Controlled reactive intermediates enabling facile molecular conjugation
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- 資料種別
- 記事
- 著者・編者
- Suguru Yoshida
- 出版年月日等
- 2018-05-15
- 出版年（W3CDTF）
- 2018-05-15
- タイトル（掲載誌）
- Bulletin of the Chemical Society of Japan
- 巻号年月日等（掲載誌）
- 91(8)
- 掲載巻
- 91(8)
- ISSN（掲載誌）
- 1348-0634
- ISSN-L（掲載誌）
- 0009-2673
- 本文の言語コード
- eng
- DOI
- 10.1246/bcsj.20180104
- 国立国会図書館永続的識別子
- info:ndljp/pid/11343800
- コレクション（共通）
- コレクション（障害者向け資料：レベル1）
- コレクション（個別）
- 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- 収集根拠
- オンライン資料収集制度
- 受理日（W3CDTF）
- 2019-08-28T20:45:13+09:00
- 保存日（W3CDTF）
- 2019-03-13
- 記録形式（IMT）
- application/pdf
- オンライン閲覧公開範囲
- 国立国会図書館内限定公開
- デジタル化資料送信
- 図書館・個人送信対象外
- 遠隔複写可否（NDL）
- 可
- 掲載誌（国立国会図書館永続的識別子）
- info:ndljp/pid/11343796
- 連携機関・データベース
- 国立国会図書館 : 国立国会図書館デジタルコレクション
- コレクション（個別）
- 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- オンライン閲覧公開範囲
- 国立国会図書館内限定公開
- デジタル化資料送信
- 図書館・個人送信対象外
- 遠隔複写可否（NDL）
- 可
- 所蔵機関
- 国立国会図書館
- 請求記号
- Z53-B35
- 関連情報（国立国会図書館永続的識別子）
- info:ndljp/pid/11343800
- 連携機関・データベース
- 国立国会図書館 : 国立国会図書館雑誌記事索引
- 書誌ID（NDLBibID）
- 029141104
- 整理区分コード
- 632
- 要約等
- コレクション : 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- DOI
- 10.1246/bcsj.20180104
- オンライン閲覧公開範囲
- インターネット公開
- 関連情報（URI）
- 参照
- Steric effects on deprotonative generation of cyclohexynes and 1,2-cyclohexadienes from cyclohexenyl triflates by magnesium amides3-Thioaryne Intermediates for the Synthesis of Diverse ThioarenesSynthesis of Diverse γ-Aryl-β-ketoesters via Aryne Intermediates Generated by C–C Bond CleavageTriazole formation of phosphinyl alkynes with azides through transient protection of phosphine by copper2-Azidoacrylamides as compact platforms for efficient modular synthesisDiverse diaryl sulfide synthesis through consecutive aryne reactionsMultisubstituted naphthalene synthesis from 4-hydroxy-2-pyrones through [4+2] cycloaddition with <i>o</i>-silylaryl triflatesSelective strain-promoted azide–alkyne cycloadditions through transient protection of bicyclo[6.1.0]nonynes with silver or goldSynthesis of Multisubstituted Benzenes from Phenols via Multisubstituted BenzynesAcylalkylation of Arynes Generated from <i>o</i>-Iodoaryl Triflates with Hydrosilanes and Cesium FluorideAssembly of four modules onto a tetraazide platform by consecutive 1,2,3-triazole formationsOne-step synthesis of benzo[<i>b</i>]thiophenes by aryne reaction with alkynyl sulfidesSynthesis of Functionalized Benzopyran/Coumarin-Derived Aryne Precursors and Their Applications(Hexafluoroacetylacetonato)copper(<scp>i</scp>)–cycloalkyne complexes as protected cycloalkynesSynthesis of <i>N</i>Ms-DACN: Small and Hydrophilic Click Reaction DeviceSequential conjugation methods based on triazole formation and related reactions using azidesFacile assembly of three cycloalkyne-modules onto a platform compound bearing thiophene <i>S</i>,<i>S</i>-dioxide moiety and two azido groups多成分集積を指向した合成のためのアライン化学Facile synthesis of diverse 2,6-disubstituted arylsilanes via silylamination and silylsulfanylation of aryne intermediates generated from o-iodoaryl triflatesSynthesis of thioxanthones through formal C-H thiolation of benzoic acid esters and acid-mediated direct cyclizationEffect of resonance on the clickability of alkenyl azides in the strain-promoted cycloaddition with dibenzo-fused cyclooctynesSynthesis of phenoxathiins and phenothiazines by aryne reactions with thiosulfonatesModular synthesis of unsymmetrical doubly-ring-fused benzene derivatives based on a sequential ring construction strategy using oxadiazinones as a platform moleculeFacile synthesis of diverse o-iodoaryl triflates from o-silylaryl triflates by aluminum-mediated desilyliodinationAryne reaction and cross-coupling approach for the synthesis of diverse N-arylphenylalanine derivatives
- 参照
