Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol

• 資料種別: 記事
• タイトル: Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol
• 著者標目: Ken-ichi Takao; Shu Sakamoto; Marianne Touati; Yusuke Kusakawa; Kin-ichi Tadano
• 出版年月日等: 2012-11-08
• 出版年（W3CDTF）: 2012-11-08
• タイトル（掲載誌）: Molecules
• 巻号年月日等（掲載誌）: 17 11
• 掲載巻: 17
• 掲載号: 11
• 掲載ページ: 13330-13344
• 掲載年月日（W3CDTF）: 2012-11-08
• 出版事項（掲載誌）: MDPI AG
• 件名標目: Sulfonamides; camphorsultam; Hydrolysis; Claisen rearrangement; Molecular Conformation; Organic chemistry; Stereoisomerism; quaternary stereocenter; Acetates; Claisen rearrangement; chiral auxiliary; camphorsultam; quaternary stereocenter; total synthesis; Article; QD241-441; Phenols; chiral auxiliary; total synthesis; Oxidation-Reduction
• 対象利用者: 一般
• 標準番号（その他）: PMID : 23138536
• DOI: 10.3390/molecules171113330; https://doi.org/10.3390/molecules171113330
• 作成日（W3CDTF）: 2012-11-08
• オンライン閲覧公開範囲: インターネット公開
• 著作権情報: https://creativecommons.org/licenses/by/3.0/
• 関連情報（URI）: https://www.mdpi.com/1420-3049/17/11/13330/pdf
• 参照: Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A; https://cir.nii.ac.jp/crid/1360004232525395456; Asymmetric Synthesis of Cyclopentene Compounds Containing All-Carbon Quaternary Stereocenters by (3 + 2) Cycloaddition and Its Application in the Formal Synthesis of (<i>R</i>)-(−)-Puraquinonic Acid; https://cir.nii.ac.jp/crid/1360580229812124800; Synthetic Studies of Polycyclic Polyprenylated Acylphloroglucinols: Asymmetric Construction of a Cyclohexanone Moiety; https://cir.nii.ac.jp/crid/1360588380133614720; The Stereoselective Construction of All-Carbon Quaternary Stereocenters by Allylations and Its Application to Synthetic Studies of Natural Products; https://cir.nii.ac.jp/crid/1390849376464967680
• 連携機関・データベース: 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• 提供元機関・データベース: Crossref; https://www.crossref.org

• 要約等: <jats:p>An asymmetric Claisen rearrangement using Oppolzer’s camphorsultam was developed. Under thermal conditions, a geraniol-derived substrate under...