Fluoroalkylation methods for synthesizing versatile building blocks
Available in National Diet Library
Find on the publisher's website
NDL Digital Collections
Digital data available
Check on the publisher's website
DOI[10.1246/bcsj.20190080]to the data of the same series
Holdings of Libraries in Japan
This page shows libraries in Japan other than the National Diet Library that hold the material.
Please contact your local library for information on how to use materials or whether it is possible to request materials from the holding libraries.
other
CiNii Research
Search ServiceDigitalYou can check the holdings of institutions and databases with which CiNii Research is linked at the site of CiNii Research.
Bibliographic Record
You can check the details of this material, its authority (keywords that refer to materials on the same subject, author's name, etc.), etc.
- Material Type
- 記事
- Author/Editor
- Shintaro KawamuraMikiko Sodeoka
- Publication, Distribution, etc.
- Publication Date
- 2019-06-26
- Publication Date (W3CDTF)
- 2019-06-26
- Periodical title
- Bulletin of the Chemical Society of Japan
- No. or year of volume/issue
- 92(7)
- Volume
- 92(7)
- ISSN (Periodical Title)
- 1348-0634
- ISSN-L (Periodical Title)
- 0009-2673
- Text Language Code
- eng
- DOI
- 10.1246/bcsj.20190080
- Persistent ID (NDL)
- info:ndljp/pid/11537202
- Collection
- Collection (Materials For Handicapped People:1)
- Collection (particular)
- 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- Acquisition Basis
- オンライン資料収集制度
- Date Accepted (W3CDTF)
- 2020-08-26T10:30:39+09:00
- Date Captured (W3CDTF)
- 2019-07-20
- Format (IMT)
- application/pdf
- Access Restrictions
- 国立国会図書館内限定公開
- Service for the Digitized Contents Transmission Service
- 図書館・個人送信対象外
- Availability of remote photoduplication service
- 可
- Periodical Title (URI)
- Periodical Title (Persistent ID (NDL))
- info:ndljp/pid/11537197
- Data Provider (Database)
- 国立国会図書館 : 国立国会図書館デジタルコレクション
- Summary, etc.
- コレクション : 国立国会図書館デジタルコレクション > 電子書籍・電子雑誌 > 学術機関 > 学協会
- DOI
- 10.1246/bcsj.20190080
- Related Material (URI)
- Is Referenced By
- Ligand‐Controlled Copper‐Catalyzed Halo‐Halodifluoromethylation of Alkenes and Alkynes Using Fluorinated Carboxylic AnhydridesAtomic Nanoarchitectonics for CatalysisMethods with Nanoarchitectonics for Small Molecules and Nanostructures to Regulate Living CellsCatalytic Difluoromethylation of Alkenes with Difluoroacetic Anhydride: Reactivity of Fluorinated Diacyl Peroxides and RadicalsLife science nanoarchitectonics at interfacesNanoarchitectonics on living cellsEnantioselective Radical Type, 1,2-Oxytrifluoromethylation of Olefins Catalyzed by Chiral Vanadyl Complexes: Importance of Noncovalent Interactions1,2-Bis-perfluoroalkylations of alkenes and alkynes with perfluorocarboxylic anhydrides<i>via</i>the formation of perfluoroalkylcopper intermediatesFullerene Nanoarchitectonics with Shape-ShiftingEvolution and Future of Hetero‐ and Hydro‐Trifluoromethylations of Unsaturated C−C BondsUnderstanding and Controlling Fluorinated Diacyl Peroxides and Fluoroalkyl Radicals in Alkene FluoroalkylationsAsymmetric Cross Couplings of Trifluoromethyl Radical to Vinylarenes with <i>N</i>‐Hydroxy‐oxazinediones and Subsequent Aerobic Oxidative Homocoupling of 2‐Naphthols Catalysed by Chiral Vanadyl ComplexesFluorofunctionalizations of C–C Multiple Bonds and C–H BondsDynamism of supramolecular DNA/RNA nanoarchitectonics : from interlocked structures to molecular machines
- References
