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Bibliographic Record
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- Material Type
- 文書・図像類
- Author/Editor
- 吉田, 昌弘
- Author Heading
- Publication, Distribution, etc.
- Alternative Title
- Stimuli-response microsphere possessing information exchange and functional control
- Text Language Code
- jpn
- Subject Heading
- Target Audience
- 一般
- Note (General)
- 2008-2010年度科学研究費補助金(基盤研究(C))研究成果報告書 課題番号:20560706 研究代表者:吉田昌弘 (鹿児島大学大学院理工学研究科(工学系)教授)電場応答を可能にするフラグメント合成、分子インプリント法による電場応答性分子認識ミクロスフェアの調製及び特性評価に関する研究開発を行った。調製したミクロスフェアの分子認識メカニズムに関しての検討を行った。通常の分子認識能力の性能評価は、2Vの電場をかけることにより分子を記憶した三次元的空洞がどのように相分離し、認識ターゲット(Fmoc-PheOH)を取り込んでいるかで評価した。An enantio-selective microsphere was prepared by the molecular imprinting technique for the separation of optically active Fmoc-PheOH. A synthetic ferroelectric liquid crystal monomer (functional monomer) responds to external electrical field possessing mesogenic group, spontaneous polarization property and chiral moiety was found to be effective for recognizing the chirality of amino acid derivative. The Fmoc-D-PheOH-imprinted microsphere containing the functional monomer reveals high enantio-selectivity toward the corresponding imprinted isomer compared to selectivity of another one in the electrical field.