Recent advances in catalytic asymmetric C-C bond-forming reactions to ketimines promoted by metal-based catalysts
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- 資料種別
- 記事
- 著者・編者
- Naoya KumagaiMasakatsu Shibasaki
- 出版年月日等
- 2014-11-17
- 出版年（W3CDTF）
- 2014-11-17
- タイトル（掲載誌）
- Bulletin of the Chemical Society of Japan
- 巻号年月日等（掲載誌）
- 88(4)
- 掲載巻
- 88(4)
- ISSN（掲載誌）
- 1348-0634
- ISSN-L（掲載誌）
- 0009-2673
- 本文の言語コード
- eng
- DOI
- 10.1246/bcsj.20140302
- 国立国会図書館永続的識別子
- info:ndljp/pid/11343185
- コレクション（共通）
- コレクション（障害者向け資料：レベル1）
- コレクション（個別）
- 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- 収集根拠
- オンライン資料収集制度
- 受理日（W3CDTF）
- 2019-08-27T20:45:33+09:00
- 保存日（W3CDTF）
- 2019-08-27
- 記録形式（IMT）
- application/pdf
- オンライン閲覧公開範囲
- 国立国会図書館内限定公開
- デジタル化資料送信
- 図書館・個人送信対象外
- 遠隔複写可否（NDL）
- 可
- 掲載誌（国立国会図書館永続的識別子）
- info:ndljp/pid/11343184
- 連携機関・データベース
- 国立国会図書館 : 国立国会図書館デジタルコレクション
- 要約等
- コレクション : 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- DOI
- 10.1246/bcsj.20140302
- 関連情報（URI）
- 参照
- Heterogeneous Heterobimetallic Catalysis Enabling Expeditious Access to CF<sub>3</sub>-Containing <i>vic</i>-Amino AlcoholsEnantioselective Aza-Friedel–Crafts Reaction of Indoles with Ketimines Catalyzed by Chiral Potassium BinaphthyldisulfonatesAsymmetric synthesis of tetrasubstituted cyclic amines <i>via</i> aza-Henry reaction using cinchona alkaloid sulfonamide/zinc(<scp>ii</scp>) catalystsOrganocatalytic Direct Enantioselective Hydrophosphonylation of <i>N</i> -Unsubstituted Ketimines for the Synthesis of α-AminophosphonatesBoron‐Catalyzed α‐Functionalizations of Carboxylic AcidsRecent Progress on Catalytic Addition Reactions to<i>N</i>-Unsubstituted IminesAsymmetric Synthesis of Less Accessible α‐Tertiary Amines from Alkynyl <i>Z‐</i>KetiminesDirect Access to N‐Unprotected α‐ and/or β‐Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich‐Type Reactions Using N‐Unprotected Trifluoromethyl KetiminesSynthesis of <i>N</i>-Boc-Propargylic and Allylic Amines by Reaction of Organomagnesium Reagents with <i>N</i>-Boc-Aminals and Their Oxidation to <i>N</i>-Boc-KetiminesSolid surface vs. liquid surface: nanoarchitectonics, molecular machines, and DNA origamiCatalytic asymmetric synthesis of CF<sub>3</sub>-substituted tertiary propargylic alcohols via direct aldol reaction of α-N<sub>3</sub>amideCationic Iridium‐Catalyzed Asymmetric Decarbonylative Aryl Addition of Aromatic Aldehydes to Bicyclic AlkenesDevelopment and Integration of New Green ReactionsRhodium(I)/Chiral Diene‐Catalyzed Enantioselective Addition of Boronic Acids to <i>N</i>‐Unsubstituted Isatin‐Derived KetiminesCatalytic Enantioselective Strecker Reaction of Isatin-Derived N-Unsubstituted KetiminesDynamism of supramolecular DNA/RNA nanoarchitectonics: From interlocked structures to molecular machinesホウ素化合物によるカルボン酸α位修飾反応の開発Synthesis of 1-Tetrasubstituted 2,2,2-Trifluoroethylamine Derivatives via Palladium-Catalyzed Allylation of sp³ C-H Bonds無保護ケチミンを活用した環境調和型新規触媒的含窒素化合物合成手法の開発
- 参照
- The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydesP-chirogenic organocatalysts : application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketiminesAsymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketiminesHighly Diastereo‐ and Enantioselective Mannich Reactions of Synthetically Flexible Ketimines with Secondary Amine OrganocatalystsRhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxineHighly enantioselective aza-Henry reaction with isatin<i>N</i>-Boc ketimines<i>N</i>-(Heteroarenesulfonyl)prolinamides-Catalyzed Aldol Reaction between Acetone and Aryl Trihalomethyl KetonesRecent Developments in Asymmetric Alkynylation of IminesCatalytic Enantioselective Strecker Reaction of KetoiminesCatalytic Enantioselective Allylation of Carbonyl Compounds and IminesRecent Advances in the Asymmetric Synthesis of α-(Trifluoromethyl)-Containing α-Amino AcidsRecent developments