Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol

• Material Type: 記事
• Title: Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol
• Author Heading: Ken-ichi Takao; Shu Sakamoto; Marianne Touati; Yusuke Kusakawa; Kin-ichi Tadano
• Publication Date: 2012-11-08
• Publication Date (W3CDTF): 2012-11-08
• Periodical title: Molecules
• No. or year of volume/issue: 17 11
• Volume: 17
• Issue: 11
• Pages: 13330-13344
• Publication date of volume/issue (W3CDTF): 2012-11-08
• Publication (Periodical Title): MDPI AG
• Subject Heading: Sulfonamides; camphorsultam; Hydrolysis; Claisen rearrangement; Molecular Conformation; Organic chemistry; Stereoisomerism; quaternary stereocenter; Acetates; Claisen rearrangement; chiral auxiliary; camphorsultam; quaternary stereocenter; total synthesis; Article; QD241-441; Phenols; chiral auxiliary; total synthesis; Oxidation-Reduction
• Target Audience: 一般
• Standard No. (Other): PMID : 23138536
• DOI: 10.3390/molecules171113330
• Date Created (W3CDTF): 2012-11-08
• Access Restrictions: インターネット公開
• Rights (production): https://creativecommons.org/licenses/by/3.0/
• Related Material (URI): https://www.mdpi.com/1420-3049/17/11/13330/pdf
• Is Referenced By: Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A; https://cir.nii.ac.jp/crid/1360004232525395456; Asymmetric Synthesis of Cyclopentene Compounds Containing All-Carbon Quaternary Stereocenters by (3 + 2) Cycloaddition and Its Application in the Formal Synthesis of (<i>R</i>)-(−)-Puraquinonic Acid; https://cir.nii.ac.jp/crid/1360580229812124800; The Stereoselective Construction of All-Carbon Quaternary Stereocenters by Allylations and Its Application to Synthetic Studies of Natural Products; https://cir.nii.ac.jp/crid/1390849376464967680
• Data Provider (Database): 国立情報学研究所 : CiNii Research; https://cir.nii.ac.jp/
• Original Data Provider (Database): Crossref; https://www.crossref.org

• Summary, etc.: <jats:p>An asymmetric Claisen rearrangement using Oppolzer’s camphorsultam was developed. Under thermal conditions, a geraniol-derived substrate under...