PEG坦特型新規置換ポリアセチレンの合成と中空糸繊維の作製および二酸化炭素分離への応用

Material type: 文書・図像類

Author: 阪口, 壽一ほか

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Publication date: 2009-06-01

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Note (General)：: 4-Trimethylsilyldiphenylacetylenes with methyl group or bromine atom were polymerized with TaCI5/n-Bu4Sn to afford poly(diphenylacetylene) derivatives...

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Material Type: 文書・図像類
Title: PEG坦特型新規置換ポリアセチレンの合成と中空糸繊維の作製および二酸化炭素分離への応用
Author/Editor: 阪口, 壽一
亀岡, 浩二
橋本, 保
Author Heading: 阪口, 壽一
亀岡, 浩二
橋本, 保
Publication Date: 2009-06-01
Publication Date (W3CDTF): 2009-06-01
Alternative Title: Synthesis of novel poly(substituted acetylene)s with PEG, preparation of fellow fibers, and their application to separeation of carbon dioxide
Periodical title: 福井大学大学院工学研究科附属繊維工業研究センター年報
No. or year of volume/issue: 2
Volume: 2
Pages: 18-22
Text Language Code: jpn
Target Audience: 一般
Note (General): 4-Trimethylsilyldiphenylacetylenes with methyl group or bromine atom were polymerized with TaCI5/n-Bu4Sn to afford poly(diphenylacetylene) derivatives. The polymers had high molecular weight over 5xlO5, and gave free-standing membranes by a solution casting method. Chlorination of the obtained poly[1-(3-methylphenyl)-2-(4-trimethylsilyl)phenylacetylene] was carried out by using sulfuryl chloride, and then substitution of polyethylene glycol was performed to give poly(diphenylacetylene) possessing polyethylene glycol moieties. Its carbon dioxide permeability (PCO2) and permselectivity (PCO2/PN2) were 2,970 barrers and 9.O, respectively.
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