in asymmetric catalytic addition to CN bondsEnantioselective N‐Heterocyclic Carbene Catalyzed Aza‐Benzoin Reaction of Enals with Activated KetiminesEnantioselective Diynylation of Cyclic <i>N</i>‐Acyl Ketimines: Access to Chiral Trifluoromethylated Tertiary CarbinaminesChiral Phosphoric Acid Catalyzed Asymmetric Friedel–Crafts Alkylation of Indole with 3‐Hydroxyisoindolin‐1‐one: Enantioselective Synthesis of 3‐Indolyl‐Substituted Isoindolin‐1‐onesDirect Catalytic Asymmetric Addition of Allylic Cyanides to KetoiminesTransition metal templates as guides for cycloadditionsRecent Advances in Direct Catalytic Asymmetric Transformations under Proton‐Transfer ConditionsHydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3‐Aryl‐3‐hydroxyisoindolin‐1‐onesAsymmetric Synthesis of (Triaryl)methylamines by Rhodium-Catalyzed Addition of Arylboroxines to Cyclic <i>N</i>-Sulfonyl KetiminesDirect Asymmetric Mannich‐Type Reaction of α‐Isocyanoacetates with Ketimines using Cinchona Alkaloid/Copper(II) CatalystsSynthesis of <i>N</i>-Alkoxycarbonyl Ketimines Derived from Isatins and Their Application in Enantioselective Synthesis of 3-AminooxindolesTransition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond CleavageDesign of N-cinnamyl sulfinamides as new sulfur-containing olefin ligands for asymmetric catalysis: achieving structural simplicity with a categorical linear frameworkDesign of N-sulfinyl homoallylic amines as novel sulfinamide-olefin hybrid ligands for asymmetric catalysis: application in Rh-catalyzed enantioselective 1,4-additionsEnantioselective total synthesis of (R)-strongylodiols A and BRhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral AllenylsilanesChiral Brønsted Acid-Catalyzed Asymmetric Trisubstituted Aziridine Synthesis Using α-Diazoacyl OxazolidinonesRhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates to <i>N</i>-Sulfonyl KetiminesAsymmetric Reductive Mannich Reaction to Ketimines Catalyzed by a Cu(I) ComplexRhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate estersCatalytic Asymmetric Synthesis of Either Enantiomer of the Calabar Alkaloids Physostigmine and PhysoveninePd-catalyzed oxidative coupling with organometallic reagents via C–H activationCyclic Ketimines as Superior Electrophiles for NHC-Catalyzed Homoenolate Additions with Broad Scope and Low Catalyst LoadingsRhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthaliminoacrylate Esters toward the Synthesis of β-Amino AcidsDesign of Chiral Sulfoxide–Olefins as a New Class of Sulfur-Based Olefin Ligands for Asymmetric CatalysisStereodivergent Direct Catalytic Asymmetric Mannich‐Type Reactions of α‐Isothiocyanato Ester with KetiminesCatalytic asymmetric synthesis of either enantiomer of physostigmine. Formation of quaternary carbon centers with high enantioselection by intramolecular Heck reactions of (Z)-2-butenanilidesDirect Catalytic Asymmetric Vinylogous Mannich‐Type Reaction of γ‐Butenolides with KetiminesTransition‐Metal‐Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond CleavageReaction between N-(Thio)Phosphoryl Imines and DiethylzincOrganocatalyzed Formal [2 + 2] Cycloaddition of Ketimines with Allenoates: Facile Access to Azetidines with a Chiral Tetrasubstituted Carbon Stereogenic CenterBis(imidazolidine)pyridine-NiCl<sub>2</sub> Catalyst for Nitro-Mannich Reaction of Isatin-Derived <i>N</i>-Boc Ketimines: Asymmetric Synthesis of Chiral 3-Substituted 3-Amino-2-oxindolesCinchona Alkaloid Amide/Copper(II) Catalyzed Diastereo‐ and Enantioselective Vinylogous Mannich Reaction of Ketimines with SiloxyfuransEffect of Chiral Diene Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Sulfonyl CompoundsDirect Catalytic Asymmetric Alkynylation of KetoiminesEnantioselective Construction of Highly Substituted Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with KetiminesEnantioselective Rhodium-Catalyzed Arylation