- Selective inhibition of the kinase DYRK1A by targeting its folding processDevelopment of an orally available inhibitor of CLK1 for skipping a mutated dystrophin exon in Duchenne muscular dystrophyGeneration of cycloalkynes through deprotonation of cyclic enol triflates with magnesium bisamidesConstruction of Condensed Polycyclic Aromatic Frameworks through Intramolecular Cycloaddition Reactions Involving Arynes Bearing an Internal Alkyne MoietyC6-Deoxy coelenterazine analogues as an efficient substrate for glow luminescence reaction of nanoKAZ: The mutated catalytic 19kDa component of Oplophorus luciferaseExpression, purification and luminescence properties of coelenterazine-utilizing luciferases from Renilla, Oplophorus and Gaussia: Comparison of substrate specificity for C2-modified coelenterazinesDirect Thioamination of Arynes via Reaction with Sulfilimines and Migratory <i>N</i>-ArylationThree-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methidesTrifluoromethanesulfonyloxy-group-directed regioselective (3 + 2) cycloadditions of benzynes for the synthesis of functionalized benzo-fused heterocyclesGeneration of cycloheptynes and cyclooctynes via a sulfoxide–magnesium exchange reaction of readily synthesized 2-sulfinylcycloalkenyl triflatesA mild and facile synthesis of aryl and alkenyl sulfides via copper-catalyzed deborylthiolation of organoborons with thiosulfonates1,3- and 1,4-Benzdiyne equivalents for regioselective synthesis of polycyclic heterocyclesControlled Generation of 3-TriflyloxyarynesFormal C–H‐Azidation – Based Shortcut to Diazido Building Blocks for the Versatile Preparation of Photoaffinity Labeling ProbesTransient Protection of Strained Alkynes from Click Reaction via Complexation with CopperThe mevalonate pathway regulates primitive streak formation via protein farnesylationIdentification of a Dual Inhibitor of SRPK1 and CK2 That Attenuates Pathological Angiogenesis of Macular Degeneration in MiceImaging the Sialome during Zebrafish Development with Copper‐Free Click ChemistryCycloaddition Chemistry of Tetrafluorothiophene <i>S</i>,<i>S</i>-DioxideStrain-Promoted Azide–Alkyne Cycloadditions of BenzocyclononynesClick Chemistry in Complex Mixtures: Bioorthogonal BioconjugationPractical, Modular, and General Synthesis of Benzofurans through Extended Pummerer Annulation/Cross‐Coupling StrategyStaudinger Ligation: A Peptide from a Thioester and AzideSteric and Chelate Directing Effects in Aromatic Borylation3,4-Di-tert-butylthiophene 1,1-dioxide, a convenient precursor of o-Di-tert-butylbenzene and its derivativesSystemic Fluorescence Imaging of Zebrafish Glycans with Bioorthogonal ChemistryHexaradialenes by Successive Ring Openings of Tris(alkoxy‐tricyclobutabenzenes): Synthesis and CharacterizationReaction of Arynes with Vinyl Sulfoxides: Highly Stereospecific Synthesis of <i>ortho</i>-Sulfinylaryl Vinyl EthersP-Arylation: Arynes to Aryl-Phosphonates, -Phosphinates, and -Phosphine OxidesUltrafast Click Chemistry with FluorosydnonesHypervalent Iodine/Triflate Hybrid Benzdiyne Equivalents: Access to Controlled Synthesis of Polycyclic Aromatic CompoundsAn efficient generation method and remarkable reactivities of 3-triflyloxybenzyneThiazolobenzyne: a versatile intermediate for multisubstituted benzothiazolesSynthesis of Diverse Aromatic Oxophosphorus Compounds by the Michaelis–Arbuzov-type Reaction of ArynesConvergent synthesis of trifunctional molecules by three sequential azido-type-selective cycloadditionsRemodeling of Actin Cytoskeleton in Mouse Periosteal Cells under Mechanical Loading Induces Periosteal Cell Proliferation during Bone FormationAryne multifunctionalization with benzdiyne and benztriyne equivalentsCu-Catalyzed Azide−Alkyne CycloadditionSynthesis of 3-Trifluoromethylbenzo[<i>b</i>]furans from Phenols via Direct <i>Ortho</i> Functionalization by Extended Pummerer ReactionDomino Aryne Precursor: A Step beyond the Boundary of Traditional Aryne ChemistryZur Existenz niedergliedriger Cycloalkine, ICobalt-Catalyzed Intramolecular Heck-Type Reaction of 6-Halo-1-hexene Derivatives<i>Meta</i>- and<i>Para</i>-Difunctionalization of Arenes via a Sulfoxide−Magnesium Exchange ReactionBinding Ensemble Profiling with Photoaffinity Labeling (BEProFL) Approach: Mapping the Binding Poses of