- Combining Photoredox‐Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α‐Trifluoromethylated Ketones from Aromatic AlkenesPerfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl SourceDifluoro‐ and Trifluoromethylation of Electron‐Deficient Alkenes in an Electrochemical MicroreactorDiastereoselective Synthesis of CF<sub>3</sub>- and CF<sub>2</sub>H-Substituted Spiroethers from Aryl-Fused Cycloalkenylalkanols by Photoredox CatalysisThe Direct C–H Difluoromethylation of Heteroarenes Based on the Photolysis of Hypervalent Iodine(III) Reagents That Contain Difluoroacetoxy LigandsORGANOALUMINUM-INDUCED ADDITION OF POLYHALOMETHANE TO OLEFINSNew Efficient Palladium-Catalyzed Perfluoroalkylation of Carbon-Carbon Multiple Bonds with <i>F</i>-Alkyl Iodides. An Expedient Route to <i>F</i>-Alkylated Alkyl and Alkenyl Iodides<i>N</i>-Heterocycle-Forming Amino/Carboperfluoroalkylations of Aminoalkenes by Using Perfluoro Acid Anhydrides: Mechanistic Studies and Applications Directed Toward Perfluoroalkylated Compound LibrariesPhotoredox-catalyzed oxytrifluoromethylation of allenes: stereoselective synthesis of 2-trifluoromethylated allyl acetatesMetal-free alkene oxy- and amino-perfluoroalkylations <i>via</i> carbocation formation by using perfluoro acid anhydrides: unique reactivity between styrenes and perfluoro diacyl peroxidesCyclization Cascades via<i>N</i>-Amidyl Radicals toward Highly Functionalized Heterocyclic ScaffoldsTelmisartan<sup>18</sup>F-Labeling of Arenes and Heteroarenes for Applications in Positron Emission TomographyCopper(i)-catalyzed diastereoselective hydroxytrifluoromethylation of dienes accelerated by phosphine ligandsRuthenium-Catalyzed Vinylsilane Synthesis and Cross-Coupling as a Selective Approach to Alkenes: Benzyldimethylsilyl as a Robust Vinylmetal FunctionalityEnantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper‐Catalyzed Asymmetric Oxytrifluoromethylation of AlkenesReaction of organolithium reagents with allylic alcoholsRegio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium TriflatesAsymmetric additions of organolithium reagents to allylic alcoholsElectrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagentsCopper-Catalyzed Three-Component Cyanotrifluoromethylation/Azidotrifluoromethylation and Carbocyclization of 1,6-EnynesManganese-Catalyzed Aerobic Oxytrifluoromethylation of Styrene Derivatives Using CF<sub>3</sub>SO<sub>2</sub>Na as the Trifluoromethyl SourceInstantaneous Deprotection of Tosylamides and Esters with SmI<sub>2</sub>/Amine/WaterMagnesium‐Catalyzed Electrophilic Trifluoromethylation: Facile Access to All‐Carbon Quaternary Centers in OxindolesLight-induced BiOBr nanosheets accelerated highly regioselective intermolecular trifluoromethylation/arylation of alkenes to synthesize CF3-containing aza-heterocyclesControlled Trifluoromethylation Reactions of Alkynes through Visible‐Light Photoredox CatalysisThe xanthate route to organofluorine derivatives. A brief accountCopper-catalyzed stereoselective oxytrifluoromethylation of propargyl amides for the construction of oxazolinesCopper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagentConversion of chiral oxiranes into chiral aziridines with retention of configuration by way of chiral episulfonium ions and reactions of the aziridines with Grignard reagentsSynthesis of α-CF<sub>3</sub>-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF<sub>3</sub>-Transfer ReagentsGeneration of CF<sub>3</sub>‐Containing Epoxides and Aziridines by Visible‐Light‐Driven Trifluoromethylation of Allylic Alcohols and AminesVisible-light-induced photocatalytic oxytrifluoromethylation of N-allylamides for the synthesis of CF<sub>3</sub>-containing oxazolines and benzoxazinesControlled Fluoroalkylation Reactions by Visible-Light Photoredox CatalysisAlkene Trifluoromethylation Coupled with CC Bond Formation: Construction of Trifluoromethylated Carbocycles and HeterocyclesFine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple BondsConvenient Preparation of (Chlorodifluoromethyl)arenes. Useful Precursors for Aryldifluoromethyl Radicals<i>Anti</i>-Diastereoselective Synthesis of CF<sub>3</sub>-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysisα-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migrationPalladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature6‐Trifluoromethyl‐Phenanthridines