一般注記Zhou Y., Doi R., Ogoshi S.. Difluoromethylene insertion into fluoroalkyl copper complexes. Chemical Communications 59, 11504 (2023); https://doi.org/10.1039/d3cc03481j.
Herein, we report the insertion of a difluoromethylene into 1,1,2,2-tetrafluoro-2-arylethyl copper complexes to synthesize extended perfluoroalkyl-bridged compounds that have various functional groups on each edge (ArCF2CF2(CF2)nR, R = arenes, halogens, alkyl, alkenyl, and benzyloxycarbonyl). Further, the one-pot syntheses of perfluoroalkyl-bridged compounds from aryl boronic acid esters were carried out.
著作権情報Reproduced from Ref. Chemical Communications with permission from the Royal Society of Chemistry. https://doi.org/10.1039/d3cc03481j
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連携機関・データベース国立情報学研究所 : 学術機関リポジトリデータベース(IRDB)(機関リポジトリ)