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Rotational Isomerism Involving Acetylene Carbon
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Rotational Isomerism Involving Acetylene Carbon
- 資料種別
- 記事
- 著者
- Shinji Toyota
- 出版者
- American Chemical Society (ACS)
- 出版年
- 2010-06-03
- 資料形態
- デジタル
- 掲載誌名
- Chemical Reviews 110 9
- 掲載ページ
- p.5398-5424
資料詳細
要約等：
- <jats:title>Abstract</jats:title><jats:p>Review: 277 refs.</jats:p>（提供元: CiNii Research）
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デジタル
- 資料種別
- 記事
- 著者標目
- 出版年月日等
- 2010-06-03
- 出版年（W3CDTF）
- 2010-06-03
- タイトル（掲載誌）
- Chemical Reviews
- 巻号年月日等（掲載誌）
- 110 9
- 掲載巻
- 110
- 掲載号
- 9
- 掲載ページ
- 5398-5424
- 掲載年月日（W3CDTF）
- 2010-06-03
- ISSN（掲載誌）
- 0009266509317597
- 出版事項（掲載誌）
- American Chemical Society (ACS)
- 対象利用者
- 一般
- 標準番号（その他）
- PMID : 20521837
- DOI
- 10.1021/cr100062810.1002/chin.201050273
- 作成日（W3CDTF）
- 2010-06-03
- 参照
- Electron-rich carbon nanorings as macrocyclic hosts for fullerenes.Chemistry of Anthracene–Acetylene Oligomers XX: Synthesis, Structures, and Self‐Association of Anthracene–Anthraquinone Cyclic Compounds with Ethynylene LinkersStructures and Conformational Analysis of 1,8-Bis(9-triptycylethynyl)anthracene and Its Derivatives as Prototypes of Molecular Spur GearsSubstituent-dependent reactivity in aldehyde transformations: 4-(phenylethynyl)benzaldehydes versus simple benzaldehydesSynthesis and structure of 1,4,5,8-tetraethynylnaphthalene derivativesBox-shaped Cyclic Oligoarenes: Synthesis and Structure of Anthracene-1,8-diyl Cyclic TetramersQuadruple and Sextuple Triptycene Gears in Macrocyclic FrameworksSynthesis and Evaluation of Charge Transport Property of Ethynylene‐Bridged Anthracene OligomersIntroduction of an Arylethynyl Group onto an Anthracene Bisimide Core for Molecular Design of New π-Conjugated CompoundsMolecular Propellers that Consist of Dehydrobenzo[14]annulene Blades1,8‐Diphenyl‐9,10‐Bis(arylethynyl)phenanthrenes: Synthesis, Distorted Structure, and Optical PropertiesTriple and Quadruple Triptycene Gears in Rigid Macrocyclic FrameworksSynthesis, Structures, and Complexation with Phenolic Guests of Acridone‐Incorporated Arylene–Ethynylene Macrocyclic CompoundsPalladium-Catalyzed Direct <i>ortho</i>-Alkynylation of Aromatic Carboxylic Acid DerivativesTetrakis(phenylethynyl)tetracene: A New π‐Extended Rubrene DerivativeTolanophane Revisited – Resolution and Racemization Mechanism of a Twisted Chiral Aromatic CompoundSynthesis, Structures, and Properties of Highly Strained Cyclophenylene–Ethynylenes with Axial and Helical ChiralityHow to Construct Chiral Macrocycles from Anthracene Units and Acetylene LinkersMacrocyclic 2,7‐Anthrylene OligomersSynthesis and Electronic Properties of Length-Defined 9,10-Anthrylene–Butadiynylene OligomersComposite Formation of Anthrylene- and Ferrocenoyl-Substituted Phenyleneethynylenes with Single-Wall Carbon Nanotubes (SWCNTs)Intramolecular benzoallene–alkyne cycloaddition initiated by site-selective S<sub>N</sub>2′ reaction of epoxytetracene en route to π-extended pyracyleneπ‐Conjugated Macrocycles Bearing Angle‐Strained AlkynesBiomimetic and Technomimetic Single Molecular Machinesエチニルアントラセン誘導体の効率合成とオリゴマー合成への応用Nanocars based on Polyaromatic or Porphyrinic ChassisChemistry of Anthracene-Acetylene Oligomers. XVIII. Construction and Structures of Belt-Shaped Macrocyclic Oligomers with Anthracene Units and Acetylene Linkers and Resolution of Chiral DerivativesSynthesis and Properties of Extended π-Conjugated Compounds with 9,10-Bis(phenylethynyl)anthracene Units
- 参照
