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非共有結合性相互作用を活用する位置選択的な炭素-水素結合変換反応の開発
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非共有結合性相互作用を活用する位置選択的な炭素-水素結合変換反応の開発
- 資料種別
- 記事
- 著者
- 國信 洋一郎
- 出版者
- The Society of Synthetic Organic Chemistry, Japan
- 出版年
- 2024-10-01
- 資料形態
- デジタル
- 掲載誌名
- 有合化 82 10
- 掲載ページ
- p.954-964
資料詳細
要約等：
- <p>The control of site-selectivity is important to obtain the desired products efficiently in synthetic organic chemistry. Because there are many C-H ...
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デジタル
- 資料種別
- 記事
- 著者標目
- 出版年月日等
- 2024-10-01
- 出版年（W3CDTF）
- 2024-10-01
- タイトル（掲載誌）
- 有合化
- 巻号年月日等（掲載誌）
- 82 10
- 掲載巻
- 82
- 掲載号
- 10
- 掲載ページ
- 954-964
- 掲載年月日（W3CDTF）
- 2024-10-01
- ISSN（掲載誌）
- 00379980
- 出版事項（掲載誌）
- The Society of Synthetic Organic Chemistry, Japan
- 本文の言語コード
- ja
- 件名標目
- 対象利用者
- 一般
- DOI
- 10.5059/yukigoseikyokaishi.82.954
- 参照
- Benzylic C(sp<sup>3</sup>)H Perfluoroalkylation of Six‐Membered Heteroaromatic Compounds2-Position-Selective C–H Perfluoroalkylation of Quinoline Derivatives4-Position-Selective C–H Perfluoroalkylation and Perfluoroarylation of Six-Membered Heteroaromatic CompoundsA meta-selective C–H borylation directed by a secondary interaction between ligand and substrateRegioselective trifluoromethylation of N-heteroaromatic compounds using trifluoromethyldifluoroborane activatorIron-Catalyzed <i>ortho</i>-Selective C–H Borylation of 2-Phenylpyridines and Their AnalogsHydrogen-Bond-Controlled Formal <i>Meta</i>-Selective C–H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds5-Position-selective C–H trifluoromethylation of 8-aminoquinoline derivatives2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compoundsmeta-Selective C–H Borylation of Benzamides and Pyridines by an Iridium–Lewis Acid Bifunctional CatalystConformation-induced remote meta-C–H activation of aminesRegioselective C–H Trifluoromethylation of Aromatic Compounds by Inclusion in CyclodextrinsIr-catalyzed proximal and distal C–H borylation of arenesAchieving Site-Selectivity for C–H Activation Processes Based on Distance and Geometry: A Carpenter’s ApproachToolbox for Distal C–H Bond Functionalizations in Organic Molecules3-Position-Selective C–H Trifluoromethylation of Pyridine Rings Based on Nucleophilic ActivationNon‐Covalent Interaction‐Controlled Site‐Selective C−H TransformationsComputationally designed ligands enable tunable borylation of remote C–H bonds in arenesCharge-controlled Pd catalysis enables the meta-C–H activation and olefination of arenesDecatungstate-Catalyzed C(sp<sup>3</sup>)–H Alkylation of a Val Residue Proximal to the N-Terminus Controlled by an Electrostatic InteractionSupramolecular catalysis: the role of H-bonding interactions in substrate orientation and activationDiversification of Aryl Sulfonyl Compounds through Ligand‐Controlled<i>meta</i>‐ and<i>para</i>‐C−H BorylationIridium‐Catalyzed <i>ortho</i>‐Selective Borylation of Aromatic Amides Enabled by 5‐Trifluoromethylated Bipyridine LigandsDistal meta-alkenylation of formal amines enabled by catalytic use of hydrogen-bonding anionic ligandsStrategies That Utilize Ion Pairing Interactions to Exert Selectivity Control in the Functionalization of C–H BondsInside front coverCatalyst-enabled Site-selectivity in the Iridium-catalyzed C–H Borylation of ArenesIridium-Catalyzed <i>ortho</i>-C–H Borylation of Thioanisole Derivatives Using Bipyridine-Type LigandLewis Acid–Base Interaction‐Controlled <i>ortho</i>‐Selective C−H Borylation of Aryl SulfidesArene diversification through distal C(sp <sup>2</sup> )−H functionalizationUrea‐Substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated Rh<sup>III</sup>‐Catalyzed <i>ortho</i>‐C−H Olefination of Benzoic Acid DerivativesEnantioselective Intermolecular C–H Amination Directed by a Chiral CationTransition Metal Catalysis Controlled by Hydrogen Bonding in the Second Coordination SpherePalladium‐Catalyzed <i>ortho</i>‐Selective CH Borylation of 2‐Phenylpyridine and Its Derivatives at Room TemperatureRecent progress of transition metal-catalysed regioselective C–H transformations based on noncovalent interactionsNoncovalent Interactions in Ir-Catalyzed