Dissociation Kinetic Analysis of Ce(III) Complex with Quin2 by Microchip Capillary Electrophoretic Reactor

Material type: 文書・図像類

Author: OHTSUKA, Kei-ichirouほか

Publisher: 日本分析化学会

Publication date: 2013-05

Material Format: Digital

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Note (General)：: Dissociation kinetic analysis of a complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5- methylphenoxyl)methyl]-6-methoxyquinoline...

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Material Type: 文書・図像類
Title: Dissociation Kinetic Analysis of Ce(III) Complex with Quin2 by Microchip Capillary Electrophoretic Reactor
Author/Editor: OHTSUKA, Kei-ichirou
IKI, Nobuhiko
HOSHINO, Hitoshi
TAKAHASHI, Toru
Author Heading: OHTSUKA, Kei-ichirou
IKI, Nobuhiko
HOSHINO, Hitoshi
TAKAHASHI, Toru
Publication, Distribution, etc.: 日本分析化学会
Publication Date: 2013-05
Publication Date (W3CDTF): 2013-05
Periodical title: Analytical Sciences
No. or year of volume/issue: 29 5
Volume: 29
Issue: 5
Pages: 553-557
Text Language Code: eng
Target Audience: 一般
Note (General): Dissociation kinetic analysis of a complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5- methylphenoxyl)methyl]-6-methoxyquinoline-N,N,N′,N′,-tetraacetic acid (Quin2), was studied by microchip capillary electrophoretic reactor. Dissociation rate constants, kd, of Ce3+-Quin2 complex in alkaline conditions at pH 8.3 – 9.8 were determined. The linear relationship of kd with the concentration of hydroxide ion indicates the existence of a hydroxide ion-assisted path in the dissociation reaction of Ce3+-Quin2 complex in alkaline conditions. The solvolytic dissociation rate constant, and the hydroxide ion-assisted dissociation rate constant of Ce3+-Quin2 complex were determined to be 1.55 × 10–3 and 3.24 × 102 s–1 in the analysis of the dependence of kd with the concentration of hydroxide ion, respectively.
Source: https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=23085&item_no=1&attribute_id=22&file_no=1
https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=23085&item_no=1&attribute_id=22&file_no=1
Access Restrictions: 限定公開
Rights (production): c 2013 The Japan Society for Analytical Chemistry
Related Material (DOI): 10.2116/analsci.29.553
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