並列タイトル等Redox potentials of polynuclear metal complexes by π-conjugated metal-interaction
一般注記Polynuclear metal ctomplexes of which redox sites are connected with π-conjugated ligands take a number of mixed valence states. They exhibit several redox potentials owing to interaction between redox centers through the π-conjugated bridges. Questions arise about the definition of the interaction, a relation between the number of nuclei and the number of redox potentials, and a relationship between redox potentials and geometry of the complexes. This paper answers these questions thermodynamically as well as quantum mechanically. The interaction energy in this paper is defined as a pair energy between a reduced and an oxidized sites. Even this simplest definition generates complicated redox behaviors because of formation of various isomers when the number metal centers increases.
一次資料へのリンクURLhttps://u-fukui.repo.nii.ac.jp/?action=repository_action_common_download&item_id=22602&item_no=1&attribute_id=22&file_no=1
連携機関・データベース国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）