Effect of mixing ratio of anionic and nonionic emulsifiers on the kinetic behavior of methyl methacrylate emulsion polymerization

Material type: 文書・図像類

Author: SUZUKI, Kiyoshiほか

Publisher: Elsevier Ltd

Publication date: 2005-07

Material Format: Digital

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Note (General)：: Emulsion polymerization of methyl methacrylate was carried out using a mixture of anionic emulsifier, sodium dodecyl sulfate (SDS) and nonionic emulsi...

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Material Type: 文書・図像類
Title: Effect of mixing ratio of anionic and nonionic emulsifiers on the kinetic behavior of methyl methacrylate emulsion polymerization
Author/Editor: SUZUKI, Kiyoshi
WAKATUKI, Youhei
SHIRASAKI, Satomi
FUJITA, Kazumi
KATO, Satoshi
NOMURA, Mamoru
Author Heading: SUZUKI, Kiyoshi
WAKATUKI, Youhei
SHIRASAKI, Satomi
FUJITA, Kazumi
KATO, Satoshi
NOMURA, Mamoru
Publication, Distribution, etc.: Elsevier Ltd
Publication Date: 2005-07
Publication Date (W3CDTF): 2005-07
Periodical title: Polymer - Letchworth
No. or year of volume/issue: 46 16
Volume: 46
Issue: 16
Pages: 5890-5895
Text Language Code: eng
Subject Heading: Emulsion polymerization
Mixed emulsifier
Number of polymer particles
Target Audience: 一般
Note (General): Emulsion polymerization of methyl methacrylate was carried out using a mixture of anionic emulsifier, sodium dodecyl sulfate (SDS) and nonionic emulsifier, poly(oxy ethylene) nonyl phenyl ether with an average of 40 oxy ethylene units per molecule (NP-40). The rate of polymerization and the number of polymer particles produced both increased with increasing the amount of NP-40 initially charged, when NP-40 was used as the sole emulsifier. Interestingly, however, both the rate of polymerization and the number of polymer particles produced was found to decrease, when the amount of NP-40 added to the fixed amount of SDS is increased in the mixed emulsifier. On the contrary, they both increased when the amount of SDS added to the fixed amount of NP-40 is increased in the mixed emulsifier. The mixed emulsifier did not affect the number of the radicals per polymer particle at a certain number of polymer particles, but affected the number of polymer particles, thus the rate of polymerization.
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