Charge Resonance and Charge Transfer Interactions in Naphthalene Homo- and Hetero-Dimers

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Charge Resonance and Charge Transfer Interactions in Naphthalene Homo- and Hetero-Dimers

Material type: 図書

Author: Inokuchi, Y.ほか

Publisher: American Institute of Physics

Publication date: 2000-12-15

Material Format: Digital

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NDC: 430

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Note (General)：: type:textCharge resonance interaction in naphthalene homo- and hetero-dimer cations is studied by photodissociation spectroscopy of the charge resonan...

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Material Type: 図書
Title: Charge Resonance and Charge Transfer Interactions in Naphthalene Homo- and Hetero-Dimers
Author/Editor: Inokuchi, Y.
Matsumoto, M.
Ohashi, K.
Nishi, N.
Author Heading: Inokuchi, Y.
Matsumoto, M.
Ohashi, K.
Nishi, N.
Publication, Distribution, etc.: American Institute of Physics
Publication Date: 2000-12-15
Publication Date (W3CDTF): 2000-12-15
Periodical title: Resonance Ionization Spectroscopy 1996 : Eighth International Symposium
Pages: 231-236
ISSN (Periodical Title): ISSN : 0094-243X
Text Language Code: eng
NDC: 430
Target Audience: 一般
Note (General): type:text
Charge resonance interaction in naphthalene homo- and hetero-dimer cations is studied by photodissociation spectroscopy of the charge resonance and the local excitation transitions. The resonance interaction in naphthalene dimer cation is slightly weaker than that of a benzene dimer cation because of partial overlapping of the respective aromatic rings. A local excitation band of the benzene cation chromophore is observed in the spectrum of a naphthalene-benzene hetero-dimer cation at nearly the same position as that of the benzene dimer cation. This indicates that in spite of its higher ionization potential the positive charge stays on the benzene molecule in some probability. On the basis of the band position of the charge resonance transition as well as the intensity of the local excitation band, the probability is analyzed to be approximately 9 %. This means 91 % is localized on the naphthalene chromophore in this hetero-dimer.
AIP Conference Proceedings 388
Format (IMT): application/pdf
Source: http://ir.lib.hiroshima-u.ac.jp/files/public/3/38471/20151119093957527962/ResIonSpectrosc_1996_231.pdf
http://ir.lib.hiroshima-u.ac.jp/files/public/3/38471/20151119093957527962/ResIonSpectrosc_1996_231.pdf
Access Restrictions: 限定公開
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Original Data Provider (Database): 広島大学 : 広島大学学術情報リポジトリ