フルオロフィリック効果を秩序構造形成の駆動力とする含フッ素ｎ型導電性高分子の合成

Material type: 文書・図像類

Author: 福元,, 博基ほか

Publisher: 茨城大学工学部

Publication date: 2018-06-22

Material Format: Digital

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Note (General)：: application/pdf研究報告書研究成果の概要（和文）：環状ペルフルオロアルキル基の「フルオロフィリック」効果と多環π共役系の「π－πスタッキング」の相乗効果を秩序構造形成の駆動力とする、全く新しいタイプの含フッ素ｎ型導電性高分子材料の開発を目的として、Mallory反応を用いた含フッ素フェ...

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Material Type: 文書・図像類
Title: フルオロフィリック効果を秩序構造形成の駆動力とする含フッ素ｎ型導電性高分子の合成
Author/Editor: 福元,, 博基
Fukumoto,, Hiroki
Author Heading: 福元,, 博基
Fukumoto,, Hiroki
Publication, Distribution, etc.: 茨城大学工学部
Publication Date: 2018-06-22
Publication Date (W3CDTF): 2018-06-22
Alternative Title: Synthesisi of fluorine-containing n-type polymers taking highly-ordered structures due to fluorine-fluorine interaction
Text Language Code: jpn
Target Audience: 一般
Note (General): application/pdf
研究報告書
研究成果の概要（和文）：環状ペルフルオロアルキル基の「フルオロフィリック」効果と多環π共役系の「π－πスタッキング」の相乗効果を秩序構造形成の駆動力とする、全く新しいタイプの含フッ素ｎ型導電性高分子材料の開発を目的として、Mallory反応を用いた含フッ素フェナントレン、フェナントロリンの高効率合成を達成した。クロスカップリングによる含フッ素ｎ型導電性高分子化を行い、固体中では、上記の相互作用に基づく自己集積化が起こり、高秩序構造を形成することを見出した。研究成果の概要（英文）：In this study, we investigated a new approach to the synthesis of fluorinated phenanthrene derivatives using Mallory reaction (irreversible photocyclization of diarylhexafluorocyclopentenes). We also synthesized fluorine-containing copolymers expected as n-type organic semiconductors. All the copolymers showed good solubility in typical organic solvents and had high thermal stability at approximately 400 °C in Ar atmosphere. UV-vis spectra of Phenanthrene-type copolymers in chloroform showed pi-pi* transition peaks at 380 nm and 354 nm, respectively, and additional shoulder peaks appeared at a longer wavelength in the film cast on a quartz plate, suggesting the molecular assembly of the polymer molecules. The copolymers showed photoluminesence (PL) in both chloroform and the film. XRD patterns of the copolymers gave a sharp peak around 19 °, indicating that the copolymer molecules took highly-ordered structure in the solid state.
DOI: 10.34405/00018414
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 茨城大学 : 茨城大学学術情報リポジトリ