through Radical Trifluoromethylation of IsonitrilesAmino- and azidotrifluoromethylation of alkenesTrifluoromethylation of aromatic compounds with bis(trifluoroacetyl) peroxideCopper‐Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF<sub>3</sub>‐Substituted Azirines and AziridinesCopper‐Catalyzed Intramolecular Carbotrifluoromethylation of Alkynes for the Construction of Trifluoromethylated HeterocyclesPhotoredox-Induced Three-Component Oxy-, Amino-, and Carbotrifluoromethylation of EnecarbamatesThe fluorous effect in biomolecular applicationsIsolation and Reactivity of Trifluoromethyl Iodonium SaltsThe Palladium-Catalyzed Trifluoromethylation of Aryl ChloridesFree-Radical Additions Involving Fluorine Compounds. VII.<sup>1</sup> The Addition of Perhaloalkanes to Vinyl Ethyl Ether and Vinyl 2,2,2-Trifluoroethyl EtherIodine(III) Reagents in Radical ChemistryThe effect of lithocholic acid on proliferation and apoptosis during the early stages of colon carcinogenesis: differential effect on apoptosis in the presence of a colon carcinogenSodium dithionite initiated addition of CF2Br2, CF3I and (CF3)2CFI to allylaromaticsCopper-catalyzed tandem trifluoromethylation/cyclization of internal alkynesCatalytic Diverse Radical-Mediated 1,2-Cyanofunctionalization of Unactivated Alkenes via Synergistic Remote Cyano Migration and Protected StrategiesPerfluoroalkyl Cobaloximes: Preparation Using Hypervalent Iodine Reagents, Molecular Structures, Thermal and Photochemical ReactivityCopper‐Catalyzed Trifluoromethylation and Bicyclizations of 1,7‐Enynes Leading to Fused PolycyclesThe copper-catalyzed synthesis of β-trifluoromethylated acrylonitriles and trifluoromethyl-substituted 2H-azirinesPhosphine-catalyzed remote α-C–H bond activation of alcohols or amines triggered by the radical trifluoromethylation of alkenes: reaction development and mechanistic insightsA Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and BromidesThree‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox CatalystsPhotoredox‐Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated AlkenesHighly Regio- and Diastereoselective Synthesis of CF<sub>3</sub>-Substituted Lactones <i>via</i> Photoredox-Catalyzed Carbolactonization of Alkenoic AcidsMetal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysisPerfluoroalkylquinones. Synthesis Using Bis(perfluoroalkanoyl) Peroxides, Absorption Bands, and SolubilitySynthesis of CF3-containing oxazolines via trifluoromethylation of allylamides with Togni reagent in the presence of alkali metal iodidesNext Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic AreasConcise synthesis of oxindole derivatives bearing a 3-trifluoroethyl group: Copper-catalyzed trifluoromethylation of acryloanilidesAminotrifluoromethylation of Olefins via Cyclic Amine Formation: Mechanistic Study and Application to Synthesis of Trifluoromethylated PyrrolidinesSynthesis of trifluoromethylated 3,4-dihydroquinolin-2(1H)-ones via a photo-induced radical cyclization of benzene-tethered 1,7-enynes with Togni reagentTrifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional GroupsPhotocatalytic Radical Trifluoromethylation/Cyclization Cascade: Synthesis of CF<sub>3</sub>-Containing Pyrazolines and IsoxazolinesVisible-light-induced perfluoroalkylation/arylmigration/desulfonylation cascades of conjugated tosyl amidesCopper‐Catalyzed Trifluoromethylation of AllylsilanesSequential asymmetric hydrogenation and photoredox chemistry with a single catalystFluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug DesignSynthesis of Perfluorinated Isoquinolinediones through Visible-Light-Induced Cyclization of AlkenesCopper‐Catalyzed One‐Pot Trifluoromethylation/Aryl Migration/Carbonyl Formation with Homopropargylic