- Rotational Isomerism Involving an Acetylenic Carbon: Synthesis of and Barrier to Rotation around C(sp)-C(sp3) Bonds in Bis(1,4-disubstituted 9-triptycyl)ethynesRotational Isomerism Involving an Acetylenic Carbon VII. Restricted Rotation about Acetylenic Axis in a Diphenylethyne Derivative with Sterically Crowded <i>m</i>-Terphenyl Moieties[2.0.2.0]Metacyclophane-1,15-diynes. A Potential Fragment of Double-Helical Conjugated SystemsSynthesis of Strained Pyridine-Containing Cyclyne via Reductive AromatizationIntramolecular Interactions Through Triple Bonds. Internal Rotation in Aminoborylpolyynes, NH<sub>2</sub>(C≡C)<sub>n</sub> BH<sub>2</sub>Synthesis of Novel Acetylenic Cyclophanes with Helical Chirality: Potential New Structures for Liquid CrystalsStructure, spectra and internal rotation of bis(trimethylsilyl) acetylene: spectral analysis by scaling quantum-chemical force fields and two methods for calculating vibrational effectsEffects of aryl and arylethynyl substituents at the 1-position on rotational barrier around C(sp)–C(sp3) bonds and bending deformation of acetylenic carbons in bis(9-triptycyl)ethynesThe Synthesis of a Novel Strained Diyneparacyclophane and Its Dimer by Metal-Mediated CouplingThe Usefulness of Phosphorus Compounds in Alkyne SynthesisBuilding molecular wires from the colours of life: conjugated porphyrin oligomersA metallocene molecular gearRolling a single molecular wheel at the atomic scaleAlkyne Metathesis: Catalysts and Synthetic ApplicationsPronounced conformational preferences in 1,4-disubstituted but-2-ynesRotational Isomerism Involving an Acetylenic Carbon II : Effect of 1-Halogen Substituents on Rotamer Population and Rotational Barrier around C(sp)-C(sp3) Bonds in Bis(9-triptycyl)ethynesChemistry of Anthracene–Acetylene Oligomers. II. Synthesis, Structure, and Properties of 1,8-Anthrylene–Ethynylene Cyclic Tetramers and Related Acyclic OligomersRotational Isomerism Involving an Acetylenic Carbon VI. Syntheses, Structures, and Dynamic Stereochemistry of Bis(1-phenyl-9-anthryl)ethynes: Highly Restricted Rotation about Acetylenic Axis in Acyclic DiarylethynesInfluence of Conformation of 9,10-Anthrylene Rotors on Structures and Self-association Properties of Macrocyclic Arylene–Alkynylene OligomersMolecular Dynamics of Covalently-Linked Multi-porphyrin ArraysBackbone-Rigidified Oligo(<i>m</i>-phenylene ethynylenes)High-resolution infrared spectra of ethanelike molecules and the barrier to internal rotation: The ν9, ν13 band of dimethylacetyleneSynthesis of extended polyynes: Toward carbyneSelf-assembly of a hexagonal supramolecular light-harvesting array from chlorophyll a trefoil building blocksEvaluation of fluorescent materials for colour control of peroxylate chemiluminescence. IV. Fluorescence quantum yields of some phenyl and phenylethynyl aromatic compoundsSurface-Rolling MoleculesPolarized Electronic Spectroscopy and Photophysical Properties of 9,10-Bis(phenylethynyl)anthraceneTheoretical Analysis of the Rotational Barrier of EthaneA reinvestigation of tolaneA Molecular BrakeSyntheses of Acetylenic Oligophenylene Macrocycles Based on a Novel Dewar Benzene Building Block ApproachThe design of a nanoscale molecular barrowMolecular WiresDirectional Control in Thermally Driven Single-Molecule NanocarsThe Sonogashira Reaction: A Booming Methodology in Synthetic Organic ChemistryTheoretical Investigations on the Geometric and Electronic Structures of Phenylene‐Acetylene MacrocyclesSynthesis of Single-Molecule NanocarsDouble elimination protocol for aryleneethynylenesImproved Physical Properties and Rotational Dynamics in a Molecular Gyroscope with an Asymmetric Stator StructureEn Route to a Motorized NanocarConformational and Electronic Engineering of Twisted DiphenylacetylenesConformational Ordering of Apolar, Chiral <i>m</i>-Phenylene Ethynylene OligomersChemistry of Anthracene–Acetylene Oligomers XV. Synthesis, Structures, and Dynamic Behavior of Chiral Anthrylene–Ethynylene Cyclic Tetramers and Related