Rapid Alternating Polarity as a Unique Tool for Synthetic Electrochemistry (Special Issue in English)
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- 資料種別
- 記事
- 著者・編者
- Yu KawamataPhil S. Baran
- シリーズタイトル
- タイトル（掲載誌）
- 有機合成化学協会誌 = Journal of synthetic organic chemistry, Japan
- 巻号年月日等（掲載誌）
- 81(11)=964:2023.11
- 掲載巻
- 81
- 掲載号
- 11
- 掲載通号
- 964
- 掲載ページ
- 1020-1027
- 掲載年月日（W3CDTF）
- 2023-11
- ISSN（掲載誌）
- 0037-9980
- ISSN-L（掲載誌）
- 0037-9980
- 出版事項（掲載誌）
- 東京 : 有機合成化学協会
- 出版地（国名コード）
- JP
- 本文の言語コード
- eng
- NDLC
- 対象利用者
- 一般
- 所蔵機関
- 国立国会図書館
- 請求記号
- Z17-256
- 連携機関・データベース
- 国立国会図書館 : 国立国会図書館雑誌記事索引
- 書誌ID（NDLBibID）
- 033183688
- 整理区分コード
- 632
- 要約等
- <p>Electrosynthesis, driven by renewable energy, is a powerful method for accessing useful chemical reactivity in a sustainable fashion. Typically, electrochemical reactions have been carried out using direct current (DC), where electrons flow in a single direction. In contrast, utilization of alternating current (AC) has been largely unexplored in synthetic electrochemistry despite its wide applications in our daily life. This could stem from a historical perception regarding the lack of unique reactivity/selectivity that would result from using such a waveform, as well as the absence of readily available instrumentation to remove the engineering barrier for mass adoption. A breakthrough in this area is the introduction of rapid alternating polarity (rAP), which alternates the polarity of an electrode in the millisecond timescale. This mode of current delivery, now implemented in the widely employed potentiostat, ElectraSyn2.0, enables access to unique reactivity and selectivity in organic synthesis that are challenging or currently impossible to achieve by any known method (chemical or electrochemical). The remarkable chemoselectivity and simplicity of rAP open new vistas in modern synthetic electrochemistry.</p>
- DOI
- 10.5059/yukigoseikyokaishi.81.1020
- オンライン閲覧公開範囲
- インターネット公開
- 連携機関・データベース
- 科学技術振興機構 : J-STAGE
- 要約等
- <p>Electrosynthesis, driven by renewable energy, is a powerful method for accessing useful chemical reactivity in a sustainable fashion. Typically, electrochemical reactions have been carried out using direct current (DC), where electrons flow in a single direction. In contrast, utilization of alternating current (AC) has been largely unexplored in synthetic electrochemistry despite its wide applications in our daily life. This could stem from a historical perception regarding the lack of unique reactivity/selectivity that would result from using such a waveform, as well as the absence of readily available instrumentation to remove the engineering barrier for mass adoption. A breakthrough in this area is the introduction of rapid alternating polarity (rAP), which alternates the polarity of an electrode in the millisecond timescale. This mode of current delivery, now implemented in the widely employed potentiostat, ElectraSyn2.0, enables access to unique reactivity and selectivity in organic synthesis that are challenging or currently impossible to achieve by any known method (chemical or electrochemical). The remarkable chemoselectivity and simplicity of rAP open new vistas in modern synthetic electrochemistry.</p>
- DOI
- 10.5059/yukigoseikyokaishi.81.1020
- 関連情報（URI）
- 参照
- Scalable Electrochemical Decarboxylative Olefination Driven by Alternating PolarityOvercoming the limitations of Kolbe coupling with waveform-controlled electrosynthesisApplications of Alternating Current/Alternating Potential Electrolysis in Organic SynthesisChemoselective (Hetero)Arene Electroreduction Enabled by Rapid Alternating PolarityCatalyst-controlled functionalization of carboxylic acids by electrooxidation of self-assembled carboxyl monolayersAlternating current electrolysis: A photoredox catalysis mimic and beyondScalable Birch reduction with lithium and ethylenediamine in tetrahydrofuranChemoselective Electrosynthesis Using Rapid Alternating PolarityPulse check: Potential opportunities in pulsed electrochemical CO2 reductionAlternating current electrolysis for organic synthesisClosed-loop recycling of polyethylene-like materialsElectrosynthesis Using Carboxylic Acid Derivatives: New Tricks for Old Reactions(Non-)Kolbe electrolysis in biomass valorization – a discussion of potential applicationsBasic Strategies and Types of Applications in Organic ElectrochemistryHindered dialkyl ether synthesis with electrogenerated carbocationsCatalytic Approaches to Monomers for Polymers Based on RenewablesScalable and safe synthetic organic electroreduction inspired by Li-ion battery chemistryThermoplastic polyacetals: chemistry from the past for a sustainable future?Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a RenaissanceTotal Synthesis and Stereochemical Assignment of ActinoranoneLong-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional PolycondensatesInfluence of anodic pulses and periodic current reversion on electrodepositsOrganic ChemistryKolbe Carbon−Carbon Coupling Electrosynthesis Using Solid-Supported BasesChemical Routes for the Transformation of Biomass into ChemicalsAmmonia Free Partial Reduction of Aromatic Compounds Using Lithium Di-<i>tert</i>-butylbiphenyl (LiDBB)A detailed investigation of the preparation of 2,7-diaminosuberic acid and 2,5-diaminoadipic acid derivatives using Kolbe electrolysisElectroorganic Synthesis. 65. Anodic Homocoupling of Carboxylic Acids Derived from Fatty Acids.The Birch reduction in organic synthesisOptimal time-varying potential controlThe<scp>B</scp>irch Reduction of Aromatic CompoundsSelectivity Changes in Electrochemical Reaction Sequences by Modulated Potential ControlElectrosynthesis of Propylene Oxide with Alternating CurrentRecent synthetic applications of the Kolbe electrolysisThe birch reduction of thiophine-2-carboxylic acidTHE ELECTROLYSIS OF SOME ORGANIC COMPOUNDS WITH ALTERNATING CURRENT
- 連携機関・データベース
- 国立情報学研究所 : CiNii Research
- 提供元機関・データベース
- Japan Link Center雑誌記事索引データベースCrossref
- 書誌ID（NDLBibID）
- 033183688