ソープフリー乳化重合による単分散ポリマー粒子の合成(総説特集 ポリマー粒子の最前線)

• 資料種別: 記事
• タイトル: ソープフリー乳化重合による単分散ポリマー粒子の合成
• 著者・編者: 今野 幹男
• シリーズタイトル: 総説特集 ポリマー粒子の最前線
• 著者標目: 今野 幹男
• タイトル（掲載誌）: 日本ゴム協会誌 = Journal of the Society of Rubber Science and Technology, Japan
• 巻号年月日等（掲載誌）: 79(2) 2006.2
• 掲載巻: 79
• 掲載号: 2
• 掲載ページ: 61～66
• 掲載年月日（W3CDTF）: 2006-02
• ISSN（掲載誌）: 0029-022X
• ISSN-L（掲載誌）: 0029-022X
• 出版事項（掲載誌）: 東京 : 日本ゴム協会
• 出版地（国名コード）: JP
• 本文の言語コード: jpn
• 件名標目: Soap-free emulsion polymerization; Monodisperse particle; Amphoteric initiator; Monomer addition method; Composite particle
• NDLC: ZP17
• 対象利用者: 一般
• 所蔵機関: 国立国会図書館
• 請求記号: Z17-125
• 連携機関・データベース: 国立国会図書館 : 国立国会図書館雑誌記事索引; https://ndlsearch.ndl.go.jp
• 書誌ID（NDLBibID）: 7830516; http://id.ndl.go.jp/bib/7830516
• 整理区分コード: 632

• 要約等: Current research on soap-free emulsion polymerization is described together with fundamental aspects concerning the mechanism of this polymerization. Conventional methods of soap-free emulsion polymerization were only applicable to the synthesis of monodisperse submicron-sized polymer particles. Previous work, however, pointed out that resultant particle size distributions are strongly dependent on particle coagulation that can be controlled by electrostatic interaction between particles. This basic concept for the particle formation has led to development of a new type of soap-free emulsion polymerization that employs an amphoteric initiator in combination with pH control. This method has enabled the production of highly monodisperse polystyrene particles up to 3μm in a single stage polymerization. Larger particles can be produced with a simple method of monomer addition to polymerization system after the formation of particles. The soap-free emulsion polymerization is also applicable to the polymerization of methyl methacrylate. Currently, soap-free polymerization methods are widely applied to the synthesis of monodisperse composite particles. The examples given are magnetic polymer latex, silica/polystyrene core-shell particles, bell-shaped hollow core-shell particles and multilayered gold/silica/polystyrene core-shell particles.
• DOI: 10.2324/gomu.79.61
• オンライン閲覧公開範囲: インターネット公開
• 連携機関・データベース: 科学技術振興機構 : J-STAGE; http://www.jstage.jst.go.jp

• 要約等: Current research on soap-free emulsion polymerization is described together with fundamental aspects concerning the mechanism of this polymerization. Conventional methods of soap-free emulsion polymerization were only applicable to the synthesis of monodisperse submicron-sized polymer particles. Previous work, however, pointed out that resultant particle size distributions are strongly dependent on particle coagulation that can be controlled by electrostatic interaction between particles. This basic concept for the particle formation has led to development of a new type of soap-free emulsion polymerization that employs an amphoteric initiator in combination with pH control. This method has enabled the production of highly monodisperse polystyrene particles up to 3μm in a single stage polymerization. Larger particles can be produced with a simple method of monomer addition to polymerization system after the formation of particles. The soap-free emulsion polymerization is also applicable to the polymerization of methyl methacrylate. Currently, soap-free polymerization methods are widely applied to the synthesis of monodisperse composite particles. The examples given are magnetic polymer latex, silica/polystyrene core-shell particles, bell-shaped hollow core-shell particles and multilayered gold/silica/polystyrene core-shell particles.
• DOI: 10.2324/gomu.79.61; https://doi.org/10.2324/gomu.79.61
• 関連情報（URI）: http://id.ndl.go.jp/bib/7830516; https://ndlsearch.ndl.go.jp/books/R000000004-I7830516
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• 提供元機関・データベース: Japan Link Center; https://japanlinkcenter.org/top; 雑誌記事索引データベース; https://ndlsearch.ndl.go.jp; Crossref; https://www.crossref.org; CiNii Articles
• 書誌ID（NDLBibID）: 7830516; http://id.ndl.go.jp/bib/7830516
• NII論文ID: 10016734643