AlcoholsTrifluoromethylation‐Initiated Remote Cross‐Coupling of Carbonyl Compounds to Form Carbon–Heteroatom/Carbon BondsFluorinated PeroxidesAromatic trifluoromethylation catalytic in copperUnusual reactions resulting from the addition on olefins of trifluoromethyl radicals obtained from dissociative electron transfer between electrochemically generated aromatic anion radicals and trifluoromethyl bromideAchiral Pyridine Ligand‐Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with AlcoholsConvenient Synthesis of N-Tosyl-2-(difluoromethyl)aziridine and Its Application to the Preparation of Difluoromethyl-β-tryptamine AnaloguesOxytrifluoromethylation of multiple bonds using copper catalyst under mild conditionsGood Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic SynthesisFluorine in Pharmaceutical and Medicinal ChemistrySynthesis of α-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysisChemo- and Regioselective Distal Heteroaryl <i>ipso</i>-Migration: A General Protocol for Heteroarylation of Unactivated AlkenesSynthesis of novel perfluoroalkyl-containing polyethersSimple Direct Synthesis of [Bis(trifluoroacetoxy)iodo]arenesSunlight decatungstate photoinduced trifluoromethylations of (hetero)aromatics and electron-poor olefinsOxy-trifluoromethylation of alkenes and its application to the synthesis of β-trifluoromethylstyrene derivativesVisible-Light Induced Trifluoromethylation of <i>N</i>-Arylcinnamamides for the Synthesis of CF<sub>3</sub>-Containing 3,4-Disubstituted Dihydroquinolinones and 1-Azaspiro[4.5]decanesCopper‐Catalyzed Cyclic Oxytrifluoromethylation of 2,3‐Allenoic Acids to Trifluoromethylated ButenolidesA new strategy to construct a CC–CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliumsCopper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp<sup>2</sup>)–N Bond Formation of Conjugated Tosyl AmidesErratumCopper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF<sub>3</sub>SiMe<sub>3</sub>: Efficient C(sp<sup>3</sup>)–CF<sub>3</sub> Bond FormationCopper-catalyzed cascade cyclization of 1,5-enynes via consecutive trifluoromethylazidation/diazidation and click reaction: self-assembly of triazole fused isoindolinesCopper-Catalyzed Trifluoromethylation of Alkenes with Redox-Neutral Remote Amidation of AldehydesCopper-catalyzed endo-type trifluoromethylarylation of alkynesCopper-Catalyzed Intermolecular Cyanotrifluoromethylation of AlkenesMetal‐Free Trifluoromethylation and Arylation of Alkenes: Domino Synthesis of Oxindole DerivativesDirect Electrophilic N‐Trifluoromethylation of Azoles by a Hypervalent Iodine ReagentElectrophilic Trifluoromethylation of <i>S</i>-Hydrogen PhosphorothioatesCopper-Catalyzed Aminotrifluoromethylation of Unactivated Alkenes with (TMS)CF<sub>3</sub>: Construction of Trifluoromethylated AzaheterocyclesCopper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond ActivationOxidative Trifluoromethylation of Unactivated Olefins: An Efficient and Practical Synthesis of α‐Trifluoromethyl‐Substituted KetonesPractical and efficient synthesis of perfluoroalkyl iodides from perfluoroalkyl chlorides via modified sulfinatodehalogenationMild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagentsTrifluoromethyl nitrogen heterocycles: synthetic aspects and potential biological targetsCopper(<scp>i</scp>)-photocatalyzed trifluoromethylation of alkenesMild Electrophilic Trifluoromethylation of Carbon‐ and Sulfur‐Centered Nucleophiles by a Hypervalent Iodine(III)–CF<sub>3</sub> ReagentCopper‐Catalyzed Trifluoromethylation of Unactivated OlefinsReactions of bromotrifluoromethane and related halides. 