Pb2+イオンがCsCl結晶に拡散していく課程の分光学的その場観測

Material type: 文書・図像類

Author: 松永, 敏宏ほか

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Publication date: 2001-03

Material Format: Digital

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Note (General)：: CuCl crystals were doped with Pb2+ ions by thermal treatment of PbCl2-deposited CsCl crystals. At the early stage of the heat treatment, the Pb2+ ion...

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Material Type: 文書・図像類
Title: Pb2+イオンがCsCl結晶に拡散していく課程の分光学的その場観測
Author/Editor: 松永, 敏宏
斎藤, 忠昭
近藤, 新一
Author Heading: 松永, 敏宏
斎藤, 忠昭
近藤, 新一
Publication Date: 2001-03
Publication Date (W3CDTF): 2001-03
Alternative Title: In situ optical absorption and reflection spectroscopy of doping CsCl crystal with Pb2+ ions
Periodical title: 遠赤外領域開発研究
No. or year of volume/issue: 2
Volume: 2
Pages: 139-148
Text Language Code: jpn
Target Audience: 一般
Note (General): CuCl crystals were doped with Pb2+ ions by thermal treatment of PbCl2-deposited CsCl crystals. At the early stage of the heat treatment, the Pb2+ ions were densely dispersed near the surface of the CsCl crystals, showing impurity-like optical absorption due to 6s to 6p transitions despite the very high concentration (~10 mol %) of the Pb2+ ions. In the case of heavy annealing at a high temperature (673 K) followed by a rapid cooling to room temperature, the Pb2+ ions were uniformly dispersed throughout the CsCl crystals, exhibiting the absorption spectrum due to isolated Pb2+ -ion centers.
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