Derivatives and Resolution of EnantiomersChemistry of Anthracene–Acetylene Oligomers. XIII. Synthesis, Structures, and Spectroscopic Properties of All Possible 1,8-Anthrylene Cyclic Tetramers with Acetylene and Diacetylene LinkersEnantiopure Anthrylene−Ethynylene Cyclic Tetramer and Racemization via Rotation of Anthracene Unit about Acetylenic Axes<sup>1</sup>Ab initio molecular orbital calculations of the internal rotational potential of biphenyl using polarized basis sets with electron correlation correctionEngineering a twist in 9,10-diethynylanthracenes by steric interactionsSynthesis of a Porphyrin-Fullerene PinwheelMolecular orbital theory of the electronic structure of organic compounds. IV. Internal rotation in hydrocarbons using a minimal Slater-type basisAn Electrostatic Theory of the Potential Barriers Hindering Rotation around Single BondsInternal rotation in diarylalkynesConformational analysis of diphenylacetylene under the influence of an external electric fieldThe rotational barrier in dimethyl acetylene and related moleculesEvidence for Solution-State Nonlinearity of sp-Carbon Chains Based on IR and Raman Spectroscopy: Violation of Mutual ExclusionBasic terminology of stereochemistry (IUPAC Recommendations 1996)Vibrational assignment of 1,4-diphenylbutadiyneCrystalline Molecular Machines: A Quest Toward Solid-State Dynamics and FunctionComplexation of carbon nanorings with fullerenesCooperative Ratiometric Chemosensors: Pinwheel Receptors with an Integrated Fluorescence SystemApolar ortho-phenylene ethynylene oligomers: conformational ordering without intermolecular aggregationSynthesis of the end-capped 5-(N,N-dimethylamino)naphthyl-1-ethynyl derivatives and their 1,4-di[5-(N,N-dimethylamino)naphthyl]-1,3-butadiynes: anti rotamer structureChemistry of Anthracene–Acetylene Oligomers. X. Synthesis, Structures, and Properties of 1,8-Anthrylene–Alkynylene Cyclic TrimersMicrowave spectrum of tetrolyl fluorideExperimental and theoretical investigations of absolute stereochemistry and chiroptical properties of enantiopure 2,2′-substituted 9,9′-bianthrylsSynthesis and properties of medium-sized (C9-C12) carbocyclic diacetylenesArtificial Molecular RotorsA joint theoretical and experimental study of phenylene–acetylene molecular wiresThe Role of Porphyrin‐to‐Porphyrin Linkage Topology in the Extensive Modulation of the Absorptive and Emissive Properties of a Series of Ethynyl‐ and Butadiynyl‐Bridged Bis‐ and Tris(porphinato)zinc ChromophoresFoldamer-Based Molecular RecognitionMD‐Simulation of Site Geometries and Photoinduced Site Interconversion of Diphenylacetylene (Tolan) in an Argon MatrixA Helicene-Containing Foldamer Displaying Highly Solvent-Dependent CD SpectraCommunication between Porphyrin Rings in the Butadiyne-Bridged Dimer Ni(OEP)(μ-C<sub>4</sub>)Ni(OEP): A Density Functional StudyAlkenylidenes in Organic SynthesisSynthesis and Ring Size Effect of Macrocyclic Ethynylhelicene OligomersSynthesis of a Triply-Bridged Molecular Gyroscope by a Directed Meridional Cyclization StrategySynthesis and fluorescence properties of 9,10-bis(phenylethynyl)anthracencesSynthesis, Crystal Structure, and Explosive Decomposition of 1,2:5,6:11,12:15,16- Tetrabenzo-3,7,9,13,17,19-hexadehydro[20]annulene: Formation of Onion- and Tube-like Closed-Shell Carbon ParticlesHelical Twist Sense Bias in Oligo(phenylene ethynylene)s Induced by an Optically Active Flexible TetherA Butane Analogue, 3-Hexyne, Is EclipsedTime-resolved resonance Raman spectroscopy of diphenylacetylene: structures and dynamics of the lowest excited triplet state, radical cation, and radical anionThermally induced resolution of racemic 1,1'-binaphthyl in the solid stateEn Route to Surface-Bound Electric Field-Driven Molecular MotorsThe Substituted Alkyne 3-Heptyne