8. Condensations with dithionite and hydroxymethanesulfinate saltsSpiroindolones, a Potent Compound Class for the Treatment of MalariaMetal-Free Direct 1,6- and 1,2-Difunctionalization Triggered by Radical Trifluoromethylation of AlkenesEfficient Copper‐Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen‐Based NucleophilesA Practical Method for Metal-Free Radical Trifluoromethylation of Styrenes with NaSO2CF3The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylationsHydrotrifluoromethylation and iodotrifluoromethylation of alkenes and alkynes using an inorganic electride as a radical generatorRational Methods for the Selection of Diverse Screening CompoundsSilver-Mediated Radical Trifluoromethylarylation of Activated Alkenes for the Synthesis of Oxindoles Bearing a CF3 GroupSimple, Stable, and Easily Accessible Well‐Defined CuCF<sub>3</sub> Aromatic Trifluoromethylating AgentsPhotoredox-Catalyzed Cascade Difluoroalkylation and Intramolecular Cyclization for Construction of Fluorinated γ-ButyrolactonesRecent progress in copper-catalyzed difunctionalization of unactivated carboncarbon multiple bondsCopper-Mediated Radical 1,2-Bis(trifluoromethylation) of Alkenes with Sodium TrifluoromethanesulfinatePerfluoroalkylation of Aryl-<i>N</i>,<i>N</i>-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl IodidesTrifluoromethylation of aromatic compounds with sodium trifluoromethanesulfinate under oxidative conditions.Perfluoroalkylations of nitrogen-containing heteroaromatic compounds with bis(perfluoroalkanoyl) peroxidesCopper‐Catalyzed Trifluoromethylation of Trisubstituted Allylic and Homoallylic AlcoholsNew Method for Trifluoromethylation of Enolate Anions and Applications to Regio-, Diastereo- and Enantioselective TrifluoromethylationMetal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF<sub>3</sub> and iodineCopper‐Catalyzed Aryltrifluoromethylation of <i>N</i>‐Phenylcinnamamides: Access to Trifluoromethylated 3,4‐Dihydroquinolin‐2(1 <i>H</i>)‐onesTrifluoromethylation of Allylsilanes under Photoredox CatalysisOperationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysisCopper-Catalyzed Cascade Transformation of Homopropargyl Azides into Trifluoromethylated Nitriles via C–C CleavageMetal‐Free Aryltrifluoromethylation of Activated AlkenesPhotocatalytic fluoroalkylation reactions of organic compoundsCopper‐Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF<sub>3</sub>‐Containing Alkyl AzidesPhosphine‐Catalyzed Remote β‐CH Functionalization of Amines Triggered by Trifluoromethylation of Alkenes: One‐Pot Synthesis of Bistrifluoromethylated Enamides and OxazolesA Free-Radical Cascade Trifluoromethylation/Cyclization of <i>N</i>-Arylmethacrylamides and Enynes with Sodium Trifluoromethanesulfinate and Iodine PentoxideIron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl groupGeneration of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenesUV light-mediated difunctionalization of alkenes with CF<sub>3</sub>SO<sub>2</sub>Na: synthesis of trifluoromethyl phenanthrene and anthrone derivativesDirect Access to α-Trifluoromethyl Enones via Efficient Copper-Catalyzed Trifluoromethylation of Meyer–Schuster RearrangementCopper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF<sub>3</sub>-Containing Allyl Azides and Thiocyanates1-Trifluoromethylisoquinolines from α-Benzylated Tosylmethyl Isocyanide Derivatives in a Modular ApproachAlkene 1,2‐Difunctionalization by Radical Alkenyl MigrationAn overview of reductive trifluoromethylation reactions using electrophilic ‘+CF3’ reagentsCopper-Mediated Cyanotrifluoromethylation of Styrenes Using the Togni ReagentTrifluoromethylation Reactions for the Synthesis of β‐TrifluoromethylaminesCopper‐Catalyzed Divergent Trifluoromethylation/Cyclization of Unactivated AlkenesIron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF<sub>3</sub>-Containing Polycyclic Benzazepine DerivativesCobalt-Catalyzed Trifluoromethylation–Peroxidation of Unactivated Alkenes with Sodium Trifluoromethanesulfinate and HydroperoxideReactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With PhenolsCopper‐Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl‐Substituted