Design and Characterization of Photorefractive Polymer Composites

Material type: 博士論文

Author: Giang Ngoc, Ha

Publisher: -

Publication date: 2014-09-25

Material Format: Digital

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Name of awarding university/degree: 京都工芸繊維大学,博士(工学)

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Note (General)：: type:ThesisIn this work, the material design direction of photoconductive polymer for photorefractive (PR) composite is proposed. Several different po...

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Material Type: 博士論文
Title: Design and Characterization of Photorefractive Polymer Composites
Author/Editor: Giang Ngoc, Ha
Author Heading: Giang Ngoc, Ha
Publication Date: 2014-09-25
Publication Date (W3CDTF): 2014-09-25
Alternative Title: フォトリクラクティブポリマー複合体の設計と評価
Degree grantor/type: 京都工芸繊維大学
Date Granted: 2014-09-25
Dissertation Number: 甲第719号
Degree Type: 博士(工学)
Text Language Code: eng
Subject Heading: Photorefractive effect
photoconductive polymer
composite
carbazole
triphenylamine
chromophore
Target Audience: 一般
Note (General): type:Thesis
In this work, the material design direction of photoconductive polymer for photorefractive (PR) composite is proposed. Several different polymers are synthesized and applied to fabricate PR composite to qualify advantage and disadvantage of each material design approach. The monolithic co-polymer with carbazole and nonlinear optical (NLO) is synthesized successfully with high molecular weight by polymer analogous reaction. The approach of using PR composite based on monolithic co-polymer has been proved its effectiveness in loading a high concentration of chromophore without phase-separation. However, response time is decreased due to low photoconductivity. The triphenylamine is chosen to improve the PR properties. Poly(4-(diphenylamino)benzyl acrylate) (PDAA) is synthesized by radical polymerization. Composite based on PDAA shows > 80% diffraction efficiency at a moderate applied field. Shorter wavelength of writing beam gives better PR performances. The demonstration of real-time hologram display is performed successfully with PDDA-based composite devices at low applied field of 25 V/?m. The strategy of using higher highest occupied molecular orbital (HOMO) level polymer is confirmed by comparing two similar polymer with different ionization potential (IP) values. Poly(4-((4-methoxyphenyl)(phenyl)amino)benzyl acrylate) (PMPAA) is synthesized with a comparable molecular weight to PDAA. The methoxy modification in PMPAA does not only raise the HOMO level but also contribute significant improvement in chromophore orientation. The comparison of the two kinds of composite based on PDAA and PMPAA reveals that higher HOMO level of photoconductive polymer does not always lead to better PR performances. The controlling of trap in PR composite is found to be more important to obtain the desired properties.
Format (IMT): application/pdf
Source: fulltext
http://repository.lib.kit.ac.jp/repo/repository/10212/2193/D1-0719_h1.pdf
fulltext
http://repository.lib.kit.ac.jp/repo/repository/10212/2193/D1-0719.pdf
Access Restrictions: インターネット公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 京都工芸繊維大学 : ＫＩＴ学術成果コレクション