Effects of Silanization Conditions on Flexural Properties of Sic Fiber-Reinforced Resin

• Material Type: 博士論文
• Title: Effects of Silanization Conditions on Flexural Properties of Sic Fiber-Reinforced Resin
• Author/Editor: Taka, Norimasa
• Publication, Distribution, etc.: 新潟大学
• Publication Date: 2019-03-25
• Publication Date (W3CDTF): 2019-03-25
• Alternative Title: Effects of Silanization Conditions on Flexural Properties of Sic Fiber-Reinforced Resin; シランカップリング処理の条件がSiC繊維強化型レジンの曲げ特性に及ぼす影響
• Degree grantor/type: 新潟大学
• Date Granted: 2019-03-25
• Date Granted (W3CDTF): 2019-03-25
• Dissertation Number: 甲第4590号
• Degree Type: 博士（歯学）
• Conferring No. (Dissertation): 甲第4590号
• Text Language Code: eng
• Subject Heading: SiC fiber; Fiber-reinforced resin; Silanization; Flexural properties
• Note (General): Objective: The aim of this study was to evaluate the effects of silanization conditions on the mechanical properties of the SiC fiber-reinforced resin.Materials and Methods: A mixture of urethane dimethacrylate and Triethylene Glycol Dimethacrylate (TEGDMA), with camphorquinone and 2-(N,N-dimethylamino)ethyl methacrylate as the visible-light initiator, was prepared as a matrix resin. The SiC fiber containing 10 mass% oxygen was silanized by two methods, using experimental silane coupling agents containing 0.5, 1.0, and 2.0 mass% 3-(Methacryloyloxy) Propyl Trimethoxy Silane (γ-MPTS). The silanization methods were the drying method, which enabled silanization at atmospheric conditions for two weeks, and the heating method, which enabled silanization at 100°C for 30 min. After silanization, SiC fibers were analyzed by Fourier Transform Infrared (FTIR) spectroscopy. Mechanical properties of experimental SiC fiber-reinforced resin were measured by the three-point bending test according to ISO 4049:2009, and the fracture surface of SiC fiber-reinforced resin was observed using an Electron Probe Micro Analyzer (EPMA).Results: The FTIR absorbance peaks at 815 cm-1 attributed to the Si-O-CH_3 groups of the γ-MPTS and 1087 cm^-1 attributed to the Si-O-Si siloxane bonding were observed on the SiC fiber silanized with 1.0 mass% γ-MPTS by the drying method. Moreover, EPMA observation showed that these SiC fibers were covered with the matrix resin. Thus, these SiC fibers could adhere chemically to the matrix resin. The flexural strength and modulus of the fiberreinforced resin containing the SiC fiber silanized with 1.0 mass% γ-MPTS using the drying method were 238.7 ± 41.1 MPa and 6.0 ± 1.1 GPa, respectively. In contrast, those of the SiC fiber-reinforced resin containing the SiC fibers silanized by the heating method was not improved.Conclusion: The reinforced resin containing the SiC fiber silanized with 1.0 mass% γ-MPTS by the drying method showed mechanical properties superior to those of the other SiC fiber-reinforced resin.; 学位の種類: 博士（歯学）. 報告番号: 甲第4590号. 学位記番号: 新大院博（歯）甲第439号. 学位授与年月日: 平成31年3月25日; Dentistry. 2018, 8(11), 524; 新大院博（歯）甲第439号; 元資料の権利情報 : 【○!C】 2018 Norimasa T, et al.; 開始ページ : 1; 終了ページ : 6
• DOI: info:doi/10.4172/2161-1122.1000524; https://doi.org/info:doi/10.4172/2161-1122.1000524
• Persistent ID (NDL): info:ndljp/pid/11337468; https://dl.ndl.go.jp/pid/11337468
• Collection: 障害者向け資料
• Collection (Materials For Handicapped People:1): テキストデータ
• Collection (particular): 国立国会図書館デジタルコレクション > デジタル化資料 > 博士論文; https://dl.ndl.go.jp/collections/A00014
• Acquisition Basis: 博士論文（自動収集）
• Date Accepted (W3CDTF): 2019-08-03T12:23:27+09:00
• Date Created (W3CDTF): 2019-09-10
• Format (IMT): application/pdf
• Access Restrictions: 国立国会図書館内限定公開
• Service for the Digitized Contents Transmission Service: 図書館・個人送信対象外
• Availability of remote photoduplication service: 可
• Periodical Title (URI): http://hdl.handle.net/10191/51344
• Data Provider (Database): 国立国会図書館 : 国立国会図書館デジタルコレクション; https://dl.ndl.go.jp