Synthesis of an organometallic alkyl-Co(Ⅲ) complex with amidoquinoline directing groups via C(sp3)-H activation and its UV-vis/NMR spectroscopic, crystallographic, DFT, and electrochemical studies
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- 資料種別
- 記事
- 著者・編者
- Keishiro TaharaShun TakezakiYoshiki Ozawa
- 出版年月日等
- 2022-01-28
- 出版年（W3CDTF）
- 2022-01-28
- タイトル（掲載誌）
- Bulletin of the Chemical Society of Japan
- 巻号年月日等（掲載誌）
- 95(3)
- 掲載巻
- 95(3)
- ISSN（掲載誌）
- 1348-0634
- ISSN-L（掲載誌）
- 0009-2673
- 本文の言語コード
- eng
- DOI
- 10.1246/bcsj.20210425
- 国立国会図書館永続的識別子
- info:ndljp/pid/12686421
- コレクション（共通）
- コレクション（障害者向け資料：レベル1）
- コレクション（個別）
- 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- 収集根拠
- オンライン資料収集制度
- 受理日（W3CDTF）
- 2023-03-07T17:43:09+09:00
- 保存日（W3CDTF）
- 2023-01-20
- 記録形式（IMT）
- application/pdf
- オンライン閲覧公開範囲
- 国立国会図書館内限定公開
- デジタル化資料送信
- 図書館・個人送信対象外
- 遠隔複写可否（NDL）
- 可
- 掲載誌（国立国会図書館永続的識別子）
- info:ndljp/pid/12686420
- 連携機関・データベース
- 国立国会図書館 : 国立国会図書館デジタルコレクション
- 要約等
- コレクション : 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- DOI
- 10.1246/bcsj.20210425
- オンライン閲覧公開範囲
- インターネット公開
- 関連情報
- CCDC 2116425: Experimental Crystal Structure Determination
- 関連情報（URI）
- 参照
- (Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and SelectivityPalladium-Catalyzed ortho-Selective C–H Chlorination of Benzamide Derivatives under Anodic Oxidation ConditionsPyrroloindolone Synthesis via a Cp*Co<sup>III</sup>-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation SequenceRedox Behavior of Simple Vitamin B12 Model Complexes with Cobalt–Carbon Bonds and Catalytic Carbon-Skeleton RearrangementsSteric Effect of Carboxylate Ligands on Pd‐Catalyzed Intramolecular C(sp<sup>2</sup>)–H and C(sp<sup>3</sup>)–H Arylation ReactionsCobalt(II)-catalyzed C H functionalization using an N,N′-bidentate directing groupMaking Carbon–Chlorine Bonds by Dipalladium ElectrocatalysisRecent developments in the field of organometallic derivatives of cobalt chelatesWeakly Coordinated Cobaltacycles: Trapping Catalytically Competent Intermediates in Cp*Co<sup>III</sup>CatalysisDehydrogenative (Hetero)arene Alkoxylations Triggered by Pd<sup>II</sup>‐Catalyzed C(sp<sup>2</sup>)–H Activation and Coordinating Substituent: Pd<sup>II,III</sup> or Pd<sup>IV</sup> Complex as Key Intermediate?The crystal and molecular structure of N,N′-ethylene- bis-(acetylacetoneiminato)methylcobalt(III)One-pot, solvent-free Pd(II)-catalyzed direct β-C-H arylation of carboxamides involving anhydrides as substrates via in situ installation of directing groupChemistry of Constrained Dioxocyclam Ligands with Co(III): Unusual Examples of C−H and C−N Bond CleavageCobalt‐Catalyzed Cross‐Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl HalidesInsights into Cobalta(III/IV/II)‐Electrocatalysis: Oxidation‐Induced Reductive Elimination for Twofold C−H ActivationFacile C−H Bond Activation: Synthesis of the N<sub>4</sub>C Donor Set Pentadentate Ligand 1,4-Bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a Structural Study of Its Alkyl−Cobalt(III) Complex [Co(dmpdacn-<i>C</i>)(OH<sub>2</sub>)](ClO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O and Its Hydroxylated Derivative [Co(dmpdacnOH-<i>O</i>)Cl](ClO<sub>4</sub>)<sub>2</sub>·C<sub>3</sub>H<sub>6</sub>OUnravelling Molecular Aspects of the Migratory Insertion Step in Cp*Co<sup>III</sup> Metallacyclic SystemsConcerted aryl-sulfur reductive elimination from PNP pincer-supported Co(<scp>iii</scp>) and subsequent Co(<scp>i</scp>)/Co(<scp>iii</scp>) comproportionationThe Influence of the Ligand in the Iridium Mediated Electrocatalyic Water OxidationPalladium-Catalyzed β-C(sp<sup>3</sup>)–H Nitrooxylation of Ketones and Amides Using Practical OxidantsPalladium‐Catalyzed C−H Iodination