キレート能を有する高分子の精密合成と金属補集体

Material type: 文書・図像類

Author: 杉原, 伸治ほか

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Publication date: 2008-09-30

Material Format: Digital

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Note (General)：: As one of the functional polymers, we focused the vinyl ether carrying β-fdicarbonyl moieties which are known to act as strong bidentate ligands, capa...

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Material Type: 文書・図像類
Title: キレート能を有する高分子の精密合成と金属補集体
Author/Editor: 杉原, 伸治
上田, 容子
笈田, 智幸
池田, 功夫
Author Heading: 杉原, 伸治
上田, 容子
笈田, 智幸
池田, 功夫
Publication Date: 2008-09-30
Publication Date (W3CDTF): 2008-09-30
Alternative Title: Precision Synthesis of Polymers with Chelating Moiety and Their Assembly
Periodical title: 福井大学大学院工学研究科附属繊維工業研究センター年報
No. or year of volume/issue: 1
Volume: 1
Pages: 33-37
Text Language Code: jpn
Subject Heading: Cationic polymerization
Living polymerization
Chelating agent
Metal ligand
Metal scavenger
Vinyl ether
Target Audience: 一般
Note (General): As one of the functional polymers, we focused the vinyl ether carrying β-fdicarbonyl moieties which are known to act as strong bidentate ligands, capable of coordinating various metal ions. The repeating unit is 2- (acetoacetoxy)ethyl vinyl ether (MVE) synthesized from 2-hydoroxyethyl vinyl ether with tert-butyl acetoacetate. Althought the AAVE possess chelating moiety, poly(AAVE) was first synthesized via 2living2 cationic polymerization using BF3OEt2 in ethyi acetate. Metal complex and cross-linked compounds, that is star-shaped polymers with metal center, were prepared by the product including poly(AAVE) segments.
Source: https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=27729&item_no=1&attribute_id=22&file_no=1
https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=27729&item_no=1&attribute_id=22&file_no=1
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