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規格・テクニカルリポート類

水素脆化抑制に及ぼす微量元素添加効果の解明と安全性評価手法の確立

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水素脆化抑制に及ぼす微量元素添加効果の解明と安全性評価手法の確立

Material type
規格・テクニカルリポート類
Author
鴻巣,, 眞二ほか
Publisher
茨城大学工学部
Publication date
2016-06-02
Material Format
Digital
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  • Ibaraki University Academic Repository

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Digital

Material Type
規格・テクニカルリポート類
Author/Editor
鴻巣,, 眞二
Konosu,, Shinji
Publication, Distribution, etc.
Publication Date
2016-06-02
Publication Date (W3CDTF)
2016
Alternative Title
Clarification of the effects of trace elements on hydrogen embritllement and establishment of technique to evaluate the structural integrity
Target Audience
一般
Note (General)
出版タイプ: VoR
application/pdf
text/plain
研究報告書
研究成果の概要(和文):鉄基材料の水素脆化感受性に与える微量元素の影響に着目し、昇温水素離脱反応と走査電顕解析によって、約0.3%のV添加による旧オーステナイト粒内でのバナジュウム炭化物の微細析出が水素脆化感受性低減に有効であるが、PやSnなどの不純物元素低下は水素助長割れ発生抵抗に対してはほとんど影響がないことを明らかにした。装置の安全性評価のためには、割れの発生抵抗である破壊じん性KIH、伝播抵抗であるdJ/daおよび一定荷重下での進展速度da/dt 特性が必要とされる。本研究においては、新たに開発したオフセットポテンシャル法を用いて微量元素を調整した2.25Cr-1Mo鋼でそれらの特性を明らかにした。 研究成果の概要(英文):By focusing attention on the effects of trace elements on hydrogen embrittlement sensitivity for iron-based materials, the thermal desorption analysis and electro probe microanalysis were conducted. A number of dispersed vanadium carbides caused by the addition of roughly 0.3 wt.% vanadium is effective in mitigating hydrogen embrittlement, while the reduction of impurity elements such as phosphorus and tin has little impact on threshold for hydrogen-induced fracture. For a structural integrity assessment, the mechanical characteristics such as threshold stress intensity factors at the onset of hydrogen-assisted crack growth, KIH, the tearing resistance, dJ/da and subcritical crack growth rates at constant loads, da/dt need to be known. In this study, the newly developed offset potential-drop method was employed to clarify these properties for 2.25Cr-1Mo steels with trace element controls.