ハロゲン化芳香族化合物の光化学的脱ハロゲン化(2) : ハロゲン化イサチン誘導体の光化学的脱ハロゲン化

Material type: 文書・図像類

Author: 立木, 次郎ほか

Publisher: 愛知工業大学

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Note (General)：: Photochemical dehalogenation of halogenated 1-substituted 7-azaisatins in degassed solutions was investigated. Photochemical reactions of 1-alkyl-5-br...

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Material Type: 文書・図像類
Title: ハロゲン化芳香族化合物の光化学的脱ハロゲン化(2) : ハロゲン化イサチン誘導体の光化学的脱ハロゲン化
Author/Editor: 立木, 次郎
土屋, 幸生
伊藤, 貴賢
Author Heading: 立木, 次郎
土屋, 幸生
伊藤, 貴賢
Publication, Distribution, etc.: 愛知工業大学
Alternative Title: Photochemical Dehalogenation of Halogenated Aromatic Compounds (2) : Photochemical Dehalogenation of Halogenated Isatin Derivatives
Periodical title: 総合技術研究所研究報告=Bulletin of Research Institute for Industrial Technology.
No. or year of volume/issue: 8
Volume: 8
Pages: 19-24
ISSN (Periodical Title): ISSN : 1344-9672
Text Language Code: jpn
Target Audience: 一般
Note (General): Photochemical dehalogenation of halogenated 1-substituted 7-azaisatins in degassed solutions was investigated. Photochemical reactions of 1-alkyl-5-bromo-7-azaisatins in degassed 2-propanol gave 1-alkyl-7-azaistins and 1-alkyl-5-bromo-7-azaoxindoles. On the other hand, photochemical reactions of 1-alkyl-5-chloro-7-axaisatins in degassed 2-propanol afforded 1-alkyl-5-chloro-7-azaoxindoles which were followed by dechlorination to give 1-alkyl-7-azaoxindoles. Photoreaction of 1-(fluorobenzyl)-7-azaisatins gave selectively 1-(fluorobenzyl)-7-azaoxyindoles. Photochemical reactions of 1-(bromobenzyl)-7-azaisatins afforded 1-(bromobenzyl)-7-azaisatins which then reduced to 1-benzyl-7-azaoxindole. Photoreaction of 1-(chlorophenyl)-7-azaisatins afforded selectively 1-(chlorobenzyl)-7-azaoxindoles.
identifier:http://repository.aitech.ac.jp/dspace/handle/11133/1658
Access Restrictions: 限定公開
Periodical Title (NCID): AA11484797
https://ci.nii.ac.jp/ncid/AA11484797
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 愛知工業大学 : 愛知工業大学学術情報リポジトリ