Silver-catalyzed vinylic C-F bond activation : synthesis of 2-fluoroindoles from β,β-difluoro-o-sulfonamidostyrenes

• 資料種別: 記事
• タイトル: Silver-catalyzed vinylic C-F bond activation : synthesis of 2-fluoroindoles from β,β-difluoro-o-sulfonamidostyrenes
• 著者・編者: Takeshi Fujita; Yota Watabe; Shigeyuki Yamashita
• 出版事項: 日本 : The Chemical Society of Japan
• 出版年月日等: 2016-05-20
• 出版年（W3CDTF）: 2016-05-20
• タイトル（掲載誌）: Chemistry letters
• 巻号年月日等（掲載誌）: 45(8)
• 掲載巻: 45(8)
• ISSN（掲載誌）: 1348-0715
• ISSN-L（掲載誌）: 0366-7022
• 本文の言語コード: eng
• DOI: 10.1246/cl.160427; https://doi.org/10.1246/cl.160427
• 国立国会図書館永続的識別子: info:ndljp/pid/11459678; https://dl.ndl.go.jp/pid/11459678
• コレクション（共通）: 障害者向け資料
• コレクション（障害者向け資料：レベル1）: テキストデータ
• コレクション（個別）: 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会; https://dl.ndl.go.jp/collections/B00043
• 収集根拠: オンライン資料収集制度
• 受理日（W3CDTF）: 2020-03-13T20:40:24+09:00
• 保存日（W3CDTF）: 2020-03-13
• 記録形式（IMT）: application/pdf
• オンライン閲覧公開範囲: 国立国会図書館内限定公開
• デジタル化資料送信: 図書館・個人送信対象外
• 遠隔複写可否（NDL）: 可
• 掲載誌（URI）: https://www.journal.csj.jp/toc/cl/45/8
• 掲載誌（国立国会図書館永続的識別子）: info:ndljp/pid/11459665; https://dl.ndl.go.jp/pid/11459665
• 連携機関・データベース: 国立国会図書館 : 国立国会図書館デジタルコレクション; https://dl.ndl.go.jp

• 要約等: An electrophilic 5-<i>endo</i>-<i>trig</i> cyclization of β,β-difluoro-<i>o</i>-sulfonamidostyrenes was performed in 1,1,1,3,3,3-hexafluoropropan-2-ol using a Ag(I) catalyst and <i>N</i>,<i>O</i>-bis(trimethylsilyl)acetamide. In this process, vinylic C–F bond activation was achieved via silver-catalyzed β-fluorine elimination, accompanied by C–N bond formation, which led to the synthesis of 2-fluoroindoles.
• DOI: 10.1246/cl.160427
• オンライン閲覧公開範囲: インターネット公開
• 連携機関・データベース: 科学技術振興機構 : J-STAGE; http://www.jstage.jst.go.jp

• 要約等: An electrophilic 5-<i>endo</i>-<i>trig</i> cyclization of β,β-difluoro-<i>o</i>-sulfonamidostyrenes was performed in 1,1,1,3,3,3-hexafluoropropan-2-ol using a Ag(I) catalyst and <i>N</i>,<i>O</i>-bis(trimethylsilyl)acetamide. In this process, vinylic C–F bond activation was achieved via silver-catalyzed β-fluorine elimination, accompanied by C–N bond formation, which led to the synthesis of 2-fluoroindoles.
• DOI: 10.1246/cl.160427; https://doi.org/10.1246/cl.160427
• 関連情報（URI）: http://id.ndl.go.jp/digimeta/11459678; https://dl.ndl.go.jp/pid/11459678; https://www.journal.csj.jp/doi/pdf/10.1246/cl.160427
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• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
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• 書誌ID（NDLBibID）: 11459678; http://id.ndl.go.jp/bib/11459678
• NII論文ID: 130005254491