is EclipsedRapid Construction of Large‐size Phenylacetylene Dendrimers up to 12.5 Nanometers in Molecular DiameterSynthetic Routes toward Carborane-Wheeled NanocarsProgress toward a Rationally Designed Molecular MotorIptycenes in the Design of High Performance PolymersThe methyl group rotation barrier of dimethylacetylene in the solid state at 4.5 KRenaissance of Annulene ChemistryMolecular “Compasses” and “Gyroscopes.” III. Dynamics of a Phenylene Rotor and Clathrated Benzene in a Slipping-Gear Crystal LatticeConjugated porphyrin oligomers from monomer to hexamerThe Perpendicular C–H Stretching Band ν9/ν13and the Torsional Potential of DimethylacetyleneCooperative Self-Assembly of Oligo(<i>m</i>-phenyleneethynylenes) into Supramolecular Coordination PolymersInternal Rotation in Dimethyl AcetylenePoly(arylene etynylene)sSynthesis and Characterization of a High Molecular Weight Stiff DendrimerMethyl group tunnelling and torsion in 2,4-hexadiyneFunctionalized oligoarylenes as building blocks for new organic materialsElectronic spectra of matrix-isolated tolan: site selective one- and two-photon spectraTwo approaches to the computational determination of molecular structure: the torsional angle in tolane and the effect of fluorination on the structure of oxiraneLadderlike Ferromagnetic Spin Coupling Network on a π-Conjugated Pendant PolyradicalSynthesis of a Nanocar with an Angled Chassis. Toward Circling MovementImportance of Correlated Motions on the Low Barrier Rotational Potentials of Crystalline Molecular GyroscopesDescription of steric relationships across single bondsMicrowave spectrum and barrier to internal rotation of 1-chloro-2-butyneSolvophobically Driven Folding of Nonbiological OligomersMicrowave spectroscopy and structures of two conformers of 6-methyl-3-heptyne and three of 2-methylpentaneRevolveneynes: Novel eneyneparacyclophanes by sequential palladium couplingStructural, Vibrational, and Electronic Characteristics of Enyne Macrocycles as a Function of Ring Strain2,2'-Dicarbomethoxy-9,9'-bitriptycyl. Synthesis, conformational stability, and separation and identification of the conformersThe Chemistry of Rotational IsomersMolecular mechanics calculations (MM3) on nitriles and alkynesHindered Rotation at the Triple BondMacrocyclic 1,8‐Anthrylene–Ethynylene Oligomers: Three‐Dimensional π‐Conjugated ArchitecturesEngineering Crystal Packing and Internal Dynamics in Molecular Gyroscopes by Refining their Components. Fast Exchange of a Phenylene Rotator by <sup>2</sup>H NMRShape-Persistent Molecular Architectures of Nanoscale DimensionLattice dynamics and methyl rotational excitations of 2-butyneSynthesis, Structure, and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M', and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CLi) and (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CC.tplbond.CLi)Molecular Machinery: Synthesis of a “Nanodragster”Intramolekulare Wechselwirkungen zwischen Dreifachbindungen, XI. 9.10.19.20‐Tetradehydro‐tetrabenzo[<i>a.c.g.i</i>]cyclododecen, ein makrocyclisches Diacetylen mit gekreuzten DreifachbindungenSolvophobically Driven π-Stacking of Phenylene Ethynylene Macrocycles and OligomersLibrational motions in dimethylacetylene studied by inelastic neutron scatteringRotational isomerism involving an acetylenic carbon<scp>iv</scp>: synthesis and structure of bis(1,1′;3′,1″-terphenyl-2′-yl)ethynes: molecular design of sterically congested alkynes toward restricted rotation about acetylenic axis.The Entropy of Dimethyl Acetylene from Low Temperature Calorimetric Measurements. Free Rotation in the Dimethyl Acetylene MoleculeThe <i>Ab initio</i> crystal-structure determination of perdeuterodimethylacetylene by high-resolution neutron powder diffractionStereochemical consequences of