HDAC8 InhibitorsSelective Activation of Arylboronate or Aryne Reactivity as a Versatile Postfunctionalization StrategyLight-Activated Staudinger–Bertozzi Ligation within Living AnimalsFluorogenic Strain‐Promoted Alkyne–Diazo CycloadditionsOne Century of Aryne ChemistryCobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck ReactionNew efficient protocol for aryne generation. Selective synthesis of differentially protected 1,4,5-naphthalenetriolsRegioselectivity of Diels–Alder reactions between 6,7-dehydrobenzofuran and 2-substituted furansTris(alkyne) and Bis(alkyne) Complexes of Coinage Metals: Synthesis and Characterization of (cyclooctyne)<sub>3</sub>M<sup>+</sup> (M = Cu, Ag) and (cyclooctyne)<sub>2</sub>Au<sup>+</sup> and Coinage Metal (M = Cu, Ag, Au) Family Group TrendsConcise Synthesis of the Bicyclic Scaffold of<i>N</i>-Methylwelwitindolinone C Isothiocyanate via an Indolyne CyclizationCell Surface Engineering by a Modified Staudinger ReactionNucleophilic Coupling with Aryl RadicalsRearrangementsA Mitochondrial Surface‐Specific Fluorescent Probe Activated by BioconversionA Multicomponent Coupling Reaction Induced by Insertion of Arynes into the CO Bond of FormamideAryne Relay Chemistry en Route to Aminoarenes: Synthesis of 3-Aminoaryne Precursors via Regioselective Silylamination of 3-(Triflyloxy)arynesThree-Component Coupling of Triflyloxy-Substituted Benzocyclobutenones, Organolithium Reagents, and Arynophiles Promoted by Generation of Aryne via Carbon–Carbon Bond CleavageFLUORIDE-INDUCED 1,2-ELIMINATION OF <i>O</i>-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONSLuminescence enhancement of the catalytic 19kDa protein (KAZ) of Oplophorus luciferase by three amino acid substitutionsDevelopment of bis-unsaturated ester aldehydes as amino-glue probes: sequential double azaelectrocyclization as a promising strategy for bioconjugationRectifier of aberrant mRNA splicing recovers tRNA modification in familial dysautonomiaCDK9 inhibitor FIT-039 prevents replication of multiple DNA viruses[4+2] Cycloaddition Reaction of Cyclic Alkyne–{Co<sub>2</sub>(CO)<sub>6</sub>} Complexes with DienesStrain-Promoted 1,3-Dipolar Cycloaddition of Cycloalkynes and Organic AzidesNovel bifunctional probe for radioisotope-free photoaffinity labeling: compact structure comprised of photospecific ligand ligation and detectable tag anchoring unitsElectronic supplementary information (ESI) available: Photo-decomposition study of phenyl and benzyl azides. Experimental details for photoreactions of 1 and 5. Synthetic procedures and characterization of new compounds. See http://www.rsc.org/suppdata/ob/b3/b316221d/.Synthetic Applications of Flexible SNO-OCT Strained Alkynes and Their Use in Postpolymerization ModificationsThree-Component Coupling Reaction Triggered by Insertion of Arynes into the S═O Bond of DMSODomino Aryne Annulation via a Nucleophilic–Ene ProcessMultifunctionalization of Polymers by Strain-Promoted CycloadditionsEfficient Synthesis of 9-Aryldihydrophenanthrenes by a Cascade Reaction Involving Arynes and StyrenesDouble Strain‐Promoted Macrocyclization for the Rapid Selection of Cell‐Active Stapled PeptidesProtein Modification by Strain‐Promoted Alkyne–Nitrone CycloadditionA metal-free turn-on fluorescent probe for the fast and sensitive detection of inorganic azidesDehydrobenzene and CycloalkynesExpanding the Strained Alkyne Toolbox: Generation and Utility of Oxygen-Containing Strained AlkynesReaction of Arynes with SulfoxidesSteric Effects Compete with Aryne Distortion To Control Regioselectivities of Nucleophilic Additions to 3-SilylarynesSynthesis of a Library of Fluorescent 2‐Aryl‐3‐trifluoromethylnaphthofurans from Naphthols by Using a Sequential Pummerer‐Annulation/Cross‐Coupling Strategy and their Photophysical PropertiesSubstituted 5,6,11,12-Tetradehydrodibenzo[<i>a</i>,<i>e</i>]cyclooctenes: Syntheses, Properties, and DFT Studies of Substituted Sondheimer–Wong DiynesModular synthesis of bis- and tris-1,2,3-triazoles by permutable sequential azide–aryne and azide–alkyne