Surface Properties of Air-Exposed α-Ti–Pd Alloys via XPS and Cross-Coupling Reaction

• 資料種別: 文書・図像類
• タイトル: Surface Properties of Air-Exposed α-Ti–Pd Alloys via XPS and Cross-Coupling Reaction
• 著者・編者: Kondo, Ryota; Nakamichi, Seiya; Azuma, Ryusei; Takahashi, Yuya; Obora, Yasushi; 竹下, 博之
• 著者標目: Kondo, Ryota; Nakamichi, Seiya; Azuma, Ryusei; Takahashi, Yuya; Obora, Yasushi; 竹下, 博之
• 出版事項: Japan Institute of Metals
• 出版年月日等: 2018-12-01
• 出版年（W3CDTF）: 2018-12-01
• タイトル（掲載誌）: Materials Transactions
• 巻号年月日等（掲載誌）: 59 12
• 掲載巻: 59
• 掲載号: 12
• 掲載ページ: 1911-1914
• ISSN（掲載誌）: ISSN : 13459678
• 本文の言語コード: eng
• 件名標目: Ti–Pd alloy; Pd catalyst; cross-coupling reaction; 平成27年度関西大学若手研究者育成経費; 関西大学; Kansai University
• 対象利用者: 一般
• 一般注記: To identify the reasons why Ti–Pd alloys for hydrogen storage materials show good hydrogenation properties, X-ray photoelectron spectroscopy and the Suzuki–Miyaura cross-coupling reaction were used to investigate a small amount of Pd added Ti–Pd alloys. Pd in or on Ti oxide films is in a valence state of 0 (Pd0). Catalytic activity was shown by Pd0 in the Suzuki–Miyaura cross-coupling reaction. Therefore, the enhanced hydrogenation properties of Ti–Pd alloys for hydrogen storage materials is due to Pd0's catalytic activity in dissociating hydrogen molecules. In addition, the potential catalytic activity of Ti–Pd alloys was shown to be based on a Pd catalyst.; This research was financially supported by the Japan Science and Technology Agency's Matching PlannerProgram, the Kansai University Fund for Supporting Young Scholars (2015) and JSPS KAKENHI Grant Number 17K14837.
• オンライン閲覧公開範囲: 限定公開
• 著作権情報: (C) The Japan Institute of Metals and Materials (https://doi.org/10.2320/matertrans.M2018240)
• 掲載誌（NCID）: AA1151294X; https://ci.nii.ac.jp/ncid/AA1151294X
• 連携機関・データベース: 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）; https://irdb.nii.ac.jp
• 提供元機関・データベース: 関西大学 : 関西大学学術リポジトリ