Transition from heterogeneous catalytic reaction to homogeneous one by variation of palladium particle size

Material type: 文書・図像類

Author: YANHONG, Zhaoほか

Publisher: Elsevier Ltd

Publication date: 2006-08

Material Format: Digital

Capacity, size, etc.: -

NDC: -

View All

Notes on use

Note (General)：: Reduction of methylene blue with hydrazine was catalyzed by nearly mono-dispersed palladium particles of which diameters (2r0) ranged from 30 to 230 n...

Search by Bookstore

Holdings of Libraries in Japan

This page shows libraries in Japan other than the National Diet Library that hold the material.

List of Cooperating Institutions and Databases

Please contact your local library for information on how to use materials or whether it is possible to request materials from the holding libraries.

other

Ｕｎｉｖｅｒｓｉｔｙ　ｏｆ　Ｆｕｋｕｉ　Ａｃａｄｅｍｉｃ　Ｒｅｐｏｓｉｔｏｒｙ
Digital
You can check the holdings of institutions and databases with which 学術機関リポジトリデータベース（IRDB）（機関リポジトリ） is linked at the site of 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）.
Ｕｎｉｖｅｒｓｉｔｙ　ｏｆ　Ｆｕｋｕｉ　Ａｃａｄｅｍｉｃ　Ｒｅｐｏｓｉｔｏｒｙ

Search by Bookstore

Bibliographic Record

You can check the details of this material, its authority (keywords that refer to materials on the same subject, author's name, etc.), etc.

Digital

Material Type: 文書・図像類
Title: Transition from heterogeneous catalytic reaction to homogeneous one by variation of palladium particle size
Author/Editor: YANHONG, Zhao
AOKI, Koichi
Author Heading: YANHONG, Zhao
AOKI, Koichi
Publication, Distribution, etc.: Elsevier Ltd
Publication Date: 2006-08
Publication Date (W3CDTF): 2006-08
Periodical title: Chemical Physics Letters
No. or year of volume/issue: 430 1-3
Volume: 430
Issue: 1-3
Pages: 117-120
Text Language Code: eng
Subject Heading: catalysis by palladium particles
methylene blue
reaction order
thickness of reaction layer
Target Audience: 一般
Note (General): Reduction of methylene blue with hydrazine was catalyzed by nearly mono-dispersed palladium particles of which diameters (2r0) ranged from 30 to 230 nm. The spectroscopically evaluated pseudo-first order reaction rate constants were proportional to r03α, where 3α varied from 2 to 3 with a decrease in the radius. The catalysis at large r0 proceeded heterogeneously, whereas that at small r0 occurred homogeneously. The relation between α and r0 allowed us to evaluate the thickness of the reaction layer to be 20 nm. The analysis of the diffusion-reaction model demonstrated the thickness did not vary largely with r0.
Source: https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=22578&item_no=1&attribute_id=22&file_no=1
https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=22578&item_no=1&attribute_id=22&file_no=1
Access Restrictions: 限定公開
Related Material (DOI): 10.1016/j.cplett.2006.08.132
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