Structural design of coordination polymers based on manganese and chromium ions bridged by oxalate ligands

• 資料種別: 記事
• タイトル: Structural design of coordination polymers based on manganese and chromium ions bridged by oxalate ligands
• 著者・編者: Masashi Yoshitake; Kazuya Kubo; Toru Endo
• 出版事項: 日本 : The Chemical Society of Japan
• 出版年月日等: 2015-12-04
• 出版年（W3CDTF）: 2015-12-04
• タイトル（掲載誌）: Bulletin of the Chemical Society of Japan
• 巻号年月日等（掲載誌）: 89(3)
• 掲載巻: 89(3)
• ISSN（掲載誌）: 1348-0634
• ISSN-L（掲載誌）: 0009-2673
• 本文の言語コード: eng
• DOI: 10.1246/bcsj.20150373; https://doi.org/10.1246/bcsj.20150373
• 国立国会図書館永続的識別子: info:ndljp/pid/11343238; https://dl.ndl.go.jp/pid/11343238
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• コレクション（障害者向け資料：レベル1）: テキストデータ
• コレクション（個別）: 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会; https://dl.ndl.go.jp/collections/B00043
• 収集根拠: オンライン資料収集制度
• 受理日（W3CDTF）: 2019-08-27T20:45:33+09:00
• 保存日（W3CDTF）: 2019-08-27
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• 掲載誌（URI）: https://www.journal.csj.jp/toc/bcsj/89/3
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• 連携機関・データベース: 国立国会図書館 : 国立国会図書館デジタルコレクション; https://dl.ndl.go.jp

• コレクション（個別）: 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会; https://dl.ndl.go.jp/collections/B00043
• オンライン閲覧公開範囲: 国立国会図書館内限定公開
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• 請求記号: Z53-B35
• 関連情報（URI）: https://dl.ndl.go.jp/info:ndljp/pid/11343238
• 関連情報（国立国会図書館永続的識別子）: info:ndljp/pid/11343238; https://dl.ndl.go.jp/info:ndljp/pid/11343238
• 連携機関・データベース: 国立国会図書館 : 国立国会図書館雑誌記事索引; https://ndlsearch.ndl.go.jp
• 書誌ID（NDLBibID）: 027165363; http://id.ndl.go.jp/bib/027165363
• 整理区分コード: 632

• 要約等: Coordination polymers based on oxalate-bridged {[Mn^IICr^III(oxalate)₃]⁻}_∞ complexes of (DAT-2H²⁺)(DCH[18]crown-6)₂[Mn^II(CH₃OH)Cr^III(oxalate)₃]⁻₂(CH₃OH)₃ and (DABCO-H⁺)₂(DABCO-2H²⁺)[Mn^II(CH₃OH)(Cl⁻)Cr^III(oxalate)₃]²⁻₂(CH₃OH), where DAT, DABCO, and DCH[18]crown-6 denote 2,5-diaminotoluene, 1,4-diazabicyclo[2.2.2]octane, and <i>cis</i>-<i>syn</i>-<i>cis</i>-dicyclohexano[18]crown-6, respectively, were synthesized. The crystal structure of the former complex was composed of [Mn^II(Λ)(CH₃OH)Cr^III(Λ)(oxalate)₃]⁻ units, whereas that of the latter crystal was composed of [Mn^II(Λ)(CH₃OH)(Cl⁻)Cr^III(Δ)(oxalate)₃]²⁻ units. The large flexible supramolecular cation in the former provided the two-dimensional structure of [Mn^II(Λ)(CH₃OH)Cr^III(Λ)(oxalate)₃]⁻, although the two-dimensional honeycomb structure of the {[Mn^II(Δ)Cr^III(Λ)(oxalate)₃]⁻}_∞ and {[Mn^II(Λ)Cr^III(Δ)(oxalate)₃]⁻}_∞ networks are often observed for the oxalate complexes. The round-shaped DABCO molecule in the latter induced a one-dimensional chain structure of [Mn^II(Λ)(CH₃OH)Cr^III(Δ)(oxalate)₃]⁻. The former crystal showed a magnetic field dependence of magnetization typical for a spin-canting system.
