アミド系抽出剤を用いたウラン酸化物の溶解試験

• Material Type: 文書・図像類
• Title: アミド系抽出剤を用いたウラン酸化物の溶解試験
• Author/Editor: 水野 峰雄; 高阪 裕二; 森 行秀; 島田 隆
• Author Heading: 水野 峰雄; 高阪 裕二; 森 行秀; 島田 隆
• Publication Date: 2004-03
• Publication Date (W3CDTF): 2004-03
• Alternative Title: The Dissolving Test of the Uranium Oxide using Amide System Extraction Solvent
• Periodical title: JNC TJ8410 2004-006
• Text Language Code: jpn
• Target Audience: 一般
• Note (General): 硝酸を抽出した網オ系抽出剤を用いて、酸化物燃料からウラン及びプルトニウムを選択的に溶解・抽出する方法(UPRISE法)を検討している。本試験では、アミド系抽出剤へのウランの溶解傾向を調査するとともに、NdN等の代表的な核分裂生成物との分離性能を模擬酸化物を用いて調べた。; /The process (the UPRISE method) of dissolving uranium and plutonium selectively and separating from oxide fuel using the amide system extraction solvent have been investigated. By the cold test which used Nd oxide so far, the dissolving of Nd with about 0.2 mol to the solvent of 250mL is confirmed. In this work, the investigations of the dissolving tendency of uranium to the amide system extraction solvent and decontamination factor (DF) of the typical fission product (FP) such as Nd were carried out, and following results are obtained. (1)In the test of the same dissolving conditions, the uranium dissolving rate to extraction solvent DOBA was approximately equivalent to the case of the DOiBA. (2)Three kinds of extraction solvent were examined in the same dissolving condition, the difference of the uranium dissolving rate was observed. The results of the dissolving rates indicated the order of NN'-hexyl-2, ethyl-hexan-amid-1.6 mol/L nitric acid complex $>$ NN'-dibutyl-butyl-amid-1.7 mol/L nitric acid complex $>$ NN'-di-isobutyl-isobutyl-amid-1.5 mol/L nitric acid complex. (3)In the case of DOBA extraction solvent, the dissolving rate increased by about 2 order with the increase of the nitric acid concentration from 1mol/L up to 3.5mol/L and strong influence of the nitric acid concentration was confirmed to the dissolving rate. (4)In the tests with the NN'-dibutyl-butyl-amid-1.7 mol/L nitrie acid complex and NN'-di-isobutyl-isobutyl-amid-1.5 mol/L nitric acid complex, the DF values of Zr, Ru and Ce increased with the elapse of the test duration and exceeded 100 after 150 hours of test duration. On the other hand, the DF value indicated around 1 for Sr, Mo and Pd, and around 0.1 for Nd. (5)In the test with the NN'-hexyl-2-ehyl-hexan-amid-1.6 mol/L nitric acid complex, significant difference wasn't observed in the tendency of the elapsed change among the DF values of the FP elements. The DF values of all FP elements except Nd and Pd exceeded 100 after 100 ...
• Source: /JNC-TJ8410-2004-006.pdf （fulltext）; https://jopss.jaea.go.jp/pdfdata/JNC-TJ8410-2004-006.pdf
• Access Restrictions: 限定公開
• Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）; https://irdb.nii.ac.jp
• Original Data Provider (Database): 日本原子力研究開発機構 : JOPSS:JAEA Originated Papers Searching System

• Summary, etc.: 硝酸を抽出した網オ系抽出剤を用いて、酸化物燃料からウラン及びプルトニウムを選択的に溶解・抽出する方法(UPRISE法)を検討している。本試験では、アミド系抽出剤へのウランの溶解傾向を調査するとともに、NdN等の代表的な核分裂生成物との分離性能を模擬酸化物を用いて調べた。/The process (t...