Calibration Method for the Gas-Chromatographic Retention Time of Polychlorinated Biphenyl Congeners

• 資料種別: 記事
• タイトル: Calibration Method for the Gas-Chromatographic Retention Time of Polychlorinated Biphenyl Congeners
• 著者・編者: Hiroshi Kato; Yoshihisa Ueda; Munetaka Nakata
• 著者標目: Hiroshi Kato; Yoshihisa Ueda; Munetaka Nakata
• タイトル（掲載誌）: Analytical Sciences
• 巻号年月日等（掲載誌）: 16(7) 2000.07
• 掲載巻: 16
• 掲載号: 7
• 掲載ページ: 693～699
• 掲載年月日（W3CDTF）: 2000-07
• ISSN（掲載誌）: 0910-6340
• ISSN-L（掲載誌）: 0910-6340
• 出版事項（掲載誌）: Tokyo : Japan Society for Analytical Chemistry
• 出版地（国名コード）: JP
• 本文の言語コード: eng
• NDLC: ZP4
• 対象利用者: 一般
• 所蔵機関: 国立国会図書館
• 請求記号: Z54-F482
• 連携機関・データベース: 国立国会図書館 : 国立国会図書館雑誌記事索引; https://ndlsearch.ndl.go.jp
• 書誌ID（NDLBibID）: 5472829; http://id.ndl.go.jp/bib/5472829
• 整理区分コード: 632

• 要約等: A calibration method for the gas-chromatographic (GC) retention time of polychlorinated biphenyl (PCB) congeners is presented. This method calculates retention time of all PCB congeners in the GC system of an analytical laboratory from one reported in the literature with a commercial PCB mixture and some pure congener standards. Two corrections were implemented to compensate for any retention differences arising from the GC condition changes, such as the column dimensions, temperature programs and flow rates. One is an instrument function correction that compensates for common congener behavior. The other is a selectivity correction that compensates for individual congener behavior. For a selectivity correction, new descriptors of a quantitative structure-retention relationship (QSRR) were developed. The method was applied to several stationary phases to evaluate its ability and precision. The standard errors of the calculated retention times were in most cases within a chromatographic peak width.
• DOI: 10.2116/analsci.16.693
• オンライン閲覧公開範囲: インターネット公開
• 連携機関・データベース: 科学技術振興機構 : J-STAGE; http://www.jstage.jst.go.jp

• 要約等: A calibration method for the gas-chromatographic (GC) retention time of polychlorinated biphenyl (PCB) congeners is presented. This method calculates retention time of all PCB congeners in the GC system of an analytical laboratory from one reported in the literature with a commercial PCB mixture and some pure congener standards. Two corrections were implemented to compensate for any retention differences arising from the GC condition changes, such as the column dimensions, temperature programs and flow rates. One is an instrument function correction that compensates for common congener behavior. The other is a selectivity correction that compensates for individual congener behavior. For a selectivity correction, new descriptors of a quantitative structure-retention relationship (QSRR) were developed. The method was applied to several stationary phases to evaluate its ability and precision. The standard errors of the calculated retention times were in most cases within a chromatographic peak width.
• DOI: 10.2116/analsci.16.693; https://doi.org/10.2116/analsci.16.693
• オンライン閲覧公開範囲: インターネット公開
• 関連情報（URI）: http://id.ndl.go.jp/bib/5472829; https://ndlsearch.ndl.go.jp/books/R000000004-I5472829; https://link.springer.com/content/pdf/10.2116/analsci.16.693.pdf; https://link.springer.com/article/10.2116/analsci.16.693/fulltext.html; http://www.jstage.jst.go.jp/article/analsci/16/7/16_7_693/_pdf
• 参照: Influence of the stationary gas chromatographic phase on the elution order of 2,4,5-substituted polychlorinated biphenyls; https://cir.nii.ac.jp/crid/1360011144570985856; Complete PCB congener distributions for 17 aroclor mixtures determined by 3 HRGC systems optimized for comprehensive, quantitative, congener‐specific analysis; https://cir.nii.ac.jp/crid/1360011145684408576; Gas chromatographic retention index system for polychlorinated biphenyls: possibilities and limitations; https://cir.nii.ac.jp/crid/1360016869976028032; Retention index system for identification of polychlorinated biphenyl congeners in gas chromatographic analysis; https://cir.nii.ac.jp/crid/1360574093538021632; Heuristic evolving latent projections: resolving two-way multicomponent data. 1. Selectivity, latent-projective graph, datascope, local rank, and unique resolution; https://cir.nii.ac.jp/crid/1360574095671196928; Nonparametric Regression and Generalized Linear Models; https://cir.nii.ac.jp/crid/1360855569774616192; A collaborative study of 209 PCB congeners and 6 Aroclors on 20 different HRGC columns 1. Retention and coelution database; https://cir.nii.ac.jp/crid/1361981471041923328; Ortho-substituent correlated retention of polychlorinated biphenyls on a 50% n-octyl-methylpolysiloxane stationary phase by HRGC/MSD; https://cir.nii.ac.jp/crid/1362262943946829312; Determination of retention indices of polychlorobiphenyls by using other compounds detectable by electrondashcapture detection or selected polychlorobiphenyls as the reference series; https://cir.nii.ac.jp/crid/1362262944660567680; A generalization of the retention index system including linear temperature programmed gas—liquid partition chromatography; https://cir.nii.ac.jp/crid/1362262946387141376; QUANTITATIVE STRUCTURE-RETENTION RELATIONSHIPS; https://cir.nii.ac.jp/crid/1363388844305381632; Peer Reviewed: Congener-Specific PCB Analysis; https://cir.nii.ac.jp/crid/1363388845261987328; Principal component analysis; https://cir.nii.ac.jp/crid/1363670319352108544; Identification of PCB Congeners by Gas Chromatography Electron Capture Detection Employing a Quantitative Structure-Retention Model; https://cir.nii.ac.jp/crid/1363670320314986880; HRGC separation of PCB congeners; https://cir.nii.ac.jp/crid/1363951793630363776; Comprehensive, quantitative, congener-specific analyses of eight aroclors and complete PCB congener assignments on DB-1 capillary GC columns; https://cir.nii.ac.jp/crid/1364233270641260672; A collaborative study of 209 PCB congeners and 6 Aroclors on 20 different HRGC columns 2. Semi-quantitative Aroclor congener distributions; https://cir.nii.ac.jp/crid/1364233270818957056; 各種クリーンアップ法とＨＲＧＣ／ＨＲＭＳを用いたポリ塩化ビフェニル（ＰＣＢｓ）の全異性体詳細分析方法; https://cir.nii.ac.jp/crid/1390001204369579648
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• 提供元機関・データベース: Japan Link Center; https://japanlinkcenter.org/top; 雑誌記事索引データベース; https://ndlsearch.ndl.go.jp; Crossref; https://www.crossref.org; CiNii Articles
• 書誌ID（NDLBibID）: 5472829; http://id.ndl.go.jp/bib/5472829
• NII論文ID: 130004440287; 10005719971