• DOI: 10.1246/bcsj.20150373
• オンライン閲覧公開範囲: インターネット公開
• 連携機関・データベース: 科学技術振興機構 : J-STAGE; http://www.jstage.jst.go.jp

• 要約等: Coordination polymers based on oxalate-bridged {[Mn^IICr^III(oxalate)₃]⁻}_∞ complexes of (DAT-2H²⁺)(DCH[18]crown-6)₂[Mn^II(CH₃OH)Cr^III(oxalate)₃]⁻₂(CH₃OH)₃ and (DABCO-H⁺)₂(DABCO-2H²⁺)[Mn^II(CH₃OH)(Cl⁻)Cr^III(oxalate)₃]²⁻₂(CH₃OH), where DAT, DABCO, and DCH[18]crown-6 denote 2,5-diaminotoluene, 1,4-diazabicyclo[2.2.2]octane, and <i>cis</i>-<i>syn</i>-<i>cis</i>-dicyclohexano[18]crown-6, respectively, were synthesized. The crystal structure of the former complex was composed of [Mn^II(Λ)(CH₃OH)Cr^III(Λ)(oxalate)₃]⁻ units, whereas that of the latter crystal was composed of [Mn^II(Λ)(CH₃OH)(Cl⁻)Cr^III(Δ)(oxalate)₃]²⁻ units. The large flexible supramolecular cation in the former provided the two-dimensional structure of [Mn^II(Λ)(CH₃OH)Cr^III(Λ)(oxalate)₃]⁻, although the two-dimensional honeycomb structure of the {[Mn^II(Δ)Cr^III(Λ)(oxalate)₃]⁻}_∞ and {[Mn^II(Λ)Cr^III(Δ)(oxalate)₃]⁻}_∞ networks are often observed for the oxalate complexes. The round-shaped DABCO molecule in the latter induced a one-dimensional chain structure of [Mn^II(Λ)(CH₃OH)Cr^III(Δ)(oxalate)₃]⁻. The former crystal showed a magnetic field dependence of magnetization typical for a spin-canting system.
• DOI: 10.1246/bcsj.20150373; https://doi.org/10.1246/bcsj.20150373
• オンライン閲覧公開範囲: インターネット公開
• 関連情報: CCDC 1437933: Experimental Crystal Structure Determination; https://cir.nii.ac.jp/crid/1880865118112336000; CCDC 1438005: Experimental Crystal Structure Determination; https://cir.nii.ac.jp/crid/1881428067921491200
• 関連情報（URI）: http://id.ndl.go.jp/bib/027165363; https://ndlsearch.ndl.go.jp/books/R000000004-I027165363; https://dl.ndl.go.jp/pid/11343238; http://id.ndl.go.jp/digimeta/11343238; https://academic.oup.com/bcsj/article-pdf/89/3/354/56278769/bcsj.20150373.pdf
• 参照: Creation of a Tetranuclear MnIII2MnII2 Metalloring Structure Supported by a Penicillamine-Derived Schiff-Base Ligand; https://cir.nii.ac.jp/crid/1360579813137298304; Solvent dependence of crystal structure and dielectric relaxation in ferromagnetic [MnCr(oxalate)₃]⁻ salt; https://cir.nii.ac.jp/crid/1360861707390741376; Stable Ferromagnetic Crystal of Two‐Dimensional Manganese‐Chromium Oxalate with Supramolecular Cation; https://cir.nii.ac.jp/crid/1361975839509826816
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The Series [Z^II(bpy)₃][ClO₄][M^IICr^III(ox)₃] (Z^II = Ru, Fe, Co, and Ni; M^II = Mn, Fe, Co, Ni, Cu, and Zn; ox = Oxalate Dianion); https://cir.nii.ac.jp/crid/1360292620549633280; Increasing the Ordering Temperatures in Oxalate-Based 3D Chiral Magnets: the Series [Ir(ppy)₂(bpy)][M^IIM^III(ox)₃]·0.5H₂O (M^IIM^III = MnCr, FeCr, CoCr, NiCr, ZnCr, MnFe, FeFe); bpy = 2,2‘-Bipyridine; ppy = 2-Phenylpyridine; ox = Oxalate Dianion); https://cir.nii.ac.jp/crid/1360292620690585856; A 