cycloadditions3-(Triflyloxy)benzynes Enable the Regiocontrolled Cycloaddition of Cyclic Ureas to Synthesize 1,4-Benzodiazepine DerivativesAryne, <i>ortho</i>-Quinone Methide, and <i>ortho</i>-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive IntermediatesAn Alternative Method for Generating Arynes from ortho-Silylaryl Triflates: Activation by Cesium Carbonate in the Presence of a Crown EtherCXCR4-derived synthetic peptides inducing anti-HIV-1 antibodiesSynthesis of Diverse <i>o</i>-Arylthio-Substituted Diaryl Ethers by Direct Oxythiolation of Arynes with Diaryl Sulfoxides Involving Migratory <i>O</i>-ArylationMetal-Free Approach for the Synthesis of <i>N</i>-Aryl Sulfoximines via Aryne IntermediatePreparation of Congested Thiophenes Carrying Bulky Substituents on the 3- and 4-Positions and Their Conversion to the Benzene DerivativesIn Vivo Imaging of Membrane-Associated Glycans in Developing ZebrafishOverturning Indolyne Regioselectivities and Synthesis of Indolactam VStrain‐Promoted Alkyne–Azide Cycloadditions (SPAAC) Reveal New Features of Glycoconjugate BiosynthesisRuthenium-Catalyzed Cycloaddition of Alkynes and Organic AzidesEnhanced clickability of doubly sterically-hindered aryl azidesAminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivativesMixed Mg/Li Amides of the Type R<sub>2</sub>NMgCl⋅LiCl as Highly Efficient Bases for the Regioselective Generation of Functionalized Aryl and Heteroaryl Magnesium CompoundsPolar Dibenzocyclooctynes for Selective Labeling of Extracellular Glycoconjugates of Living CellsEnantiospecific Total Synthesis of <i>N</i>‐Methylwelwitindolinone D IsonitrileThe aromatic ene reactionComputational predictions of substituted benzyne and indolyne regioselectivitiesFluorophore Targeting to Cellular Proteins via Enzyme-Mediated Azide Ligation and Strain-Promoted CycloadditionA Strain-Promoted [3 + 2] Azide−Alkyne Cycloaddition for Covalent Modification of Biomolecules in Living SystemsReaktionen von Cyclooctin mit Übergangsmetall‐DerivatenBioconjugation via azide–Staudinger ligation: an overviewPREPARATION OF BENZOCYCLOBUTENONE DERIVATIVES BASED ON AN EFFICIENT GENERATION OF BENZYNESConcise Enantiospecific Total Synthesis of Tubingensin AReliable and Diverse Synthesis of Aryl Azides through Copper‐Catalyzed Coupling of Boronic Acids or Esters with TMSN<sub>3</sub>Remarkably Selective Iridium Catalysts for the Elaboration of Aromatic C-H BondsIndolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic AdditionsExploring Strain‐Promoted 1,3‐Dipolar Cycloadditions of End Functionalized PolymersSynthesis of Trifunctional Bis-azide Photoaffinity ProbeCommunications. Reaction of Benzyne with Organophosphorus Esters.Vicinal Diamination of Arenes with Domino Aryne PrecursorsSynthetic Methods for the Generation and Preparative Application of BenzyneDirect Access to Fused Salicylaldehydes and Salicylketones from TetraynesUntersuchungen an Siebenringsystemen, II. Zur Synthese und Umlagerung von Tribenzocycloheptatrienon‐DerivatenInverse electron demand Diels–Alder (iEDDA)-initiated conjugation: a (high) potential click chemistry schemeMechanism of the Reactions of Alcohols with <i>o</i>-BenzynesFacile synthesis of diazido-functionalized biaryl compounds as radioisotope-free photoaffinity probes by Suzuki–Miyaura couplingUntersuchungen an Siebenringsystemen, I. Über das intermediäre Auftreten von 4.5‐Dehydro‐2.3;6.7‐dibenzo‐ cycloheptatrienonConvergent Assembly and Surface Modification of Multifunctional Dendrimers by Three Consecutive Click ReactionsMechanistic Investigation of the Staudinger LigationHighly accelerated inverse electron-demand cycloaddition of electron-deficient azides with aliphatic cyclooctynesHaloTag Technology: A Versatile Platform for Biomedical ApplicationsRegioselective reactions of 3,4-pyridynes enabled by the aryne distortion modelHexadehydro-Diels–Alder (HDDA)-Enabled Carbazolyne Chemistry: Single Step, de Novo Construction of the Pyranocarbazole Core of Alkaloids of the <i>Murraya koenigii</i> (Curry Tree) FamilyHeteroatom‐embedded