dynamic gearingMolecular Compasses and Gyroscopes: Engineering Molecular Crystals with Fast Internal RotationCrystal structure of 5,6-didehydrodibenzo[a,e]cyclo-octeneCarbo-mers: from skeleton to functionChirally Twisted Oligo(phenyleneethynylene) by Cyclization with α-Helical PeptideCarbon‐Rich CompoundsThe Bestmann - Ohira Reagent for the Conversion of Aldehydes into Terminal AlkynesRole of Triple Bond in 1,2-Diphenylacetylene Crystal: A Combined Experimental and Theoretical StudySynthesis and solid-state dynamics of molecular dirotors2-Amino-2′-carboxydiphenylacetylenes as β-turn mimetics. synthesis and conformational propertiesIntramolekulare Wechselwirkungen zwischen Dreifachbindungen, XV. Kristall‐ und Molekularstruktur von 9,10,19,20‐Tetradehydro‐tetrabenzo[<i>a,c</i>]cyclododecen mit Benzol als AdduktSelectivity via Cooperative Interactions: Detection of Dicarboxylates in Water by a Pinwheel ChemosensorOrbital phase control of conformations of alkyne derivativesMicrowave Spectrum and Internal Rotation of 1-Chloro-2-ButyneInternal rotation in dimethyl acetyleneUnusual fluorescene emission from ethynyltriphenylene-substituted diacetylenic molecular hinge. Formation of intramolecular excimerThe Synthesis and Physicochemical and Supramolecular Properties of Strained Phenylacetylene MacrocyclesFolding a Conjugated Chain: Oligo(<i>o</i>-phenyleneethynylene-<i>alt</i>-<i>p</i>-phenyleneethynylene)Probing Electronic Communication in Covalently Linked Multiporphyrin Arrays. A Guide to the Rational Design of Molecular Photonic DevicesMolecular Folding of C60 Acetylenic Cyclophanes: π-Stacking of Superimposed Aromatic RingsTorsional analysis of 2-butynolTemplate-Directed Synthesis of Helical Phenanthroline CyclophanesMolecular Crystals with Moving Parts: Synthesis, Characterization, and Crystal Packing of Molecular Gyroscopes with Methyl-Substituted Triptycyl FramesSynthesis and self-assembly of propeller-shaped amphiphilic moleculesCooperative Chemical Sensing with Bis-tritylacetylenes: Pinwheel Receptors with Metal Ion Recognition PropertiesRotational isomerism involving an acetylenic carbon. Part 5: Restricted rotation about acetylenic axis in sterically crowded bis(1-phenyl-9-anthryl)ethynesSynthesis and Properties of [2.2]Paracyclophane-Layered PolymersFrom Macrocyclic Oligo-acetylenes to Aromatic Ring <i>Carbo</i>-mersPrecursors to Endohedral Metal Fullerene Complexes: Synthesis and X-ray Structure of a Flexible Acetylenic Cyclophane C<sub>60</sub>H<sub>18</sub>Synthesis of a novel tweezers-type host aiming at chiral discrimination by circular dichroism spectroscopy †A Water-Soluble <i>m</i>-Phenylene Ethynylene FoldamerSupramolecular Organization of Foldable Phenylene Ethynylene OligomersCyclynes. Part 5. Pericyclynes: "exploded cycloalkanes" with unusual orbital interactions and conformational properties. MM2 and STO-3G calculations, x-ray crystal structures, photoelectron spectra, and electron transmission spectraThe influence of chain elongation on Karplus-type relationships: a DFT study of scalar coupling constants in polyacetylene derivativesDesign and synthesis of molecular turnstiles.Conformational Isomers from Rotation of Diacetylenic Bond in an Ethynylpyrene-Substituted Molecular HingeMolecular Compasses and Gyroscopes. II. Synthesis and Characterization of Molecular Rotors with Axially Substituted Bis[2-(9-triptycyl)ethynyl]arenesConjugated Porphyrin LaddersStructure and rotational isomerism of disubstituted acetylenes with OR, SR, CR=O, and CH = CH2 substituentsCoordination‐Driven Self‐Assembly, Structures, and Dynamic Properties of Diplatinum Hexatriynediyl and Butadiynediyl Complexes in which the sp Carbon Chains are Shielded by sp<sup>3</sup> Carbon Chains: Towards Endgroup–Endgroup InteractionsRecent progress