Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography

Material type: 文書・図像類

Author: Miyagawa, Shinobuほか

Publisher: Wiley-VCH

Publication date: 2020-08-11

Material Format: Digital

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Note (General)：: A crown ether/amine‐type [2]rotaxane was synthesized and utilized as a probe for the detection of acids and anions. The addition of acids to the amine...

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Material Type: 文書・図像類
Title: Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography
Author/Editor: Miyagawa, Shinobu
Kimura, Masaki
Kagami, Shin
Kawasaki, Tsuneomi
Tokunaga, Yuji
Author Heading: Miyagawa, Shinobu
Kimura, Masaki
Kagami, Shin
Kawasaki, Tsuneomi
Tokunaga, Yuji
Publication, Distribution, etc.: Wiley-VCH
Publication Date: 2020-08-11
Publication Date (W3CDTF): 2020-08-11
Alternative Title: Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography
Periodical title: Chemistry An Asian Journal
No. or year of volume/issue: 15 19
Volume: 15
Issue: 19
Pages: 3044-3049
ISSN (Periodical Title): ISSN : 1861-4728
Text Language Code: eng
Subject Heading: Company legal issue
Ammonium compounds
Ammonium paratungstate
Target Audience: 一般
Note (General): A crown ether/amine‐type [2]rotaxane was synthesized and utilized as a probe for the detection of acids and anions. The addition of acids to the amine‐type [2]rotaxane solution generated corresponding crown ether/ammonium‐type [2]rotaxanes, which were purified by silica gel column chromatography as ammonium salts. The isolated yields of the [2]rotaxanes, possessing a variety of anions, depended on the acidity and polarity of the counter anions. The behaviours of the ammonium‐type [2]rotaxanes on thin‐layer chromatography (TLC) silica gel reflected the properties of the counter anions. The treatment of the amine‐type [2]rotaxane with acids afforded the corresponding ammonium‐type [2]rotaxanes bearing several different anions. The ammonium‐type [2]rotaxanes behaved similarly to the purified [2]rotaxanes on the TLC silica gel. Furthermore, we succeeded in the analysis of anions using mixtures of the amine‐type [2]rotaxane and salts in an appropriate solvent. We demonstrated the detection of anions by the combination of TLC and the utilization of the [2]rotaxane probe.
Access Restrictions: 限定公開
Related Material (DOI): 10.1002/asia.202000746
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 福井大学 : 福井大学学術機関リポジトリ