記事
ベンザインの分子内反応を拡張するプラットフォーム分子を活用した新奇反応開発
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ベンザインの分子内反応を拡張するプラットフォーム分子を活用した新奇反応開発
- Material type
- 記事
- Author
- 瀧川 紘
- Publisher
- The Society of Synthetic Organic Chemistry, Japan
- Publication date
- 2025-02-01
- Material Format
- Digital
- Journal name
- 有合化 83 2
- Publication Page
- p.131-141
Detailed bibliographic record
Summary, etc.：
- <p>This paper describes the development of novel “benzyne platform” molecules and their applications in discovering unique intramolecular reactions. T...
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Digital
- Material Type
- 記事
- Author Heading
- Publication Date
- 2025-02-01
- Publication Date (W3CDTF)
- 2025-02-01
- Periodical title
- 有合化
- No. or year of volume/issue
- 83 2
- Volume
- 83
- Issue
- 2
- Pages
- 131-141
- Publication date of volume/issue (W3CDTF)
- 2025-02-01
- ISSN (Periodical Title)
- 00379980
- Publication (Periodical Title)
- The Society of Synthetic Organic Chemistry, Japan
- Text Language Code
- ja
- Target Audience
- 一般
- DOI
- 10.5059/yukigoseikyokaishi.83.131
- Related Material (URI)
- References
- Intramolecular Ynamide–Benzyne (3+2) CycloadditionsConstruction of Condensed Polycyclic Aromatic Frameworks through Intramolecular Cycloaddition Reactions Involving Arynes Bearing an Internal Alkyne MoietyThe temporary silicon connection in the control of the regiochemistry of 4 + 2 cycloadditionsSilicon-Tethered Strategies for C–H Functionalization Reactions2-(Chlorodiisopropylsilyl)-6-(trimethylsilyl)phenyl triflate: a modified platform for intramolecular benzyne cycloadditionsIntramolecular Propargylic Ene Reaction of Benzyne En Route to Highly Functionalized Allenes and AllenamidesTransition-metal free umpolung carbon–nitrogen versus carbon–chlorine bond formation1.3-Dipolare additionen der azomethin-imineEne Reaction of Arynes with AlkynesAryne Chemistry: Generation Methods and Reactions Incorporating Multiple ArynesNucleophilic Substitution Reaction at the Nitrogen of Arylsulfonamides with Phosphide AnionIntramolecular Benzyne–Phenolate [4+2] CycloadditionsYnamides as Three-Atom Components in Cycloadditions: An Unexplored Chemical Reaction SpaceFLUORIDE-INDUCED 1,2-ELIMINATION OF <i>O</i>-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONSGeneral and Convenient Approach to Flavan-3-ols: Stereoselective Synthesis of (−)-Gallocatechin2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloadditionOne-step synthesis of benzo[<i>b</i>]thiophenes by aryne reaction with alkynyl sulfidesSynthesis and Determination of the Absolute Configuration of Cavicularin by a Symmetrization/Asymmetrization ApproachDevelopment of Synthetic Phenol from Benzene Halides<sup>1</sup>Recent progress in transition-metal-free functionalization of allenamidesAn Alternative Method for Generating Arynes from ortho-Silylaryl Triflates: Activation by Cesium Carbonate in the Presence of a Crown EtherAllenamides: A Powerful and Versatile Building Block in Organic SynthesisSilylmethyl radical cyclization: new stereoselective method for 1,3-diol synthesis from allylic alcoholsTransition-Metal-Free Electrophilic Amination between Aryl Grignard Reagents and<i>N</i>-ChloroaminesRecent Advances on Transition-Metal-Catalyzed Allenamides CyclizationMetal-free dearomative [5+2]/[2+2] cycloaddition of 1<i>H</i>-indoles with <i>ortho</i>-(trimethylsilyl)aryl triflatesSynthesis of Functionalized Medium‐Sized <i>trans</i>‐Cycloalkenes by 4π Electrocyclic Ring Opening/Alkylation SequenceNovel reactions of benzyne with acetylenic ethersAn Interesting Benzyne-Mediated Annulation Leading to Benzo[<i>a</i>]pyreneNeuer Zugang zu Dehydrobenzol‐ReaktionenIntramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and DienesDisposable tethers in synthetic organic chemistryBenz-in als DipolarophilA novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular diels-alder reaction of a sllyl acetal trieneSilicon-Tethered ReactionsControl of ring junction stereochemistry via radical cyclizationThe Huisgen Reaction: Milestones of the 1,3‐Dipolar CycloadditionCrown ether metal complex fluoride salt as a facile and low hygroscopic fluoride source for nucleophilic fluorinationHalogen-Magnesium Exchange via Trialkylmagnesates for the Preparation of Aryl- and Alkenylmagnesium ReagentsIntramolecular Reactions of Temporarily Silicon-Tethered MoleculesThe Emergence of Allenamides in Organic SynthesisTotal synthesis of pseudopterosin A and E aglyconArylnaphthalene Lignans through Pd‐Catalyzed [2+2+2] Cocyclization of Arynes and Diynes: Total Synthesis of Taiwanins C and ESynthesis of 2,3-, 2,5-, and 2,6-disubstituted-benzobarrelenes high temperature bromination IIDomino Aryne Precursor: Efficient Construction of 2,4-Disubstituted BenzothiazolesFirst intramolecular benzyne diels-alder reaction with an acyclic diene. Unusual effect of diene geometry on the course of the reaction脱芳香化された多環性芳香族ポリケチド天然物の合成戦略
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