of <i>N</i>‐(8‐Quinolinyl)benzamide Derivatives Under Electrochemical and Non‐Electrochemical ConditionsNoninnocent Ligand in Rhodium(III)-Complex-Catalyzed C–H Bond Amination with Tosyl AzideCobalt(<scp>ii</scp>)-catalyzed chelation-assisted C–H iodination of aromatic amides with I<sub>2</sub>Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp<sup>2</sup>)–H Bond FunctionalizationPalladium-Catalyzed Transformations of Alkyl C–H BondsIsolation of Key Organometallic Aryl-Co(III) Intermediates in Cobalt-Catalyzed C(sp<sup>2</sup>)–H Functionalizations and New Insights into Alkyne Annulation Reaction MechanismsC−C, C−O, C−N Bond Formation on sp<i><sup>2</sup></i> Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant AgentsCobalt-Catalyzed Electrochemical Oxidative C–H/N–H Carbonylation with Hydrogen EvolutionCobalt-Catalyzed Cyclization of Aliphatic Amides and Terminal Alkynes with Silver-CocatalystTridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene HydrofunctionalizationCp*Co(III)-Catalyzed C(sp<sup>3</sup>)–H Bond Activation: A Highly Stereoselective and Regioselective Alkenylation of 8-Methylquinoline with AlkynesEnabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic ApplicationsCobalt-Catalyzed Intramolecular Oxidative C(sp<sup>3</sup>)–H/N–H Carbonylation of Aliphatic AmidesOxidatively Induced Reductive Eliminations. A Mechanistic Study of the Oxidation Chemistry of CnRhMe<sub>3</sub> (Cn = 1,4,7-Trimethyl-1,4,7-triazacyclononane)The Reversible and Stereoselective N- to C-bonded Rearrangement of Tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III)Synthesis and Reactivity of Stable Alkyl-Pd(IV) Complexes Relevant to Monodentate <i>N</i>-Directed C(sp<sup>3</sup>)–H Functionalization ProcessesCobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium ArylboratesVersatile Cp*Co(III)(LX) Catalyst System for Selective Intramolecular C–H Amidation ReactionsA New Family of Low‐Spin Co<sup>III</sup> Bis(amidate) Complexes with Two <i>cis</i> or <i>trans</i> CyanidesControlling Coordination Number of Rhodium(III) Complex by Ligand-Based Redox for Catalytic C–H AminationBioinspired catalytic reactions with vitamin B12 derivative and photosensitizersDensity-functional thermochemistry. III. The role of exact exchangeSynthesis, X-ray structure, and theoretical studies of novel cationic mono-cyclopentadienyl complexes of Co(III): the orthometalation of trans-azobenzeneMixed Directing‐Group Strategy: Oxidative C−H/C−H Bond Arylation of Unactivated Arenes by Cobalt CatalysisElectrooxidative Allene Annulations by Mild Cobalt-Catalyzed C–H ActivationExperimental and Computational Studies on Remote γ-C(sp<sup>3</sup>)–H Silylation and Germanylation of Aliphatic CarboxamidesCarboxylate-Assisted Formation of Aryl-Co(III) Masked-Carbenes in Cobalt-Catalyzed C–H Functionalization with Diazo EstersSynthesis of (POCOP)Co(Ph)(X) Pincer Complexes and Observation of Aryl–Aryl Reductive Elimination Involving the Pincer ArylMechanistic Considerations for C–C Bond Reductive Coupling at a Cobalt(III) CenterRedefining the Mechanistic Scenario of Carbon−Sulfur Nucleophilic Coupling via High‐Valent Cp*Co<sup>IV</sup> SpeciesRegioselective β-Csp<sup>3</sup>-Arylation of β-Alanine: An Approach for the Exclusive Synthesis of Diverse β-Aryl-β-amino AcidsRedox Potentials of Cobalt Corrinoids with Axial Ligands Correlate with Heterolytic Co–C Bond Dissociation EnergiesEnantioselective C(sp<sup>3</sup>)–H Amidation of Thioamides Catalyzed by a Cobalt<sup>III</sup>/Chiral Carboxylic Acid Hybrid SystemHemoproteins Reconstituted with Artificial Metal Complexes as Biohybrid CatalystsLearning from B<sub>12</sub> enzymes: biomimetic and bioinspired catalysts for eco-friendly organic synthesisPalladium-catalyzed