Surface Properties of Air-Exposed α-Ti–Pd Alloys via XPS and Cross-Coupling Reaction

Material type: その他

Author: Kondo, Ryotaほか

Publisher: Japan Institute of Metals

Publication date: 2018-12-01

Material Format: Digital

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Note (General)：: 出版タイプ： VoRTo identify the reasons why Ti–Pd alloys for hydrogen storage materials show good hydrogenation properties, X-ray photoelectron spectroscopy...

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Material Type: その他
Title: Surface Properties of Air-Exposed α-Ti–Pd Alloys via XPS and Cross-Coupling Reaction
Author/Editor: Kondo, Ryota
Nakamichi, Seiya
Azuma, Ryusei
Takahashi, Yuya
Obora, Yasushi
竹下, 博之
Author Heading: Kondo, Ryota
Nakamichi, Seiya
Azuma, Ryusei
Takahashi, Yuya
Obora, Yasushi
Publication, Distribution, etc.: Japan Institute of Metals
Publication Date: 2018-12-01
Publication Date (W3CDTF): 2018
Periodical title: Materials Transactions
No. or year of volume/issue: 59 12
Volume: 59
Issue: 12
Pages: 1911-1914
ISSN (Periodical Title): ISSN : 13459678
Subject Heading: Ti–Pd alloy
Pd catalyst
cross-coupling reaction
平成27年度関西大学若手研究者育成経費
関西大学
Kansai University
Target Audience: 一般
Note (General): 出版タイプ： VoR
To identify the reasons why Ti–Pd alloys for hydrogen storage materials show good hydrogenation properties, X-ray photoelectron spectroscopy and the Suzuki–Miyaura cross-coupling reaction were used to investigate a small amount of Pd added Ti–Pd alloys. Pd in or on Ti oxide films is in a valence state of 0 (Pd0). Catalytic activity was shown by Pd0 in the Suzuki–Miyaura cross-coupling reaction. Therefore, the enhanced hydrogenation properties of Ti–Pd alloys for hydrogen storage materials is due to Pd0's catalytic activity in dissociating hydrogen molecules. In addition, the potential catalytic activity of Ti–Pd alloys was shown to be based on a Pd catalyst.
This research was financially supported by the Japan Science and Technology Agency's Matching PlannerProgram, the Kansai University Fund for Supporting Young Scholars (2015) and JSPS KAKENHI Grant Number 17K14837.
Access Restrictions: インターネット公開
Periodical Title (NCID): AA1151294X
https://ci.nii.ac.jp/ncid/AA1151294X
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 関西大学 : 関西大学学術リポジトリ