Creative Work for 2013 : Highly Atom Economical Molecular Transformation via Hetero-Nickelacycle; https://cir.nii.ac.jp/crid/1390282679121081728
• 参照: Nickel-Catalyzed Intermolecular [2 + 2] Cycloaddition of Conjugated Enynes with Alkenes; https://cir.nii.ac.jp/crid/1360002216658501632; Catalytic Addition of Olefinic C–H Bonds to Olefins; https://cir.nii.ac.jp/crid/1360002219109093632; Nickel-catalyzed Reactions between Enone and Two Ethylenes; https://cir.nii.ac.jp/crid/1360002219111232640; Recent Advances in the Synthesis of Pyridines by Transition-Metal-Catalyzed [2+2+2] Cycloaddition; https://cir.nii.ac.jp/crid/1360011144455053696; Formation of an Aza‐nickelacycle by Reaction of an Imine and an Alkyne with Nickel(0): Oxidative Cyclization, Insertion, and Reductive Elimination; https://cir.nii.ac.jp/crid/1360011146614460032; Nickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of α,β-Unsaturated Phenyl Esters with Alkynes; https://cir.nii.ac.jp/crid/1360283691635001600; Nickel-Catalyzed Dehydrogenative [4 + 2] Cycloaddition of 1,3-Dienes with Nitriles; https://cir.nii.ac.jp/crid/1360285708189753600; Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis; https://cir.nii.ac.jp/crid/1360292619259954560; Palladium(0)‐Catalyzed [2σ + 2π] Cycloadditions Methylenecyclopropane to Alkenes; https://cir.nii.ac.jp/crid/1360292619643902848; [3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride; https://cir.nii.ac.jp/crid/1360292620311502336; The Tishchenko Reaction: A Classic and Practical Tool for Ester Synthesis; https://cir.nii.ac.jp/crid/1360565169064295936; Verbesserte Dimerisierung von Methylen-cyclopropan an modifizierten Nickel(0)-Katalysatoren; https://cir.nii.ac.jp/crid/1360574093826007936; Selective Cyclotrimerization of Enones and Alkynes by a Nickel and Aluminum Catalytic System; https://cir.nii.ac.jp/crid/1360574094879736576; Regioselective Cyclic Cotrimerization of α,β-Enones and Alkynes by a Nickel−Aluminum Catalyst System; https://cir.nii.ac.jp/crid/1360574095986294784; Synthesis of Five‐ and Six‐Membered Benzocyclic Ketones through Intramolecular Alkene Hydroacylation Catalyzed by Nickel(0)/N‐Heterocyclic Carbenes; https://cir.nii.ac.jp/crid/1360848654848984320; The fascinating construction of pyridine ring systems by transition metal-catalysed [2 + 2 + 2] cycloaddition reactions; https://cir.nii.ac.jp/crid/1360855568575387776; Dimerization of Cyclopropyl Ketones and Crossed Reactions of Cyclopropyl Ketones with Enones as an Entry to Five-Membered Rings; https://cir.nii.ac.jp/crid/1360855569727506048; α‐Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition Reactions; https://cir.nii.ac.jp/crid/1360855570204340736; Reaction of (η2-arylaldehyde)nickel(0) complexes with Me3SiX (X=OTf, Cl). Application to catalytic reductive homocoupling reaction of arylaldehyde; https://cir.nii.ac.jp/crid/1361137043790593536; Nickel-Catalyzed Direct Conjugate Addition of Simple Alkenes to Enones; https://cir.nii.ac.jp/crid/1361137044702461952; Direct Observation of Oxidative Cyclization of η²-Alkene and η²-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me₃SiOTf; https://cir.nii.ac.jp/crid/1361699994425318784; Reaktionen der Methylencyclopropane, VI ¹⁾ Palladium(0)‐katalysierte [2σ + 2π]‐Cycloadditionen des 1‐Methylen‐2‐vinylcyclopropans; https://cir.nii.ac.jp/crid/1361699994565559552; Cyclodimerization of Methylenecyclopropane on a Ni(0) Catalyst; https://cir.nii.ac.jp/crid/1361699995475710976; Catalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistance; https://cir.nii.ac.jp/crid/1361699996369049984; Reversible