Medium‐Sized Cycloalkynes: Concise Synthesis, Structural Analysis, and ReactionsA Comprehensive History of Arynes in Natural Product Total SynthesisA one-pot synthesis of m-terphenyls, via a two-aryne sequenceTotal synthesis and absolute stereochemical assignment of gilvocarcin M.Reactions of hexadehydro-Diels–Alder benzynes with structurally complex multifunctional natural productsCobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium ChlorideAngle strained cycloalkynesCycloadditions of Cyclohexynes and CyclopentyneChemoselective Staudinger‐Phosphite Reaction of Azides for the Phosphorylation of Proteins<i>N</i>-Tosyl-3-Azacyclohexyne. Synthesis and Chemistry of a Strained Cyclic YnamideA new source for generation of benzyne and pyridyne: Reactions of O-halophenyl (or 3-bromo-4-pyridyl) phenyl sulfoxides with grignard reagantsReadily Accessible Bicyclononynes for Bioorthogonal Labeling and Three‐Dimensional Imaging of Living CellsChemistry of Thiophene 1,1-DioxidesIsolable Tris(alkyne) and Bis(alkyne) Complexes of Gold(I)Stereospecificity in [2 + 2] cycloaddition of benzyne and ketene silyl acetalRecent advances in molecular rearrangements involving aryne intermediatesSynthesis of phosphonamidate peptides by Staudinger reactions of silylated phosphinic acids and estersTwo-faced copperThe Hexadehydro-Diels–Alder Cycloisomerization Reaction Proceeds by a Stepwise MechanismClicking 1,2,4,5-tetrazine and cyclooctynes with tunable reaction ratesAn Interesting Benzyne-Mediated Annulation Leading to Benzo[<i>a</i>]pyreneFast copper-free click DNA ligation by the ring-strain promoted alkyne-azide cycloaddition reactionÜber das intermediäre Auftreten von CyclopentinControl and Design of Mutual Orthogonality in Bioorthogonal CycloadditionsRecent advances in the staudinger reactionOrthogonal synthesis of pyrroles and 1,2,3-triazoles from vinyl azides and 1,3-dicarbonyl compoundsClick-EM for imaging metabolically tagged nonprotein biomolecules1‐Benzyl‐1,2,3,4‐tetrahydroisoquinoline binds with tubulin β, a substrate of parkin, and reduces its polyubiquitinationSynthesis of a Fluorogenic Cyclooctyne Activated by Cu-Free Click ChemistryBioorthogonal Chemistry: Fishing for Selectivity in a Sea of FunctionalityTotal Synthesis of Selaginpulvilin C and D Relying on<i>in Situ</i>Formation of Arynes and Their HydrogenationTotal Synthesis of the Gilvocarcins3-Azidodifluoromethyl-3H-diazirin-3-yl group as an all-in-one functional group for radioisotope-free photoaffinity labelingA Hydrophilic Azacyclooctyne for Cu-Free Click ChemistryDesign of dantrolene-derived probes for radioisotope-free photoaffinity labeling of proteins involved in the physiological Ca2+ release from sarcoplasmic reticulum of skeletal muscleThe Reaction of Thio Acids with Azides: A New Mechanism and New Synthetic ApplicationsRuthenium-Catalyzed Azide−Alkyne Cycloaddition: Scope and MechanismSynthesis of Oxygen Heterocycles via Aromatic C-O Bond Formation Using ArynesGeneration of cyclohexyne and its Diels-Alder reaction with α-pyronesThe aza-Wittig reaction: an efficient tool for the construction of carbon–nitrogen double bondsThe use of arynes in organic synthesisIntramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and DienesPreparation of Well‐Defined Antibody–Drug Conjugates through Glycan Remodeling and Strain‐Promoted Azide–Alkyne CycloadditionsA click-and-release approach to CO prodrugsSelective Aryne Formation via Grob Fragmentation from the [2+2] Cycloadducts of 3-TriflyloxyarynesIsochroman-3-ones via site-selective ring opening of benzocyclobutenones promoted by lithium tetramethylpiperidide and reaction with aromatic aldehydesPhotoreactive “Nanorulers” Detect a Novel Conformation of Full Length HDAC3-SMRT Complex in SolutionUse of benzynes for the synthesis of heterocyclesCopper-free click chemistry for dynamic <i>in vivo</i> imagingTwo‐Directional Annelation: Dual Benzyne Cycloadditions Starting from Bis(sulfonyloxy)diiodobenzeneTotal Synthesis of (−)-<i>N</i>-Methylwelwitindolinone C IsothiocyanateTotal synthesis of