1D coordination polymer of copper(II) with three different bridging anions: synthesis, crystal structure and magnetic behaviour; https://cir.nii.ac.jp/crid/1360292620968419840; Synthesis, Structure, and Magnetic Properties of the Oxalate-Based Bimetallic Ferromagnetic Chain {[K(18-crown-6)][Mn(H₂O)₂Cr(ox)₃]}_∞ (18-crown-6 = C₁₂H₂₄O₆, ox = C₂O₄²^-); https://cir.nii.ac.jp/crid/1360292621037797504; Structure and NLO Properties of Layered Bimetallic Oxalato-Bridged Ferromagnetic Networks Containing Stilbazolium-Shaped Chromophores; https://cir.nii.ac.jp/crid/1360292621387725440; Ferrimagnetic Mixed-Valency and Mixed-Metal Tris(oxalato)iron(III) Compounds: Synthesis, Structure, and Magnetism; https://cir.nii.ac.jp/crid/1360292621486918400; Hydroxyl Group Recognition by Hydrogen-Bonding Donor and Acceptor Sites Embedded in a Layered Metal–Organic Framework; https://cir.nii.ac.jp/crid/1360565166611668736; Syntheses, Crystal Structures, and Magnetic Properties of the Oxalato-Bridged Mixed-Valence Complexes [Fe^II(bpm)₃]₂[Fe^III₂(ox)₅]·8H₂O and Fe^II(bpm)₃Na(H₂O)₂Fe(ox)₃·4H₂O (bpm = 2,2‘-Bipyrimidine); https://cir.nii.ac.jp/crid/1360574096344308480; (3-Fluoro-4-methoxyanilinium)+([18]Crown-6) Supramolecular Cation Salt of Ferromagnetic [MnIICrIII(oxalate)3]−; https://cir.nii.ac.jp/crid/1360846644041875328; Chiral, Three-Dimensional Supramolecular Compounds: Homo- and Bimetallic Oxalate- and 1,2-Dithiooxalate-Bridged Networks. 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Hydrothermal Synthesis, Crystal Structures, Magnetic Properties, and Theoretical Study of [M₂(μ-pymca)₃]OH·H₂O (M = Fe^II, Co^II); https://cir.nii.ac.jp/crid/1362262944325331072; A Molecular Metal Ferromagnet from the Organic Donor Bis(ethylenedithio)tetraselenafulvalene and Bimetallic Oxalate Complexes; https://cir.nii.ac.jp/crid/1362544419112443392; π-Donor BETS Based Bifunctional Superconductor with Polymeric Dicyanamidomanganate(II) Anion Layer: κ-(BETS)₂Mn[N(CN)₂]₃; https://cir.nii.ac.jp/crid/1362544419831763840; Hybrid Organic−Inorganic Conductor with a Magnetic Chain Anion: κ-BETS₂[Fe^III(C₂O₄)Cl₂] [BETS = Bis(ethylenedithio)tetraselenafulvalene]; https://cir.nii.ac.jp/crid/1362544420301495296; Single Chain Magnets Based on the Oxalate Ligand; https://cir.nii.ac.jp/crid/1362544420476430208; Design of a homonuclear ferromagnetic chain: structures and magnetic properties of oxalato-bridged copper(II) complexes with one-dimensional structures; https://cir.nii.ac.jp/crid/1362825893919662976; Enantioselective Synthesis of Optically Active Polymeric Homo- and Bimetallic Oxalate-Bridged Networks [M₂(ox)₃]<i>_n</i>; https://cir.nii.ac.jp/crid/1362825894080009088; Incommensurate Nature of the Multilayered Molecular Ferromagnetic Metals Based on Bis(ethylenedithio)tetrathiafulvalene and Bimetallic Oxalate Complexes; https://cir.nii.ac.jp/crid/1362825895620527872; A