on nanovehiclesMolecular “Compasses” and “Gyroscopes”. I. Expedient Synthesis and Solid State Dynamics of an Open Rotor with a Bis(triarylmethyl) FrameSynthesis and oxygen-catalysed racemization of 2,2′-bismethoxycarbonyl-9,9′-bianthrylElectronic spectra of tolan in a supersonic free jet: large-amplitude torsional motion[<i>N</i>]Chalcogena[<i>N</i>]pericyclynes: DFT Studies on Binaric Carbon−Chalcogen CompoundsSteric effects. A study of a rationally designed systemRational Monomer Design towards 2D Polymers: Synthesis of a Macrocycle with Three 1,8‐Anthrylene UnitsSynthesis and Properties of Trefoil-Shaped Tris(hexadehydrotribenzo[12]annulene) and Tris(tetradehydrotribenzo[12]annulene)Conformational structure of divinylacetyleneChemical Sensors Based on Amplifying Fluorescent Conjugated PolymersAlkyne-Linked 2,2-Disubstituted-indolin-3-one Oligomers as Extended β-Strand MimeticsTorsional Barriers and Equilibrium Angle of Biphenyl: Reconciling Theory with ExperimentInternal Rotation in Tolane: Molecular Structure in Gas and Crystal Phases.Oligo(<i>p</i>-phenyleneethynylene)s with Hydrogen-Bonded Coplanar ConformationMolecular machines: synthesis and characterization of two prototypes of molecular wheelbarrowsButatrienes as Extended Alkenes: Barriers to Internal Rotation and Substitution Effects on the Stabilities of the Ground States and Transition StatesPolyynes as a Model for Carbyne: Synthesis, Physical Properties, and Nonlinear Optical ResponseEngineering Control over the Conformation of the Alkyne−Aryl Bond by the Introduction of Cationic ChargeCavity Ring-Down Spectroscopy of the Torsional Motions of 1,4-Bis(phenylethynyl)benzeneEn route to diplatinum polyynediyl complexes trans,trans-(Ar)(R3P)2Pt(C≡C)nPt(PR3)2(Ar): Untold tales, including end-group strategiesCarbon−Carbon Rotational Barriers in Butane, 1-Butene, and 1,3-ButadieneCarbon Networks Based on 1,5-Naphthalene Units. Synthesis of 1,5-Naphthalene Nanostructures with Extended π-ConjugationAb initio study of geometries and force fields of diphenylacetylene in the ground state, radical cation, radical anion, and lowest excited triplet stateInteractions between Ordinary Vibrations and Hindered Internal Rotation. II. Theory of Internal Rotation Fine Structure in Some Perpendicular Bands of Ethane-Type MoleculesA Simple Model for Barriers to Internal RotationOrigin of Methyl Internal Rotation BarriersObservation of torsional motion in the ground-state cation of jet-cooled tolane by two-color threshold photoelectron spectroscopyA Functional Assay for Heparin in Serum Using a Designed Synthetic ReceptorAdjustable cavity for host–guest recognition in cofacial bis-porphyrinic tweezerMillimeter-wave spectrum and internal rotation of 1-silylpropyne, CH3CCSiH3The vibrational spectra of (CH3)3MCCCCM(CH3)3, with M = C, Si, Ge, or SnRotational Dynamics in a Crystalline Molecular Gyroscope by Variable-Temperature <sup>13</sup>C NMR, <sup>2</sup>H NMR, X-Ray Diffraction, and Force Field CalculationsAmphidynamic Crystals: Structural Blueprints for Molecular MachinesSolution <sup>1</sup>H NMR Confirmation of Folding in Short <i>o</i>-Phenylene Ethynylene OligomersHindered rotation in an “exploded” biphenylIntramolecular π-Stacking Interaction in a Rigid Molecular Hinge Substituted with 1-(Pyrenylethynyl) UnitsSynthesis and characterization of amphiphilic o-phenylene ethynylene oligomersSynthesis of a nanocar with organometallic wheelsStructure−Property Relationships of Donor/Acceptor-Functionalized Tetrakis(phenylethynyl)benzenes and Bis(dehydrobenzoannuleno)benzenesSelf-Assembled Trigonal Prismatic Altitudinal Rotors with Triptycene Paddle WheelsElimination Strategy for Aromatic AcetylenesOrganic Single‐Crystalline Ribbons of a Rigid “H”‐type Anthracene Derivative and