of Cyclic <i>N</i>-Sulfamidate Alkylketimines: A New Access to Chiral β-Alkyl-β-aryl Amino AlcoholsDirect transition metal-catalyzed functionalization of heteroaromatic compoundsCatalytic Enantioselective Allylation of KetoiminesSynthesis of Enantiomerically Enriched 3-Amino-2-oxindoles through a Palladium-Mediated Asymmetric Intramolecular Arylation of α-Ketimino AmidesThe Atom Economy—A Search for Synthetic EfficiencySimple Branched Sulfur–Olefins as Chiral Ligands for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Highly Enantioselective Construction of Tetrasubstituted Carbon StereocentersVinylogous Mannich reactions: selectivity and synthetic utilityA Class of Benzene Backbone-Based Olefin–Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to EnonesEnantioselective Catalytic Addition of HCN to Ketoimines. Catalytic Synthesis of Quaternary Amino Acids[3+2] Cycloaddition Approaches to Five‐Membered Rings via Trimethylenemethane and Its Equivalents [New Synthetic Methods (55)]Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year UpdateChiral N-thiophosphoryl imine-induced diastereoselective aza-Morita–Baylis–Hillman reactionIsocyanoacetate Derivatives: Synthesis, Reactivity, and ApplicationCatalytic Methods for CH Bond Functionalization: Application in Organic SynthesisEnantioselective Rhodium(I)‐Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH ActivationsHighly Enantioselective Organocatalytic aza-Henry Reaction of Nitroalkanes to N-Boc Isatin KetiminesAsymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketiminesN-Thiophosphoryl imines: convenient substrates in the aza-Henry reactionImproved Catalysts for the Palladium-Catalyzed Synthesis of Oxindoles by Amide α-Arylation. Rate Acceleration, Use of Aryl Chloride Substrates, and a New Carbene Ligand for Asymmetric TransformationsThe highly enantioselective addition of indoles and pyrroles to isatins-derived N-Boc ketimines catalyzed by chiral phosphoric acidsEnantioselective ProPhenol-Catalyzed Addition of 1,3-Diynes to Aldehydes to Generate Synthetically Versatile Building Blocks and Diyne Natural ProductsHighly enantioselective zinc/BINOL-catalyzed alkynylation of α-ketoimine ester: a new entry to optically active quaternary α-CF<sub>3</sub> α-amino acidsEvolution of the Vinylogous Mannich Reaction as a Key Construction for Alkaloid SynthesisChiral Brønsted acid-catalyzed enantioselective addition of indoles to ketiminesIntermolecular Hydroacylation by Transition‐Metal ComplexesSynthesis of fluorinated amino acidsCatalytic C−H/Olefin CouplingA facile method for the synthesis of oxindole based quaternary α-aminonitriles via the Strecker reactionA walk around the A3-couplingOrganocatalytic asymmetric cyanation of isatin derived N-Boc ketoiminesFrom Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic CompoundsDevelopment of an N-heterocyclic carbene ligand based on concept of chiral mimeticCatalytic Asymmetric Alkynylation of C1‐Substituted C,N‐Cyclic Azomethine Imines by Cu<sup>I</sup>/Chiral Brønsted Acid Co‐CatalystSynthesis of enantiomerically pure α-ethyl, α-vinyl and α-ethynyl 3,3,3-trifluoro alaninatesTransition Metal-Mediated Cycloaddition ReactionsA convenient and practical method for the synthesis of <i>N</i>‐thiophosphoryl aldimines and ketiminesChiral Olefins as Steering Ligands in Asymmetric CatalysisRecent Advances in Asymmetric Isocyanide‐Based Multicomponent ReactionsHighly Diastereo‐ and Enantioselective Silver‐Catalyzed Double [3+2] Cyclization of α‐Imino Esters with IsocyanoacetateZinc-mediated enantioselective addition of terminal 1,3-diynes to N-arylimines of trifluoropyruvatesRhodium-Catalyzed Highly Enantioselective Arylation of Cyclic Diketimines: Efficient Synthesis of Chiral Tetrasubstituted 1,2,5-Thiadiazoline 1,1-DioxidesMetal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent RecoveryCatalytic Enantioselective