BDPA ラジカルを用いた動的核偏極における溶媒効果

Material type: 文書・図像類

Author: 藤井, 裕ほか

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Publication date: 2009-06

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Note (General)：: In order to investigate the experimental technique and the high magnetic field effect in the dynamical nuclear polarization (DNP) experiments, the X-b...

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Material Type: 文書・図像類
Title: BDPA ラジカルを用いた動的核偏極における溶媒効果
Author/Editor: 藤井, 裕
南, 修平
光藤, 誠太郎
石黒, 佑介
神戸, 高志
Author Heading: 藤井, 裕
南, 修平
光藤, 誠太郎
石黒, 佑介
神戸, 高志
Publication Date: 2009-06
Publication Date (W3CDTF): 2009-06
Alternative Title: DNP experiments on BDPA-doped solutions with different organic solvents
Periodical title: 遠赤外領域開発研究
No. or year of volume/issue: 10
Volume: 10
Pages: 87-99
Text Language Code: jpn
Target Audience: 一般
Note (General): In order to investigate the experimental technique and the high magnetic field effect in the dynamical nuclear polarization (DNP) experiments, the X-band 1H-DNP experiments have been performed on a organic solution of a,y-bisdiphenylene-β-phyenylallyl (BDPA) radical at room temperature. Because BDPA-doped toluene solution evaporated immediately during sub-THz irradiation, we tried DNP experiments with changing the solvent from toluene to benzene. As a result, we obtained similar DNP effects on the two solutions. We can expect that benzene solution is an appropriate sample for sub-THz DNP experiments. Further, we performed pulse-ESR experiments in order to measure electron relaxation times. We discuss the power dependence of DNP enhancement with measured relaxation times.
Source: https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=27303&item_no=1&attribute_id=22&file_no=1
https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=27303&item_no=1&attribute_id=22&file_no=1
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