C–H activation/C–C cross-coupling reactions via electrochemistry<i>Ab initio</i> effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to HgContribution of Electrochemistry to Organometallic CatalysisPlatinum-Catalyzed C–H FunctionalizationElectrochemical Ortho Functionalization of 2-Phenylpyridine with Perfluorocarboxylic Acids Catalyzed by Palladium in Higher Oxidation StatesCross-dehydrogenative coupling for the intermolecular C–O bond formationCobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp3 carbonsMolecular Catalysis of Electrochemical Reactions. Mechanistic AspectsTransition metal-catalyzed sp<sup>3</sup> C–H activation and intramolecular C–N coupling to construct nitrogen heterocyclic scaffoldsCobalt-Catalyzed Intermolecular C–H Amidation of Unactivated AlkanesMechanistic insights into the S<sub>N</sub>2-type reactivity of aryl-Co(<scp>iii</scp>) masked-carbenes for C–C bond forming transformationsRecent advances in cobalt-catalysed C–H functionalizationsCurrent Mechanistic Understanding of Cobalt-Catalyzed C–H FunctionalizationIridium-catalysed arylation of C–H bonds enabled by oxidatively induced reductive eliminationCobalt catalyzed carbonylation of unactivated C(sp<sup>3</sup>)–H bondsCobalt-catalysed C–H carbonylative cyclisation of aliphatic amidesDetailed Mechanistic Studies on Palladium-Catalyzed Selective C–H Olefination with Aliphatic Alkenes: A Significant Influence of Proton ShuttlingCoenzyme B12 model studies: an electrochemical comparison of both alkylcobaloxime and nonalkyl cobaloxime and Co[C2(DO)(DOH)pn] complexes to coenzyme B12Recent Advances in C–H Functionalization Using Electrochemical Transition Metal CatalysisFlow Rhodaelectro-Catalyzed Alkyne Annulations by Versatile C–H Activation: Mechanistic Support for Rhodium(III/IV)Evaluation of Solvent Effects in Isotropic and Anisotropic Dielectrics and in Ionic Solutions with a Unified Integral Equation Method: Theoretical Bases, Computational Implementation, and Numerical ApplicationsPalladium catalyzed CH functionalization with electrochemical oxidationPalladium-Catalyzed C(sp<sup>3</sup>)—H Oxygenation via Electrochemical Oxidation3d Transition Metals for C–H ActivationOrganocobalt chemistry of vitamin B12 model compounds (cobaloximes)Thioamide‐Directed Cobalt(III)‐Catalyzed Selective Amidation of C(sp<sup>3</sup>)−H BondsC–H functionalization by high-valent Cp*Co(<scp>iii</scp>) catalysisManifestations of Noninnocent Ligand BehaviorCobalt-Promoted Dimerization of Aminoquinoline BenzamidesOxygenation and oxidative coupling processes of alkyl ligands of cis-dialkylcobalt(III) complexes with dioxygen catalyzed by coenzyme analogs in the presence of perchloric acidImidate as the Intact Directing Group for the Cobalt-Catalyzed C–H AllylationRedox-Induced Aromatic C–H Bond Functionalization in Metal Complex Catalysis from the Electrochemical Point of ViewSwitch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic OlefinsScalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive EliminationSynthetic Organic Electrochemical Methods Since 2000: On the Verge of a RenaissanceThe influence of polarization functions on molecular orbital hydrogenation energiesQuantum Mechanical Continuum Solvation ModelsRedox trends in cyclometalated palladium(<scp>ii</scp>) complexesElectrochemical Cobalt-Catalyzed C–H Oxygenation at Room TemperatureCobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyneLigand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff BasesOxidatively Induced Reductive Elimination: Exploring the Scope and Catalyst Systems with Ir, Rh, and Ru ComplexesCobalt(II)-Catalyzed Acyloxylation of C–H Bonds in Aromatic Amides with Carboxylic AcidsOrganocobalt Complexes as Sources