Dichroic infrared absorption of dipole centers in cadmium halide crystals

Material type: 文書・図像類

Author: TERAKAMI, Mほか

Publisher: Elsevier Ltd

Publication date: 2004-06

Material Format: Digital

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Note (General)：: Dichroic infrared (IR) absorption measurements on CN~ or OH~ centers in cadmium halide crystals were carried out at 6 K with a high spectral resolutio...

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Material Type: 文書・図像類
Title: Dichroic infrared absorption of dipole centers in cadmium halide crystals
Author/Editor: TERAKAMI, M
NAKAGAWA, H
FUKUI, K
OKAMURA, H
HIRONO, T
IKEMOTO, Y
MORIWAKI, T
KIMURA, H
Author Heading: TERAKAMI, M
NAKAGAWA, H
FUKUI, K
OKAMURA, H
HIRONO, T
IKEMOTO, Y
MORIWAKI, T
KIMURA, H
Publication, Distribution, etc.: Elsevier Ltd
Publication Date: 2004-06
Publication Date (W3CDTF): 2004-06
Periodical title: Journal of Luminescence
No. or year of volume/issue: 108 1-4
Volume: 108
Issue: 1-4
Pages: 75-79
Text Language Code: eng
Subject Heading: CN~
OH~
Polarized IR absorption
Libration
Cadmium halide
Target Audience: 一般
Note (General): Dichroic infrared (IR) absorption measurements on CN~ or OH~ centers in cadmium halide crystals were carried out at 6 K with a high spectral resolution of 0.025 cm-1 at 2000 cm-1, by using a FT-IR spectrometer. Several sharp absorption lines with widths less than 0.1 cm-1 are observed in the energy region of the stretching vibration, i.e. 2000–2250 cm-1 for CN~ and 2500–4500 cm-1 for OH~. These lines are classified into three groups attributed to: (1) an isolated center simply substituted for a halogen ion, (2) an interstitial center located between the cadmium and halogen ion sheets and (3) a coupled center with an anion vacancy. A doublet structure is observed in CdI2 which comes from different halogen-ion sites in the 4H-polytype crystal. The isolated CN~ centers in CdCl2 and CdBr2 align toward Cd2+ ions, away from the direction of the c-axis. Almost all of the coupled center with a vacancy lies in a halogen-ion plane. The doublet structure of the coupled center in CdCl2 and CdBr2 is connected to the tunneling splitting of a vibrational level.
Source: https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=23979&item_no=1&attribute_id=22&file_no=1
https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=23979&item_no=1&attribute_id=22&file_no=1
Access Restrictions: 限定公開
Related Material (DOI): 10.1016/j.jlumin.2004.01.014
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