Construction of All-Carbon Quaternary StereocentersCatalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck ReactionsAsymmetric Alkynylation of Imines by Cooperative Hydrogen Bonding and Metal CatalysisGeneral and practical catalytic enantioselective Strecker reaction of ketoimines: significant improvement through catalyst tuning by protic additivesRhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to heteroaryl α-ketoesters for synthesis of heteroaromatic α-hydroxy estersThe Aza‐Morita–Baylis–Hillman Reaction of <i>N</i>‐Thiophosphoryl Imines Catalyzed by 1,3,5‐Triaza‐7‐phosphaadamantane (PTA) –– Convenient Synthesis of α‐Methylene‐β‐Amino Ketone or Acid DerivativesEnantioselective Rhodium-Catalyzed Allylation of Cyclic Imines with Potassium AllyltrifluoroboratesSc(BINOL)2Li: a new heterobimetallic catalyst for the asymmetric Strecker reactionSimple <i>N</i>-Sulfinyl-Based Chiral Sulfur–Olefin Ligands for Rhodium-Catalyzed Asymmetric 1,4-AdditionsC-H Bond Functionalization in Complex Organic SynthesisEnantioselective Catalytic Formation of Quaternary Stereogenic CentersHighly Functional Group Compatible Rh-Catalyzed Addition of Arylboroxines to Activated <i>N</i>-<i>tert</i>-Butanesulfinyl KetiminesSynthesis of 3‐Fluoro‐3‐aryl Oxindoles: Direct Enantioselective α Arylation of AmidesEnantioselective Construction of Pyrrolidines by Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of Trimethylenemethane with IminesEnantioselective Ruthenium-Catalyzed 1,3-Dipolar Cycloadditions between <i>C</i>-Carboalkoxy Ketonitrones and Methacrolein: Solvent Effect on Reaction Selectivity and Its RationalAdvances in the Catalytic Asymmetric Arylation of Imines using Organoboron Reagents: An Approach to Chiral ArylaminesOrganocatalyzed Enantioselective Synthesis of Quaternary Carbon‐Containing Isoindolin‐1‐onesPalladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and PracticalityDistinct chemoselectivity in the reaction of N-(thio)phosphoryl imines with diethylzincCarboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and ScopeAsymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and KetiminesChiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesisEnantioselective and Solvent-Controlled Diastereoselective Mannich Reaction of Isatin Imines with Hydroxyacetone: Synthesis of 3-Substituted 3-AminooxindolesHighly Enantioselective Addition of Enals to Isatin-Derived Ketimines Catalyzed by N-Heterocyclic Carbenes: Synthesis of Spirocyclic γ-LactamsNucleophilic phosphine-catalyzed [3+2] cycloaddition of allenes with N-(thio)phosphoryl imines and acidic methanolysis of adducts N-(thio)phosphoryl 3-pyrrolines: a facile synthesis of free amine 3-pyrrolinesProbing Electronic Effects in the Asymmetric Heck Reaction with the BIPI LigandsAn Easy Entry to Optically Active Spiroindolinones: Chiral Brønsted Acid‐Catalysed Pictet–Spengler Reactions of IsatinsHighly Enantioselective Aza-Henry Reaction of Ketoimines Catalyzed by Chiral <i>N</i>,<i>N</i>′-Dioxide−Copper(I) ComplexesRhodium-Catalyzed Enantioselective Addition of Organoaluminum Reagents to <i>N</i>-Tosyl KetiminesEnantioselective Pictet–Spengler reactions of isatins for the synthesis of spiroindolonesDirect Catalytic Enantio‐ and Diastereoselective Mannich Reaction of Isocyanoacetates and KetiminesAsymmetric hydrogenolysis of racemic tertiary alcohols, 3-substituted 3-hydroxyisoindolin-1-onesSulfoxide–Alkene Hybrids: A New Class of Chiral Ligands for the Hayashi–Miyaura ReactionDirect Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond ActivationEnantioselective Strecker Reaction of Phosphinoyl Ketoimines Catalyzed by in Situ Prepared Chiral <i>N</i>,<i>N</i>‘-DioxidesDevelopment of an Asymmetric Trimethylenemethane Cycloaddition Reaction: Application in the Enantioselective Synthesis of Highly Substituted CarbocyclesRhodium-Catalyzed Asymmetric Arylation of <i>N</i>-Tosyl KetiminesRhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond ActivationHigh Performance of a Palladium Phosphinooxazoline Catalyst in the Asymmetric Arylation of Cyclic <i>N</i>‐Sulfonyl KetiminesRu-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic AspectsTransition Metal Catalyzed Alkene and Alkyne HydroacylationOxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligandsElectronic supplementary information (ESI) available: spectroscopic data for 10 and 12. See http://www.rsc.org/suppdata/cc/b2/b208045a/Creation of quaternary stereocenters in carbonyl allylation reactionsSynthetic strategies to α-trifluoromethyl and α-difluoromethyl substituted α-amino acidsCooperative Asymmetric Catalysis Using Thioamides toward Truly Practical Organic SynthesesChiral Propargyl Alcohols via the Enantioselective Addition of Terminal Di- and Triynes to AldehydesChiral Sulfoxide‐Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium‐Catalyzed Asymmetric Conjugate AdditionsCatalytic asymmetric direct Mannich reaction: a powerful tool for the synthesis of α,β-diamino acidsRhodium‐Catalyzed, Highly Enantioselective 1,2‐Addition of Aryl Boronic Acids to α‐Ketoesters and α‐Diketones Using Simple, Chiral Sulfur–Olefin LigandsBifunctional Iminophosphorane Organocatalysts for Enantioselective Synthesis: Application to the Ketimine Nitro-Mannich ReactionPalladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsAccess to α-Substituted Amino Acid Derivatives via 1,3-Dipolar Cycloaddition of α-Amino Ester Derived NitronesA Palladium‐Catalyzed Enantioselective Addition of Arylboronic Acids to Cyclic KetiminesThe Enantioselective Addition of Alkyne Nucleophiles to Carbonyl GroupsEnantioselective Rhodium‐Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic IminesStructure-Based Analysis and Optimization of a Highly Enantioselective Catalyst for the Strecker ReactionAryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct ArylationHighly Enantioselective Alkynylation of Trifluoropyruvate with Alkynylsilanes Catalyzed by the BINAP−Pd Complex: Access to α-Trifluoromethyl-Substituted Tertiary Alcohols“Sulfolefin”: Highly modular mixed S/Olefin ligands for enantioselective Rh-catalyzed 1,4-additionAssembly State of Catalytic Modules as Chiral Switches in Asymmetric Strecker Amino Acid SynthesisA Convenient and Practical Method for the Synthesis of Aromatic Nthiophosphoryl IminesNitrogen-Containing Organofluorine Derivatives: An OverviewEnantioselective Construction of Quaternary Stereocenter through a Reissert-Type Reaction Catalyzed by an Electronically Tuned Bifunctional Catalyst: Efficient Synthesis of Various Biologically Significant CompoundsBulky Chiral Carbene Ligands and Their Application in the Palladium‐Catalyzed Asymmetric Intramolecular α‐Arylation of AmidesEnantioselective Rhodium‐Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents<i>N</i>-Benzyl Aspartate Nitrones: Unprecedented Single-Step Synthesis and [3 + 2] Cycloaddition Reactions with AlkenesThe Vinylogous Aldol and Related Addition Reactions: Ten Years of ProgressCatalytic Enantioselective Mannich-type Reactions of KetoiminesAn Organocatalytic Addition of Nitromethane to Activated KetiminesCatalytic enantioselective addition of terminal 1,3-diynes to aromatic ketones: facile access to chiral nonracemic tertiary alcoholsAsymmetric Activation of <i>tropos</i> 2,2′‐Biphenol with Cinchonine Generates an Effective Catalyst for the Asymmetric Strecker Reaction of <i>N</i>‐Tosyl‐Protected Aldimines and KetoiminesCopper-Catalyzed Asymmetric Alkylation of Imines with Dialkylzinc and Related Reactions
- 連携機関・データベース
- 国立情報学研究所 : CiNii Research
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- 雑誌記事索引データベースCrossrefCiNii Articles科学研究費助成事業データベースCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossref
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