A [2]ROTAXANE CONTAINING N,N-DIALKYLAMMONIUM ION AND N-ALKYLANILINE CENTERS. TRANSLATIONAL ISOMERISM, AND SPECIFIC N-ACYLATIONS

Material type: 文書・図像類

Author: TOKUNAGA, Yujiほか

Publisher: 日本複素還化学研究所

Publication date: 2010-01

Material Format: Digital

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Note (General)：: This paper describes the molecular shuttling and specific N-acylations of a [2]rotaxane featuring an encircling crown ether unit and both N-alkylanili...

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Material Type: 文書・図像類
Title: A [2]ROTAXANE CONTAINING N,N-DIALKYLAMMONIUM ION AND N-ALKYLANILINE CENTERS. TRANSLATIONAL ISOMERISM, AND SPECIFIC N-ACYLATIONS
Author/Editor: TOKUNAGA, Yuji
KAWABATA, Masanori
YAMAUCHI, Yuji
HARADA, Naoki
Author Heading: TOKUNAGA, Yuji
KAWABATA, Masanori
YAMAUCHI, Yuji
HARADA, Naoki
Publication, Distribution, etc.: 日本複素還化学研究所
Publication Date: 2010-01
Publication Date (W3CDTF): 2010-01
Periodical title: Heterocycles
No. or year of volume/issue: 81 1
Volume: 81
Issue: 1
Pages: 62-72
Text Language Code: eng
Target Audience: 一般
Note (General): This paper describes the molecular shuttling and specific N-acylations of a [2]rotaxane featuring an encircling crown ether unit and both N-alkylaniline and N,N-dialkylamine centers on its dumbbell-shaped component. The crown binds predominantly to the dialkylammonium center under neutral conditions. Reactions with acid anhydride in nonpolar solvents and in the absence or presence of a weak base resulted in the N-acylations occurring mainly at the aniline moiety, and selective N-acylations of the dialkylamine unit occurred in polar solvents in the presence of strong bases.
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