Spiro‐2<i>H</i>‐azirines from 1,6‐EnynesRapid and Selective Electrophilic Trifluoromethylation of the 4,4‐Difluoro‐4‐bora‐3a,4a‐diaza‐<i>s</i>‐indacene (BODIPY) ScaffoldLight-mediated cascade transformation of activated alkenes: BiOBr nanosheets as efficient photocatalysts for the synthesis of α-aryl-β-trifluoromethyl amidesCopper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compoundsCopper‐Catalyzed Difunctionalization of Activated Alkynes by Radical Oxidation–Tandem Cyclization/Dearomatization to Synthesize 3‐Trifluoromethyl Spiro[4.5]trienonesSynthesis and Antiviral and Fungicidal Activity Evaluation of β-Carboline, Dihydro-β-carboline, Tetrahydro-β-carboline Alkaloids, and Their DerivativesTandem Radical Fluoroalkylation–Cyclization: Synthesis of Tetrafluoro ImidazopyridinesMetal-free radical perfluoroalkylation of (hetero)arenesCu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodideRedox-ligand sustains controlled generation of CF<sub>3</sub> radicals by well-defined copper complexTTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles2-Trifluoromethylated Indoles via Radical Trifluoromethylation of IsonitrilesOne pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysisEfficient trifluoromethylation <i>via</i> the cyclopropanation of allenes and subsequent C–C bond cleavageRadical-mediated hydroxyalkylation of α,β-unsaturated estersCopper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF<sub>3</sub><sup>+</sup> ReagentRelay cooperation of K<sub>2</sub>S<sub>2</sub>O<sub>8</sub>and O<sub>2</sub>in oxytrifluoromethylation of alkenes using CF<sub>3</sub>SO<sub>2</sub>NaA Practical Source of Chlorodifluoromethyl Radicals. Convergent Routes to <i>gem</i>-Difluoroalkenes and -dienes and (2,2-Difluoroethyl)-indoles, -azaindoles, and -naphtholsElectrophilic Trifluoromethylation by Use of Hypervalent Iodine ReagentsNew Methods of Free-Radical Perfluoroalkylation of Aromatics and Alkenes. Absolute Rate Constants and Partial Rate Factors for the Homolytic Aromatic Substitution by <i>n</i>-Perfluorobutyl RadicalIntermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox CatalystsDirect Synthesis of α-Trifluoromethyl Ketone from (Hetero)arylacetylene: Design, Intermediate Trapping, and Mechanistic InvestigationsTransition‐Metal‐Free Trifluoromethylaminoxylation of AlkenesMetal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl AzaheterocyclesCatalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox systemCatalysis of Radical Reactions: A Radical Chemistry PerspectiveRecent advances in the trifluoromethylation methodology and new CF3-containing drugsCopper-catalyzed trifluoromethylation of N-arylacrylamides “on water” at room temperatureAsymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic RadicalsPower-variable trifluoromethylating agents, (trifluoromethyl)dibenzothio- and -selenophenium salt systemCopper-catalyzed intermolecular cyanotrifluoromethylation of alkenes: Convenient synthesis of CF3-containing alkyl nitrilesElectrophilic Trifluoromethylation of Primary Phosphines: Synthesis of a <i>P</i>-Bis(trifluoromethyl) Derivative of BINAPCopper‐Catalyzed Regioselective Oxytrifluoromethylation of Allenes Using a CF<sub>3</sub>‐Transfer ReagentDirect Cupration of FluoroformCopper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of HeterocyclesEnantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical ProcessDividing a complex reaction involving a hypervalent iodine reagent into three limiting mechanisms by <i>ab initio</i> molecular dynamicsNMP and O<sub>2</sub> as Radical Initiator: Trifluoromethylation of Alkenes to Tertiary β-Trifluoromethyl Alcohols at Room TemperatureMetal‐Free Direct Aryltrifluoromethylation of Allylic Alcohols with Langlois’ Reagent through Concomitant 1,2‐Aryl MigrationPhotoredox-catalysed redox-neutral trifluoromethylation of vinyl azides for the