of Carbon-Centered Radicals for Organic and Polymer ChemistriesPalladium-Catalyzed Electrochemical C–H Alkylation of ArenesStructural and Electronic Properties of Co-corrole, Co-corrin, and Co-porphyrinTandem Remote Csp<sup>3</sup>–H Activation/Csp<sup>3</sup>–Csp<sup>3</sup> Cleavage in Unstrained Aliphatic Chains Assisted by Palladium(II)Transition‐Metal‐Catalyzed Acyloxylation: Activation of C(sp<sup>2</sup>)–H and C(sp<sup>3</sup>)–H BondsAn Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl<sub>2</sub>]<sub>2</sub> (M = Rh, Ir)Palladium-Catalyzed C–H Bond Acetoxylation via Electrochemical OxidationAuxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp<sup>2</sup> and sp<sup>3</sup> Carbon−Hydrogen BondsCrystal structure refinement with<i>SHELXL</i>Pyridine-directed palladium-catalyzed electrochemical phosphonation of C(sp2)–H bondElectrochemical C−H/N−H Activation by Water‐Tolerant Cobalt Catalysis at Room TemperatureArtificial Metalloenzymes: Reaction Scope and Optimization StrategiesCarbon–Carbon Bond Formation in a Weak Ligand Field: Leveraging Open‐Shell First‐Row Transition‐Metal CatalystsRecent advances using [Cp*Co(CO)I<sub>2</sub>] catalysts as a powerful tool for C–H functionalisationIntramolecular carbon-hydrogen bond activation: preparation, structure, and properties of a unique cobalt(III) complex, K[Co(III)(dacoda)(SO3).cntdot.5H2O, containing a weak agostic interaction in aqueous solutionElectrocatalytic C–H ActivationCobalt-Catalyzed C–H ActivationElectron Transfer Mechanism of Organocobalt Porphyrins. Site of Electron Transfer, Migration of Organic Groups, and Cobalt−Carbon Bond Energies in Different Oxidation StatesPalladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsElectrochemical strategies for C–H functionalization and C–N bond formationMechanism of oxidative cleavage of organocobalt(III) macrocycles. Application of electrochemical techniques to irreversible electron-transfer processesElectron-Transfer Oxidation of Coenzyme B<sub>12</sub>Model Compounds and Facile Cleavage of the Cobalt(IV)−Carbon Bond via Charge-Transfer Complexes with Bases. A Negative Temperature Dependence of the RatesCo(II)-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Aryl C–H Bonds with Carboxylic AcidsElectroremovable Traceless Hydrazides for Cobalt-Catalyzed Electro-Oxidative C–H/N–H Activation with Internal AlkynesCobalt-Catalyzed Aryl−Sulfur Bond FormationPalladium-Catalyzed Aryl C−H Bonds Activation/Acetoxylation Utilizing a Bidentate SystemElectrochemical Arylation ReactionIntramolecular carbon-hydrogen bond activation in aqueous solution: preparation of a unique cobalt(III)-alkyl complex by deprotonation of an agostic intermediate. Crystal structure of [Co(III)(dacoda-C(2))(H2O)].cntdot.2H2OEfficient Cobalt‐Catalyzed Formation of Unsymmetrical Biaryl Compounds and Its Application in the Synthesis of a Sartan IntermediateDirect <i>ortho</i>‐Acyloxylation of Arenes and Alkenes by Cobalt CatalysisCobalt‐Catalyzed, Aminoquinoline‐Directed C(sp<sup>2</sup>)H Bond Alkenylation by AlkynesNickel, Cobalt and Palladium Catalysed C−H Functionalization of Un‐Activated C(sp<sup>3</sup>)−H Bond<i>WinGX</i>and<i>ORTEP for Windows</i>: an updateFull Selectivity Control in Cobalt(III)‐Catalyzed C−H Alkylations by Switching of the C−H Activation MechanismCp*Co<sup>III</sup>‐Catalyzed C(sp<sup>3</sup>)−H Bond Amidation of 8‐MethylquinolineRedox behavior of simple vitamin B12 model complexes and electrochemical catalysis of carbon-skeleton rearrangements.Electrochemical Catalytic Carbon-skeleton Rearrangement Mediated by Imine/Oxime-type B12 Model Complex
- 連携機関・データベース
- 国立情報学研究所 : CiNii Research
- 提供元機関・データベース
- 雑誌記事索引データベースCrossref科学研究費助成事業データベース
- 書誌ID（NDLBibID）
- 12686421