C–H Activation: L-Shaped Ligand for Para-Selective Borylation of Aromatic EstersRecent Developments in Remote <i>Meta</i>‐C−H Bond FunctionalizationsPalladium-Catalyzed <i>meta</i>-Selective C–H Functionalization by Noncovalent H-Bonding InteractionTransition metal–catalyzed remote C─H borylation: An emerging synthetic toolWeak bonding strategies for achieving regio- and site-selective transformationsExtended sulfonated bipyridine ligands targeting the para-selective borylation of arenesFast and Selective β-C–H Borylation of N-Heterocycles with a Supramolecular Iridium Catalyst: Circumventing Deactivation Pathways and Mechanistic InsightsMolecular editing of aza-arene C–H bonds by distance, geometry and chiralityTheoretical Design of a Catalyst with Both High Activity and Selectivity in C–H BorylationUnderstanding the Regioselectivity of Ion-Pair-Assisted Meta-Selective C(sp<sup>2</sup>)–H Activation in Conformationally Flexible Arylammonium SaltsBifunctional NHC-Promoted C2-Alkylation of Pyridine via Ni–Al Bimetallic-Catalyzed Hydroarylation of Unactivated AlkenesSite-Selective C–H Functionalization of Arenes Enabled by Noncovalent InteractionsIridium-Catalyzed <i>ortho</i>-Selective C–H Silylation of Aromatic Compounds Directed toward the Synthesis of π-Conjugated Molecules with Lewis Acid–Base InteractionStrategic evolution in transition metal-catalyzed directed C–H bond activation and future directionsInnate C-H trifluoromethylation of heterocyclesNew horizons for catalysis disclosed by supramolecular chemistryA directive Ni catalyst overrides conventional site selectivity in pyridine C–H alkenylationMeta Selective C–H Borylation of Sterically Biased and Unbiased Substrates Directed by Electrostatic InteractionMetal-catalysed C–H bond activation and borylationEnzyme‐like Supramolecular Iridium Catalysis Enabling C−H Bond Borylation of Pyridines with <i>meta</i>‐SelectivityRemarkably Selective Iridium Catalysts for the Elaboration of Aromatic C-H BondsDirected Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium SystemActivation of remote meta-C–H bonds assisted by an end-on templateConcept of Ir-catalyzed C H bond activation/borylation by noncovalent interaction<i>meta</i>‐Selective C−H Borylation of Benzylamine‐, Phenethylamine‐, and Phenylpropylamine‐Derived Amides Enabled by a Single Anionic LigandHarnessing non-covalent interactions to exert control over regioselectivity and site-selectivity in catalytic reactionsPractical and innate carbon–hydrogen functionalization of heterocyclesHydrogen Bond Directed <i>ortho</i>‐Selective C−H Borylation of Secondary Aromatic AmidesPd(II)-Catalyzed <i>ortho</i>-Trifluoromethylation of Arenes Using TFA as a PromoterRemote site-selective C–H activation directed by a catalytic bifunctional templateIon-Pair-Directed Borylation of Aromatic Phosphonium SaltsAmide Effects in C−H Activation: Noncovalent Interactions with L‐Shaped Ligand for <i>meta</i> Borylation of Aromatic AmidesEnantioselective remote C–H activation directed by a chiral cationIon Pair-Directed Regiocontrol in Transition-Metal Catalysis: A Meta-Selective C–H Borylation of Aromatic Quaternary Ammonium SaltsIon Pair-Directed C–H Activation on Flexible Ammonium Salts: <i>meta</i>-Selective Borylation of Quaternized Phenethylamines and PhenylpropylaminesRuthenium-Catalyzed Meta Sulfonation of 2-PhenylpyridinesPalladium‐Catalyzed CH Fluorosilylation of 2‐Phenylpyridines: Synthesis of Silafluorene EquivalentsMild Iridium-Catalyzed Borylation of Arenes. High Turnover Numbers, Room Temperature Reactions, and Isolation of a Potential IntermediateRecent Developments in Enantioselective Transition Metal Catalysis Featuring Attractive Noncovalent Interactions between Ligand and SubstrateAccess to the <i>meta</i> position of arenes through transition metal catalysed C–H bond functionalisation: a focus on metals other than palladium<i>meta</i>‐ and <i>para</i>‐Selective C−H Functionalization using Transient Mediators and Noncovalent TemplatesDevelopment of Novel C–H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules基質認識部位をもつ遷移金属触媒の創製と位置選択的，基質特異的な炭素-水素結合変換反応の開発
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