Carbon−Carbon Bond Formation between 1,3-Dienes and Aldehyde or Ketone on Nickel(0); https://cir.nii.ac.jp/crid/1361699996393612800; Recent Strategies for the Synthesis of Pyridine Derivatives; https://cir.nii.ac.jp/crid/1361981469588082432; Novel Chemoselectivity and Stereochemical Aspects of Nickel-Catalyzed [2 + 2 + 2] Cycloadditions; https://cir.nii.ac.jp/crid/1362262943806629376; AlMe₃-Promoted Oxidative Cyclization of η²-Alkene and η²-Ketone on Nickel(0). Observation of Intermediate in Methyl Transfer Process; https://cir.nii.ac.jp/crid/1362262944154982400; A Study of the Mixed Tischtschenko Reaction; https://cir.nii.ac.jp/crid/1362262946444712192; Nickel-Catalyzed [2 + 2 + 2] Cycloaddition of Two Enones and an Alkyne; https://cir.nii.ac.jp/crid/1362544419189572992; Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex; https://cir.nii.ac.jp/crid/1362544420384468480; Selective dimerization of aldehydes to esters catalyzed by zirconocene and hafnocene complexes; https://cir.nii.ac.jp/crid/1362544421106614400; Synthesis and Reactivity of Six‐Membered Oxa‐Nickelacycles: A Ring‐Opening Reaction of Cyclopropyl Ketones; https://cir.nii.ac.jp/crid/1362825893913164288; Nickel-Catalyzed Selective Conversion of Two Different Aldehydes to Cross-Coupled Esters; https://cir.nii.ac.jp/crid/1362825895020826240; Construction of Pyridine Rings by Metal-Mediated [2 + 2 + 2] Cycloaddition; https://cir.nii.ac.jp/crid/1362825895154721280; [3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient Alkylidenecyclopropanes; https://cir.nii.ac.jp/crid/1363107368901100288; Transition Metal Catalyzed Alkene and Alkyne Hydroacylation; https://cir.nii.ac.jp/crid/1363107369973030400; Modern Organonickel Chemistry; https://cir.nii.ac.jp/crid/1363107370051455104; Activation of C-H Bonds: Catalytic Reactions; https://cir.nii.ac.jp/crid/1363107370352605696; Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine; https://cir.nii.ac.jp/crid/1363670318351484800; Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde; https://cir.nii.ac.jp/crid/1363670319395578240; Nickel(0)-catalyzed hydroacylation of alkynes with aldehydes to .alpha.,.beta.-enones; https://cir.nii.ac.jp/crid/1363670320694625280; [2+2+2] Cycloaddition Reactions Catalyzed by Transition Metal Complexes; https://cir.nii.ac.jp/crid/1363951793342817024; Elaboration of Conjugated Alkenes Initiated by Insertion into a Vinylic C-H Bond; https://cir.nii.ac.jp/crid/1363951793615255424; Trimerisation von Methylencyclopropan an triorganophosphan‐modifizierten Nickel (o)‐Katalysatoren; https://cir.nii.ac.jp/crid/1363951794884589824; Nickel(0)-Catalyzed Dimerization of Ethyl Cyclopropylideneacetates; https://cir.nii.ac.jp/crid/1364233268851395584; Formation of Nickeladihydropyran by Oxidative Addition of Cyclopropyl Ketone. Key Intermediate in Nickel-Catalyzed Cycloaddition; https://cir.nii.ac.jp/crid/1364233270055990912; 触媒反応における鍵中間体としてのヘテロニッケラサイクルの研究; https://cir.nii.ac.jp/crid/1390001205313187840; ローダサイクル中間体を経由する新規環化反応とその応用; https://cir.nii.ac.jp/crid/1390282680289726976
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• 提供元機関・データベース: Japan Link Center; https://japanlinkcenter.org/top; Crossref; https://www.crossref.org; CiNii Articles
• NII論文ID: 10031148196

• 要約等: Nickelacycles have been known as a key reaction intermediate. The β-hydrogen transfer reactions from nickelacycles allow us to synthesize acyclic orga...