antibiotic C104: Benzyne-Furan cycloaddition approach to the angucyclinesFunctionalized Cyclopropenes As Bioorthogonal Chemical ReportersMetal-Free Sequential [3 + 2]-Dipolar Cycloadditions using Cyclooctynes and 1,3-Dipoles of Different ReactivityFunctional Role of Neuroendocrine-Specific Protein-Like 1 in Membrane Translocation of GLUT4A “Traceless” Staudinger Ligation for the Chemoselective Synthesis of Amide BondsReactions of HDDA-Derived Benzynes with Sulfides: Mechanism, Modes, and Three-Component ReactionsFrom Mechanism to Mouse: A Tale of Two Bioorthogonal ReactionsAn Efficient Computational Model to Predict the Synthetic Utility of Heterocyclic ArynesThiacycloalkynes for Copper‐Free Click ChemistrySynthesis and Reactivity of DibenzoselenacycloheptynesStoichiometric and Catalytic B−C Bond Formation from Unactivated Hydrocarbons and BoranesNew synthetic reactions catalyzed by cobalt complexesBioorthogonal Labeling of Human Prostate Cancer Tissue Slice Cultures for GlycoproteomicsOn the Regiochemistry of Cycloaddition of Unsymmetrical Aryne with Nitrone Remarkable Effect of Trialkylsilyl SubstituentBenzyne-Furan Cycloaddition Approach to the Angucyclines: First Total Synthesis of Antibiotic C104Reactivity of Biarylazacyclooctynones in Copper-Free Click ChemistrySynthesis of Benzo[<i>b</i>]thiophenes by Cyclization of Arylketene Dithioacetal Monoxides under Pummerer-like Conditions<i>N</i>-Arylation of Tertiary Amines under Mild ConditionsDesign, Synthesis, Docking, and Biological Evaluation of Novel Diazide-Containing Isoxazole- and Pyrazole-Based Histone Deacetylase ProbesBi‐3<i>H</i>‐diazirin‐3‐yls as Precursors of Highly Strained CycloalkynesAryne Cycloaddition Reactions in the Synthesis of Large Polycyclic Aromatic CompoundsDodecamethoxy- and Hexaoxotricyclobutabenzene: Synthesis and CharacterizationStrain-Induced Regioselectivities in Reactions of Benzyne Possessing a Fused Four-Membered Ring1,2,4-Triazines Are Versatile Bioorthogonal ReagentsAlkane desaturation by concerted double hydrogen atom transfer to benzyneTotal syntheses of indolactam alkaloids (−)-indolactam V, (−)-pendolmycin, (−)-lyngbyatoxin A, and (−)-teleocidin A-2Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynesTwo-step bioorthogonal activity-based proteasome profiling using copper-free click reagents: A comparative studyDiamination of Domino Aryne Precursor with SulfonamidesUnsaturated eight-membered ring compounds. XI. Synthesis of sym-dibenzo-1,5-cyclooctadiene-3,7-diyne and sym-dibenzo-1,3,5-cyclooctatrien-7-yne, presumably planar conjugated eight-membered ring compoundsCopper-free click chemistry in living animalsBlue-Emitting Arylalkynyl Naphthalene Derivatives via a Hexadehydro-Diels–Alder Cascade ReactionSixty years of staudinger reactionLigand-Accelerated Cu-Catalyzed Azide−Alkyne Cycloaddition: A Mechanistic ReportAnnulations with tetrachlorothiophene 1,1-dioxideSynthesis of biaryls using aryne intermediatesCu-free click cycloaddition reactions in chemical biologyAngle‐Strained CycloalkynesThree different consecutive orbital symmetry-controlled reactions in the novel stereospecific synthesis of 1-phenyl-4-(1-phenylethenyl)naphthalene. The reaction of 3,4-diphenylthiophene 1,1-dioxide with ethynylbenzeneSurface Modification of Polymeric Micelles by Strain‐Promoted Alkyne–Azide CycloadditionsTransition-Metal-Free Catalytic Synthesis of 1,5-Diaryl-1,2,3-triazolesIndolyne and Aryne Distortions and Nucleophilic RegioselectivitesSecond-Generation Difluorinated Cyclooctynes for Copper-Free Click ChemistryPhoto-click chemistry strategies for spatiotemporal control of metal-free ligation, labeling, and surface derivatizationAryne 1,2,3-Trifunctionalization with Aryl Allyl SulfoxidesAzide: A Unique Dipole for Metal‐Free Bioorthogonal LigationsSubstituted Cyclopropenones<sup>1</sup>Copper‐Free Click Reactions with Polar Bicyclononyne Derivatives for Modulation of Cellular ImagingDifluorobenzocyclooctyne: Synthesis, Reactivity, and Stabilization by β-CyclodextrinTotal Synthesis of Oxidized Welwitindolinones