1,2,4-トリアゾール-3-オン銅錯体硝酸塩の熱的特性および燃焼特性

Material type: 文書・図像類

Author: 大貫, 学ほか

Publisher: 宇宙航空研究開発機構(JAXA)

Publication date: 2015-03-13

Material Format: Digital

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Note (General)：: 本研究の目的は，ガス発生剤として1,2,4-トリアゾール-3-オン銅錯体硝酸塩(TOCu)を合成し，熱的特性および初期分解機構の検討からTOCuの反応性に及ぼすCuの影響を検討することである．ガス発生剤としての性能評価は燃焼試験により行った．TOCuは，1,2,4-トリアゾール-3-オン(TO)およ...

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Material Type: 文書・図像類
Title: 1,2,4-トリアゾール-3-オン銅錯体硝酸塩の熱的特性および燃焼特性
Author/Editor: 大貫, 学
吉野, 悟
三宅, 淳巳
富山, 昇吾
羽生, 宏人
小森谷, 友絵
坂本, 恵一
Ohnuki, Manabu
Yoshino, Satoru
Miyake, Atsumi
Tomiyama, Shogo
Habu, Hiroto
Komoriya, Tomoe
Sakamoto, Keiichi
Author Heading: 大貫, 学
吉野, 悟
三宅, 淳巳
富山, 昇吾
羽生, 宏人
小森谷, 友絵
坂本, 恵一
Ohnuki, Manabu
Yoshino, Satoru
Miyake, Atsumi
Tomiyama, Shogo
Habu, Hiroto
Komoriya, Tomoe
Sakamoto, Keiichi
Publication, Distribution, etc.: 宇宙航空研究開発機構(JAXA)
Publication Date: 2015-03-13
Publication Date (W3CDTF): 2015-03-13
Alternative Title: Thermal and combustion characteristics of 1,2,4-triazole-3-one copper complex nitrate
Periodical title: 宇宙航空研究開発機構研究開発報告: 高エネルギー物質研究会: 平成26年度研究成果報告書 = JAXA Research and Development Report
No. or year of volume/issue: JAXA-RR-14-005
Volume: JAXA-RR-14-005
Pages: 33-39
ISSN (Periodical Title): ISSN : 1349-1113
Text Language Code: jpn
Subject Heading: gas-generating agents
1,2,4-triazole-3-one cooper complex
combustion characteristics
thermal characteristics
Target Audience: 一般
Note (General): 本研究の目的は，ガス発生剤として1,2,4-トリアゾール-3-オン銅錯体硝酸塩(TOCu)を合成し，熱的特性および初期分解機構の検討からTOCuの反応性に及ぼすCuの影響を検討することである．ガス発生剤としての性能評価は燃焼試験により行った．TOCuは，1,2,4-トリアゾール-3-オン(TO)および硝酸銅(Ⅱ)･3水和物(Cu(NO3)2・3H2O)を用いて合成した．元素分析の結果からTOCuは，Cu2+-bis[(C2H3N3O)(NO3)(-)]･2H2Oとして合成された． TOCuの熱的特性を検討し，発熱量および発熱ピークの鋭さからTOおよびTO/Cu(NO3)2・3H2Oのそれらより反応性が向上されたことがわかった．生成ガス分析からTOCuは，N2，H2O， HNCO， HCN，CO2，CO，NOx ，NH3のガスが生成されることがわかった．TOCuの燃焼特性の検討し，Vieille's の式に従い圧力指数を算出し，0.6451であることがわかった．
In order to obtain a better understanding of the thermal characteristics and combustion characteristics of 1,2,4-triazole-3-one copper complex (TOCu), elemental analysis, infrared spectrometry (IR), X-ray diffraction(XRD), sealed cell-differential scanning calorimetry (SC-DSC), themogravimetry-differential thermal analysis-mass spectrometry (TG-DTA-MS) and burning test were performed. TOCu was synthesized from 1,2,4-triazole-3-one (TO) and trihydrated copper nitrate (Cu(NO3)2･3H2O). TOCu was obtained as 〔Cu(2+)(C2N3H3O)2(NO3)(-)2・2H2O〕. From the DSC results, the heat of reaction of TOCu was larger than those of pure TO and TO/Cu(NO3)2･3H2O mixtures. The exothermic peak of TOCu sharply became compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. It was found that the reactivity of TOCu was improved to compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. TG-DTA-MS curves of TOCu were showed from 3 steps of mass loss, exothermic peak and decomposition gases in the temperature ranges were 100-180 C, 200-260 C and 300-360 C. From the results of TG-DTA-MS, the gases evolved from TOCu were determined as N2, H2O, HNCO, HCN, CO2, CO, NOx and NH3 at 100-360 C. From burning test results, the burning rate of TOCu was calculated by pressure exponent 0.6451 based on Vieille's law.
形態: カラー図版あり
Physical characteristics: Original contains color illustrations
資料番号: AA1530013005
レポート番号: JAXA-RR-14-005
Access Restrictions: 限定公開
Periodical Title (NCID): AA1192675X
https://ci.nii.ac.jp/ncid/AA1192675X
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 宇宙航空研究開発機構 : 宇宙航空研究開発機構リポジトリ