チオール及びアミン化合物による古タイヤゴムの化学再生

Material type: 文書・図像類

Author: 尾之内, 千夫ほか

Publisher: 愛知工業大学

Publication date: 1980-03-31

Material Format: Digital

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Note (General)：: The reclamation of crushed tire scrap of passenger cars was carried out by a conventional mechano-chemical procedure with organic thiol and amine comp...

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Material Type: 文書・図像類
Title: チオール及びアミン化合物による古タイヤゴムの化学再生
Author/Editor: 尾之内, 千夫
稲垣, 慎二
岡本, 弘
古川, 淳二
Author Heading: 尾之内, 千夫
稲垣, 慎二
岡本, 弘
古川, 淳二
Publication, Distribution, etc.: 愛知工業大学
Publication Date: 1980-03-31
Publication Date (W3CDTF): 1980-03-31
Alternative Title: チオールオヨビアミンカゴウブツニヨルフルタイヤゴムノカガクサイセイ
Chemical Reclamation of Used Tire with Thiol and Amine Compounds
Periodical title: 愛知工業大学研究報告. B, 専門関係論文集 = Bulletin of Aichi Institute of Technology. Part B
No. or year of volume/issue: 15
Volume: 15
Pages: 43-48
ISSN (Periodical Title): ISSN : 0387-0812
Text Language Code: jpn
Target Audience: 一般
Note (General): The reclamation of crushed tire scrap of passenger cars was carried out by a conventional mechano-chemical procedure with organic thiol and amine compounds which are usually employed as an accelerator, antioxidant and peptizer for vulcanizates. Consequently, 2-mercaptobenzothiazole and its cyclohexylamine salt were found to be the more effective reclaiming agents. From the swelling measurement of SBR vulcanizates in benzene solution containing a small amount of thiol and amine compounds as a reclaiming agent, it was that thiophenol, pchlorothiophenol, n-butylamine and dimethylamine contributed considerably to the degradation of vulcanizates. Moreover, the thiol-amine complex was found to serve remarkably as a breaker of crossliking which is presented in the form of di-and poly-sulfide linkages. These reclaimed rubbers obtained by the mechano-chemical procedure with thiol and amine compounds have low Mooney viscosity and these re-vulcanizates show the excellent tensile properties. Especially, the re-vulcanizates having the tensile strengt of 170kgf/(cm)^2 were obtained by the use of the reclaiming agents composed of thiophenol and n-butylamine or morpholine.
identifier:http://repository.aitech.ac.jp/dspace/handle/11133/555
Format (IMT): application/pdf
Source: http://repository.aitech.ac.jp/dspace/bitstream/11133/555/1/%e7%b4%80%e8%a6%8115%e5%8f%b7B%28P43-48%29.pdf
http://repository.aitech.ac.jp/dspace/bitstream/11133/555/1/%e7%b4%80%e8%a6%8115%e5%8f%b7B%28P43-48%29.pdf
Access Restrictions: 限定公開
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 愛知工業大学 : 愛知工業大学学術情報リポジトリ