Microwave spectra of CuOD and AgOD: Molecular structure and harmonic force field of CuOH and AgOH

Material type: 文書・図像類

Author: WHITHAM, Christopher J.ほか

Publisher: American Institute of Physics

Publication date: 2000-01

Material Format: Digital

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Note (General)：: Pure rotational spectra are reported for the deuterated species of copper and silver hydroxide, (CuOD)-Cu-63, (AgOD)-Ag-107, and (AgOD)-Ag-109. Togeth...

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Material Type: 文書・図像類
Title: Microwave spectra of CuOD and AgOD: Molecular structure and harmonic force field of CuOH and AgOH
Author/Editor: WHITHAM, Christopher J.
OZEKI, Hiroyuki
SAITO, Shuji
Author Heading: WHITHAM, Christopher J.
OZEKI, Hiroyuki
SAITO, Shuji
Publication, Distribution, etc.: American Institute of Physics
Publication Date: 2000-01
Publication Date (W3CDTF): 2000-01
Periodical title: Journal of Chemical Physics
No. or year of volume/issue: 112 2
Volume: 112
Issue: 2
Pages: 641-646
Text Language Code: eng
Target Audience: 一般
Note (General): Pure rotational spectra are reported for the deuterated species of copper and silver hydroxide, (CuOD)-Cu-63, (AgOD)-Ag-107, and (AgOD)-Ag-109. Together with the CuOH and AgOH data previously reported, a number of harmonic force constants were determined. These constants are interpreted in terms of the balance between competing ionic and covalent interactions. The harmonic force field allowed the r(z) structures to be determined. Both molecules are strongly bent indicating considerable covalent character.
Access Restrictions: 限定公開
Rights (production): 〓 2000 American Institute of Physics
Related Material (DOI): 10.1063/1.480725
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