rare 3D lanthanide metal–organic framework with the rutile topology: Synthesis, structure and properties; https://cir.nii.ac.jp/crid/1362825896297928448; Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound; https://cir.nii.ac.jp/crid/1363107369594254720; Hybrid Molecular Materials Based upon Magnetic Polyoxometalates and Organic π-Electron Donors: Syntheses, Structures, and Properties of Bis(ethylenedithio)tetrathiafulvalene Radical Salts with Monosubstituted Keggin Polyoxoanions; https://cir.nii.ac.jp/crid/1363107369795347328; Electrical Conducting Bis(Oxalato)platinate Complex with Direct Connection of Cu^II Ions; https://cir.nii.ac.jp/crid/1363107370427564416; Synthesis, Crystal Structure, and Properties of Multicomponent Bis(ethylenedithio)tetrathiafulvalene Charge-Transfer Salts of the [Mo₃S₇Br₆]^2- Cluster; https://cir.nii.ac.jp/crid/1363107370776338432; Synthesis, Structure, and Magnetic Ordering of Layered (2-D) V-Based Tris(oxalato)metalates; https://cir.nii.ac.jp/crid/1363388843300577664; Co(C₂O₄)(HO(CH₂)₃OH): An Antiferromagnetic Neutral Zigzag Chain Compound Showing Long-Range Ordering of Spin Canting; https://cir.nii.ac.jp/crid/1363388843500182528; Weak Ferromagnetism in Chiral 3-Dimensional Oxalato-Bridged Cobalt(II) Compounds. 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Syntheses and magnetic properties of mixed-metal assemblies {NBu4[MCr(ox)3]}x (NBu4+ = tetra(n-butyl)ammonium ion; ox2- = oxalate ion; M = Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+); https://cir.nii.ac.jp/crid/1363951794395459584; Ferroelectricity and polarity control in solid-state flip-flop supramolecular rotators; https://cir.nii.ac.jp/crid/1363951795191435904; Oxalate-Based Soluble 2D Magnets: The Series [K(18-crown-6)]₃[M^II₃(H₂O)₄{M^III(ox)₃}₃] (M^III = Cr, Fe; M^II = Mn, Fe, Ni, Co, Cu; ox = C₂O₄²⁻; 18-crown-6 = C₁₂H₂₄O₆); https://cir.nii.ac.jp/crid/1363951795547049600; Syntheses, Crystal Structures, and Magnetic Properties of One-Dimensional Oxalato-Bridged Co(II), Ni(II), and Cu(II) Complexes with <i>n-</i>Aminopyridine (<i>n</i> = 2−4) as Terminal Ligand; https://cir.nii.ac.jp/crid/1363951796255140352; Oxalate-Bridged Bimetallic Complexes {NH(prol)₃}[MCr(ox)₃] (M = Mn^II, Fe^II, Co^II; NH(prol)₃⁺ = Tri(3-hydroxypropyl)ammonium) Exhibiting Coexistent Ferromagnetism and Proton Conduction; https://cir.nii.ac.jp/crid/1364233269182811136; Conjugated Ligands Modulated Sandwich Structures and Luminescence Properties of Lanthanide Metal–Organic Frameworks; https://cir.nii.ac.jp/crid/1364233269551522944; 単結晶構造解析ソフトウェア（Ｙａｄｏｋａｒｉ‐ＸＧ ２００９）の公開; https://cir.nii.ac.jp/crid/1390001204087874432
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
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• 書誌ID（NDLBibID）: 027165363; http://id.ndl.go.jp/bib/027165363; 11343238; http://id.ndl.go.jp/bib/11343238
• NII論文ID: 130005137575