不飽和炭化水素類の環境調和型分子変換反応の開発

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Author: 大宮, 寛久ほか

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Publication date: 2015-06-11

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Note (General)：: 金沢大学医薬保健研究域薬学系 / 北海道大学研究者は、不飽和化合物であるアルキン誘導体を出発原料とした銅(I)触媒反応の開発を検討した。その結果、9-BBN型アルキルボラン/アルキノエート/スズアルコキシドの銅(I)触媒高選択的三成分カップリング反応を用いたアルケニルスズ化合物の合成法を開発した。さ...

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https://kaken.nii.ac.jp/search/?qm=40508876

https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620072/

https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620072/25620072seika/

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Material Type: 文書・図像類
Title: 不飽和炭化水素類の環境調和型分子変換反応の開発
Author/Editor: 大宮, 寛久
Ohmiya, Hirohisa
Author Heading: 大宮, 寛久
Ohmiya, Hirohisa
Publication Date: 2015-06-11
Publication Date (W3CDTF): 2015-06-11
Alternative Title: Development of Environmentally-friendly Molecular Transformation of Unsaturated Compounds
Periodical title: 平成26(2014)年度科学研究費補助金挑戦的萌芽研究研究成果報告書 = 2014 Fiscal Year Final Research Report
No. or year of volume/issue: 2013-04-01 - 2015-03-31
Volume: 2013-04-01 - 2015-03-31
Pages: 4p.-
Text Language Code: jpn
Subject Heading: 不飽和化合物
銅触媒
カルボスタニル化
水素化
Target Audience: 一般
Note (General): 金沢大学医薬保健研究域薬学系 / 北海道大学
研究者は、不飽和化合物であるアルキン誘導体を出発原料とした銅(I)触媒反応の開発を検討した。その結果、9-BBN型アルキルボラン/アルキノエート/スズアルコキシドの銅(I)触媒高選択的三成分カップリング反応を用いたアルケニルスズ化合物の合成法を開発した。さらに、分子状水素を用いた内部アルキンの銅/N-ヘテロ環カルベン錯体触媒シン選択的水素化反応を見出した。
The researcher examined copper(I)-catalyzed reactions using alkyne substrates. As a result, a copper-catalyzed three-component coupling with alkylboranes, alkynoates, and tributyltin methoxide was developed as a versatile route to trisubstituted alkenylstannanes. Additionally, syn-selective hydrogenation of internal alkynes with molecular hydrogen under the influence of a catalytic amount of copper complexes was achieved.
DOI: 10.24517/00051696
Access Restrictions: 限定公開
Related Material: https://kaken.nii.ac.jp/search/?qm=40508876
https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620072/
https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-25620072/25620072seika/
Data Provider (Database): 国立情報学研究所 : 学術機関リポジトリデータベース（IRDB）（機関リポジトリ）
https://irdb.nii.ac.jp
Original Data Provider (Database): 金沢大学 : 金沢大学学術情報リポジトリKURA