and (−)-<i>N</i>-Methylwelwitindolinone C IsonitrileArynes and Cyclohexyne in Natural Product SynthesisBoryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through CH Activation and Orthogonal ReactivityA Comparative Study of Bioorthogonal Reactions with AzidesStrain-promoted double-click reaction for chemical modification of azido-biomoleculesControlled Multi‐functionalization Facilitates Targeted Delivery of Nanoparticles to Cancer CellsAnilide Formation from Thioacids and Perfluoroaryl AzidesAryne‐Based Multicomponent ReactionsA Homologation Approach to the Synthesis of Difluorinated CycloalkynesVisualizing Metabolically Labeled Glycoconjugates of Living Cells by Copper‐Free and Fast Huisgen CycloadditionsTotal Syntheses of the Elusive Welwitindolinones with Bicyclo[4.3.1] CoresClick and Release: SO<sub>2</sub> Prodrugs with Tunable Release RatesZur Existenz niedergliedriger Cycloalkine, VIII Zur Bildung und Reaktivität von CyclooctinAryl Fluorosulfate Trapped Staudinger ReductionChemoselective Formation of Successive Triazole Linkages in One Pot: “Click−Click” ChemistryStrain‐Promoted Reaction of 1,2,4‐Triazines with BicyclononynesPreparation of Polyfunctional Arynes via 2‐Magnesiated Diaryl SulfonatesIndolynes as Electrophilic Indole Surrogates: Fundamental Reactivity and Synthetic ApplicationsMetal Complexes of Small Cycloalkynes and ArynesMonomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)<sup>1</sup>A new entry to the preparation of pyrrolo[2,3-b]quinolines by an aza Wittig/electrocyclic ring-closure/nitrene insertion processRapid Cu-Free Click Chemistry with Readily Synthesized BiarylazacyclooctynonesEnabling the Use of Heterocyclic Arynes in Chemical SynthesisTransition-Metal-Catalyzed Reactions Involving ArynesSynthesis of <i>o</i>-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl SulfoxidesSelective Labeling of Living Cells by a Photo-Triggered Click ReactionCopper-free click chemistry for the in situ crosslinking of photodegradable star polymersDesign, synthesis, modeling, biological evaluation and photoaffinity labeling studies of novel series of photoreactive benzamide probes for histone deacetylase 2Thiol–Ene Click ChemistryDecoupling Deprotonation from Metalation: Thia‐Fries RearrangementSulfur dioxide prodrugs: triggered release of SO<sub>2</sub>via a click reactionA Bioorthogonal Ligation Enabled by Click Cycloaddition of <i>o</i>-Quinolinone Quinone Methide and Vinyl ThioetherSynthesis of Heterobifunctional Protein Fusions Using Copper‐Free Click Chemistry and the Aldehyde TagThe Staudinger Ligation—A Gift to Chemical BiologyMulticomponent Coupling Reaction of Arynes for Construction of Heterocyclic SkeletonsReactions of arynes promoted by silver ionsBringing chemistry to lifeTotal Synthesis of Galtamycinone, the Common Aglycon of the C-Glycosyl Naphthacenequinone AntibioticsFine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTsAryne Insertion Reactions into Carbon-Carbon σ-BondsA “Hot, Energized” BenzyneTheory of 1,3-Dipolar Cycloadditions: Distortion/Interaction and Frontier Molecular Orbital ModelsStrain-Promoted Oxidation-Controlled Cyclooctyne–1,2-Quinone Cycloaddition (SPOCQ) for Fast and Activatable Protein ConjugationRecent advances in fluoride-free aryne generation from arene precursorsThe pentadehydro-Diels–Alder reactionMild Iridium-Catalyzed Borylation of Arenes. High Turnover Numbers, Room Temperature Reactions, and Isolation of a Potential IntermediateElectronic Effects versus Distortion Energies During Strain‐Promoted Alkyne‐Azide Cycloadditions: A Theoretical Tool to Predict Reaction KineticsA general method for affinity-based proteomic profiling of exo-α-glycosidasesAlkane C–H Insertion by Aryne Intermediates with a Silver Catalyst[2+2] Cycloaddition of Benzyne and Ketene Silyl Acetal as an Efficient Route to BenzocyclobutenonesClick Chemistry for Biotechnology and Materials ScienceThe Role of Aryne Distortions, Steric Effects, and Charges in Regioselectivities of Aryne ReactionsThe synthesis and biological evaluation of