High‐Performance, Short‐Channel Field‐Effect Transistors of Individual Micro/Nanometer‐Sized Ribbons Fabricated by an “Organic Ribbon Mask” TechniqueChain Length-Dependent Affinity of Helical Foldamers for a Rodlike Guest9,10-Ter-anthrylene-ethynylene: a new molecular architecture for solution processed anthracene-based thin film transistorsMicrowave spectrum and internal rotation of 2-butyne-1, 1, 1-<i>d</i>3 (dimethylacetylene), CH3C≡CCD3Crystal structure of 1,2 : 5,6 : 9,10 : 13,14 : 17,18 : 21,22 : 25,26 : 29,30 : 33,34 : 37,38 decabenzo-3,7,11,15,19,23,27,31,35,39-decadehydro[40]annulene (C80H40), a 40-membered macrocyclic ring and the synthesis and characterization of its 80-(C160H80), 120-(C240H120), 160-(C320H160) and 200-(C400H200) membered ring homologuesDendrimers and DendronsIntramolecular Rotation in a Porphyrin Dimer Controls Singlet Oxygen ProductionConjugated Polymers with Main Chain Chirality. 3. Synthesis of Optically Active Poly(aryleneethynylene)sFree internal rotation in CH3–CC–CF3Dimethylacetylene: Internal Rotation and the Analysis of the Methyl Rocking Infrared Fundamental BandSteps To Demarcate the Effects of Chromophore Aggregation and Planarization in Poly(phenyleneethynylene)s. 1. Rotationally Interrupted Conjugation in the Excited States of 1,4-Bis(phenylethynyl)benzeneSynthesis of Expanded Graphdiyne SubstructuresSyntheses and crystal structures of 1,2:5,6:9,10:13,14:17,18:21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene (HBC), 1,2:5,6:9,10:13,14-tetrabenzo-3,7,11,15-tetradehydro[16]annulene (QBC) and a tetracobalt complex of QBC. The first example of a transition metal complex of QBCTheoretical Interpretation of Conductivity Measurements of a Thiotolane Sandwich. A Molecular Scale Electronic ControllerA Versatile Bis‐Porphyrin Tweezer Host for the Assembly of Noncovalent Photoactive Architectures: A Photophysical Characterization of the Tweezers and Their Association with Porphyrins and Other GuestsSynthesis of Highly Fluorescent BODIPY-Based NanocarsMolecular Structures of Related Compounds of Mesogens Studied by <sup>1</sup>H NMR Using a Liquid Crystal Solvent: Tolan and <i>trans</i>-AzobenzeneTwistophane Macrocycles with Integrated 6,6′-Connected-2,2′-Bipyridine Units: A New Lead Class of Fluorescence Sensors for Metal IonsSynthesis and magnetic characterization of monodisperse oligo(9,10-anthryleneethynylene)-based polyradicals with two pendant stable phenoxyls in one anthracene skeletonSynthesis and absorption/emission spectroscopic properties of bis(phenylethynyl)benzenes and 9,10-bis(phenylethynyl)anthracenesTriplet Energy Transfer in Porphyrin Dimers: Comparison between π- and σ-Chromophore Bridged Systems<sup>1</sup>H nuclear magnetic resonance and molecular orbital estimates of the internal rotational barrier in phenylpropynal in solution and in the vaporFar-Ir Spectrum of Dimethylacetylene: Internal Rotation and Evidence for a <i>D</i>6<i>h</i> Effective SymmetryOn the Possibility of Free Rotation in Crystalline DimethylacetyleneNon-centrosymmetry in organic crystals: a study of molecular conformation in some substituted tolansInternal rotation in halogen derivatives of tolane X5C6CCC6X5 determined by molecular mechanics calculationsA new strategy for folding oligo(m-phenylene ethynylenes)Electronic supplementary information available: experimental data. See http://www.rsc.org/suppdata/cc/b2/b209809a/Hindered Rotation III. The Qualitative Nature of the Interactions HIndering Internal RotationAltitudinal Surface-Mounted Molecular RotorsThe vibrational spectra of 2,4-hexadiyne (dimethyldiacetylene), 2,4-hexadiyne-d6 and 2,4-hexadiyne-1,1,1-d3
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- 連携機関・データベース
- 国立情報学研究所 : CiNii Research
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