ポリイミド基板上に作製されたVOPc薄膜の形態と非線形光学特性へのコロナ帯電効果

Material type: 文書・図像類

Author: 中野, 寛之ほか

Publisher: 愛知工業大学

Publication date: 2003-01-20

Material Format: Digital

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Note (General)：: One important factor for a nonlinear optical thin film having high second and third nonlinear optical susceptibilities is a high packing density. Vana...

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Material Type: 文書・図像類
Title: ポリイミド基板上に作製されたVOPc薄膜の形態と非線形光学特性へのコロナ帯電効果
Author/Editor: 中野, 寛之
酒井, 雄二
内田, 悦行
大橋, 朝夫
小嶋, 憲三
落合, 鎮康
Author Heading: 中野, 寛之
酒井, 雄二
内田, 悦行
大橋, 朝夫
小嶋, 憲三
落合, 鎮康
Publication, Distribution, etc.: 愛知工業大学
Publication Date: 2003-01-20
Publication Date (W3CDTF): 2003-01-20
Alternative Title: ポリイミドキバンジョウニサクセイサレタ　VOPc ハクマクノケイタイトヒセンケイコウガクトクセイエノ　コロナタイデンコウカ
Effects of Corona Charging on Nonlinear Optical Property and Morphology of VOPc Thin Film Prepared on Polyimide Substrate by Molecular Beam Epitaxy
Periodical title: 総合技術研究所研究報告=Bulletin of Research Institute for Industrial Technology.
No. or year of volume/issue: 4
Volume: 4
Pages: 59-62
ISSN (Periodical Title): ISSN : 1344-9672
Text Language Code: eng
Subject Heading: epitaxy
VOPc film
corona charging
phase transition
THG
Target Audience: 一般
Note (General): One important factor for a nonlinear optical thin film having high second and third nonlinear optical susceptibilities is a high packing density. Vanadyl-phthalocyanine (VOPc) thin films were prepared on non-charged and corona-charged polyimide substrates by the molecular beam epitaxy (MBE). The VTS/UV spectrum of Sample 1 on a non-charged substrate had a maximum absorption peak at 835nm. According to Griffiths et al., the VOPc thin film has a maximum absorption peak at 830nm, after prepared on a glass at room temperature and heated at 325℃ for 2 hours. He called the morphology of Phase III. The maximum absorption peak of Sample 1 shifted longer by 5nm than that reported by Griffiths. This means that the packing density of Sample 1 is higher than that of the VOPc thin film reported by Griffiths. A maximum absorption peak in Q band region of Sample 4 on a corona charged substrate appeared at 845nm, which is longer by lOnm than that of Sample 1. This suggests that a strong interaction between VOPc molecule and electric charge on polyimide substrate makes a high molecular packing of Sample 4. The third harmonic (TH) generations of Samples 1 and 4 were measured by Maker fringe with P polarized laser light. The peak value of TH intensity of Sample 4 was larger by 2 times than that of Sample 1. This means that the nonlinear optical property of VOPc thin film is improved by corona charging.
identifier:http://repository.aitech.ac.jp/dspace/handle/11133/1605
Access Restrictions: 限定公開
Periodical Title (NCID): AA11484797
https://ci.nii.ac.jp/ncid/AA11484797
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 愛知工業大学 : 愛知工業大学学術情報リポジトリ