labelled karrikinolides for the elucidation of the mode of action of the seed germination stimulantAlkyne Phosphonites for Sequential Azide–Azide CouplingsProbing the Mycobacterial Trehalome with Bioorthogonal ChemistryLive‐Cell Imaging of Cellular Proteins by a Strain‐Promoted Azide–Alkyne CycloadditionPhotochemical Hexadehydro-Diels–Alder ReactionReduction d'azides en amines primaires par une methode generale utilisant la reaction de staudingerHaloTag Protein‐Mediated Site‐Specific Conjugation of Bioluminescent Proteins to Quantum DotsA Fluorogenic Probe for the Catalyst-Free Detection of Azide-Tagged MoleculesPhotochemical generation of oxa-dibenzocyclooctyne (ODIBO) for metal-free click ligationsDomino Aryne Precursor: Efficient Construction of 2,4-Disubstituted BenzothiazolesIsomeric Cyclopropenes Exhibit Unique Bioorthogonal ReactivitiesCyclopropenone-caged Sondheimer diyne (dibenzo[a,e]cyclooctadiyne): a photoactivatable linchpin for efficient SPAAC crosslinkingCycloheptyne Intermediate in the Reaction of Chiral Cyclohexylidenemethyliodonium Salt with SulfonatesSynthesis of DIBAC analogues with excellent SPAAC rate constantsMany-Membered Carbon Rings. VI. Unsaturated Nine-membered Cyclic Hydrocarbons<sup>1</sup>Novel histone deacetylase 8 ligands without a zinc chelating group: Exploring an ‘upside-down’ binding poseSite-Specific Antibody–Drug Conjugates: The Nexus of Bioorthogonal Chemistry, Protein Engineering, and Drug DevelopmentEmploying Arynes in Diels–Alder Reactions and Transition-Metal-Free Multicomponent Coupling and Arylation ReactionsDibenzofuran. XXIII. Rearrangement of Halogen Compounds in Amination by Sodamide<sup>1</sup>The identification of substituted benzothiophene derivatives as PGE2 subtype 4 receptor antagonists: From acid to non-acidPoly-Oxygenated Tricyclobutabenzenes via Repeated [2 + 2] Cycloaddition of Benzyne and Ketene Silyl AcetalC−H Activation for the Construction of C−B BondsPYRROC: the first functionalized cycloalkyne that facilitates isomer-free generation of organic molecules by SPAACPhotolysis of 1‐Tosylamino‐1,2,3‐triazole Anions; A New Synthesis of AlkynesSynthesis of Penicillenol C<sub>1</sub> and of a Bis-Azide Analogue for Photoaffinity LabelingPyridynes and indolynes as building blocks for functionalized heterocycles and natural productsBranched Polyhedral Oligomeric Silsesquioxane Nanoparticles Prepared via Strain-Promoted 1,3-Dipolar CycloadditionsThe hexadehydro-Diels–Alder reactionStaudinger Ligation as a Method for BioconjugationPeptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to AzidesTotal Synthesis of the Gilvocarcins.Prenatal neurogenesis induction therapy normalizes brain structure and function in Down syndrome miceGeneration of arynes using trimethylsilylmethyl Grignard reagent for activation of ortho-iodoaryl or ortho-sulfinylaryl triflatesSynthesis of diverse benzotriazoles from aryne precursors bearing an azido group via inter- and intramolecular cycloadditionsFacile synthesis of multisubstituted benzo[b]furans via 2,3-disubstituted 6,7-furanobenzynes generated from ortho-iodoaryl triflate-type precursorsAromatic azido-selective reduction via the Staudinger reaction using tri-n-butylphosphonium tetrafluoroborate with triethylamineThe renaissance and bright future of synthetic aryne chemistryReactions of arynes with sulfoximines : formal sulfinylamination vs. N-arylationEnhancing the synthetic utility of 3-haloaryne intermediates by their efficient generation from readily synthesizable ortho-iodoaryl triflate-type precursorsGeneration of arynes triggered by sulfoxide-metal exchange reaction of ortho-sulfinylaryl triflatesSequential molecular conjugation using thiophene S,S-dioxides bearing a clickable functional groupFacile synthesis of diverse multisubstituted ortho-silylaryl triflates via C-H borylationFacile diversification of simple benzo[b]thiophenes via thienobenzyne intermediates
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- 国立情報学研究所 : CiNii Research
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