Preparation and optical properties of CeF3-containing oxide fluoride glasses

Material type: 文書・図像類

Author: TAKAHASHI, Hiroshほか

Publisher: ELSEVIER SCIENCE SA

Publication date: 2008-11

Material Format: Digital

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Note (General)：: Cerium-containing oxide fluoride glasses CeF_3-BaF_2-AlF_3-SiO_2 were prepared under CO and Ar atmospheres. The glass prepared in CO exhibited blue em...

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Material Type: 文書・図像類
Title: Preparation and optical properties of CeF3-containing oxide fluoride glasses
Author/Editor: TAKAHASHI, Hirosh
YONEZAWA, Susumu
KAWAI, Masayuk
TAKASHIMA, Masayuki
Author Heading: TAKAHASHI, Hirosh
YONEZAWA, Susumu
KAWAI, Masayuk
TAKASHIMA, Masayuki
Publication, Distribution, etc.: ELSEVIER SCIENCE SA
Publication Date: 2008-11
Publication Date (W3CDTF): 2008-11
Periodical title: JOURNAL OF FLUORINE CHEMISTRY
No. or year of volume/issue: 129 11
Volume: 129
Issue: 11
Pages: 1114-1118
Text Language Code: eng
Subject Heading: Oxide fluoride glass
Cerium fluoride
CO atmosphere
Luminescence
X-ray photoelectron spectroscopy (XPS)
Target Audience: 一般
Note (General): Cerium-containing oxide fluoride glasses CeF_3-BaF_2-AlF_3-SiO_2 were prepared under CO and Ar atmospheres. The glass prepared in CO exhibited blue emission under UV irradiation. Peak analyzes were performed to investigate their optical properties. The emission spectra were separable into three peak components by peak analysis. X-ray photoemission spectroscopy (XPS) spectra were measured to investigate the valency of the elements in the glass. Oxygen and fluorine in the glasses were more covalent and ionic than those in simple oxide and fluoride compounds. The cerium ion in the glass prepared in CO might be under a cationic condition whereas that in Ar might be under an anionic condition.
Access Restrictions: 限定公開
Related Material (DOI): 10.1016/j.jfluchem.2008.07.021
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