放射状6アミン化合物の酸化重合反応の低電位化と防錆機能

Material type: 文書・図像類

Author: 西海, 豊彦ほか

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Publication date: 2008-09-30

Material Format: Digital

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Note (General)：: N,N,N -tris [4-(phenylamino)-phenyl]-I,3,5-benzenetriamine (PAB), composed of six arylamines with a starburst type, was oxidized electrochemically to ...

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Material Type: 文書・図像類
Title: 放射状6アミン化合物の酸化重合反応の低電位化と防錆機能
Author/Editor: 西海, 豊彦
吉川, 雄一郎
MOTIN, Md.Abdul
青木, 幸一
Author Heading: 西海, 豊彦
吉川, 雄一郎
MOTIN, Md.Abdul
青木, 幸一
Publication Date: 2008-09-30
Publication Date (W3CDTF): 2008-09-30
Alternative Title: Low Potential of Starburst Six-arylamino Compounds Generating Conducting polymers and Its Corrosion Protection
Periodical title: 福井大学大学院工学研究科附属繊維工業研究センター年報
No. or year of volume/issue: 1
Volume: 1
Pages: 28-32
Text Language Code: jpn
Target Audience: 一般
Note (General): N,N,N -tris [4-(phenylamino)-phenyl]-I,3,5-benzenetriamine (PAB), composed of six arylamines with a starburst type, was oxidized electrochemically to yield an electrically conducting polymer film. The polymerization potential was lower than those of aniline and its derivatives. The lower shift was explained in terms of the redox interaction between the cation radical and the other arylamines through phenyl groups. The linear relation of the oxidation potential with the inverse of the number of redox sites was valid even for the starburst compounds. Tafel plot of the PAB cast film on the iron electrode reveled moderate corrosion protection function rivals polyaniline.
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