Participation in Self-Emulsification by Oil-Thin Film Voltammetry

Material type: 文書・図像類

Author: Aoki, Koichi Jeremiahほか

Publisher: Canadian Center of Science and Education

Publication date: 2014-04-22

Material Format: Digital

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Note (General)：: When an oil phase comes in contact with an aqueous phase, emulsions are formed spontaneously in each phase even without surfactant. The self-emulsific...

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Material Type: 文書・図像類
Title: Participation in Self-Emulsification by Oil-Thin Film Voltammetry
Author/Editor: Aoki, Koichi Jeremiah
Yu, Jie
Chen, Jingyuan
Nishiumi, Toyohiko
Author Heading: Aoki, Koichi Jeremiah
Yu, Jie
Chen, Jingyuan
Nishiumi, Toyohiko
Publication, Distribution, etc.: Canadian Center of Science and Education
Publication Date: 2014-04-22
Publication Date (W3CDTF): 2014-04-22
Periodical title: International Journal of Chemistry
No. or year of volume/issue: 6 2
Volume: 6
Issue: 2
Pages: 73-81
ISSN (Periodical Title): ISSN : 1916-9698
Text Language Code: eng
Subject Heading: thin-layer cell voltammetry at oil-coated film electrodes
self-emulsification at nitrobenzene/waterinterface
water droplets in oil phase
electron transfer mechanism
Target Audience: 一般
Note (General): When an oil phase comes in contact with an aqueous phase, emulsions are formed spontaneously in each phase even without surfactant. The self-emulsification seems inconsistent with the electron transfer model proposed by Anson, in which ferricyanide in the aqueous phase is reduced at the oil/water interface by decamethylferrocene of the thin nitrobenzene phase. Anson's experimental data were here reproduced at slow scan voltammetry. However, the electron transfer model did not agree with our experimental results at high scan rates, in that the reduction wave of ferricyanide appeared without decamethylferrocene. Ferricyanide was demonstrated to pass through the nitrobenzene film in the form of aqueous droplets, which were adsorbed on the electrode surface. Formation of aqueous droplets can explain electrode reactions at carbon paste electrodes without including redox species in paste.
Source: https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=22927&item_no=1&attribute_id=22&file_no=1
https://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=22927&item_no=1&attribute_id=22&file_no=1
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