synthesis of α-trifluoromethylated ketonesGeneration of benzosultams via trifluoromethylation of 2-ethynylbenzenesulfonamide under visible lightEfficient Synthesis of the Peptide Fragment of the Natural Depsipeptides Jaspamide and ChondramideCatalytic Hydrotrifluoromethylation of Unactivated AlkenesSynthesis of Oxindoles through Silver‐Catalyzed Trifluoromethylation–, Difluoromethylation– and Arylsulfonylation–Cyclization Reaction of <i>N</i>‐Arylacrylamides<i>S</i>‐Trifluoromethylation of Thiols by Hypervalent Iodine Reagents: A Joint Experimental and Computational StudyElectrochemical hydrotrifluoromethylation of fumaronitrileThe mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO<sub>2</sub>: a computational studyFormation of DMSO and DMF radicals with minute amounts of baseP‐Stereogenic Trifluoromethyl Derivatives of Josiphos: Synthesis, Coordination Properties, and Applications in Asymmetric CatalysisExpanding the Scope of Hypervalent Iodine Reagents for Perfluoroalkylation: From Trifluoromethyl to Functionalized PerfluoroethylIodotrifluoromethylation of Alkenes and Alkynes with Sodium Trifluoromethanesulfinate and Iodine PentoxideVanadium‐Catalyzed Solvent‐Free Synthesis of Quaternary α‐Trifluoromethyl Nitriles by Electrophilic TrifluoromethylationCopper-Catalyzed Oxytrifluoromethylation of Unactivated AlkenesMetal-free cascade cyclization of alkenes toward perfluorinated oxindolesElectron‐Catalyzed Fluoroalkylation of Vinyl AzidesA Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of AlkenesNotification about the Explosive Properties of Togni’s Reagent II and One of Its PrecursorsPerfluoroalkylation of azo compoundsA new preparation of trifluoromethanesulfinate saltsEffects of B2pin2 and PCy3 on copper-catalyzed trifluoromethylation of substituted alkenes and alkynes with the Togni reagentRadical cascade reactions triggered by single electron transferSupramolecular Aggregation of Perfluoroorganyl Iodane Reagents in the Solid State and in Solution<i>syn</i>-Fluoro- and -Oxy-trifluoromethylation of ArylacetylenesSynthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3<i>H</i>-1λ<sup>3</sup>,2-benziodaoxol-3-oneCircumventing Intrinsic Metal Reactivity: Radical Generation with Redox‐Active LigandsVersatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of AlkenesOxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as a Nucleophilic CF<sub>3</sub> SourceCopper-catalyzed tandem trifluoromethylation–cyclization of olefinic carbonyls: synthesis of trifluoromethylated 2,3-dihydrofurans and 3,4-dihydropyransPower-variable electrophilic trifluoromethylating agents. S-, Se-, and Te-(trifluoromethyl)dibenzothio-, -seleno-, and -tellurophenium salt systemTrifluoromethylation of Allylsilanes under Copper CatalysisDevelopment and Challenges in the Copper-Catalyzed Trifluoromethylation of AlkenesA convenient synthesis of ethyl 3,3,3,-trifluoropropanoate and its 2-bromo derivativeEnantioselective CH Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated AlkeneEnantioselective α-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C CF3 and C C bondsElectrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF<sub>3</sub>-Transfer Reagents to Alkenes and AlkynesElectrochemical trifluoromethylation of acrylonitrile and crotonitrile. Preparation of 2,3-bis(2,2,2-trifluoroethyl)succinonitrile and 3,4-dicyano-2,5-bis(trifluoromethyl)-n-hexaneTfNHNHBoc as a Trifluoromethylating Agent for Vicinal Difunctionalization of Terminal AlkenesFacile perfluoroalkylation of uracils and uridines at the C-5 positionElectrochemical trifluoromethylation of 3-sulpholene. Synthesis of meso- and DL-3,4-bis(trifluoromethyl) sulpholanesCoreactant Strategy for the Photoredox Catalytic Generation of Trifluoromethyl Radicals under Low-Energy PhotoirradiationSilver‐Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF<sub>3</sub>SiMe<sub>3</sub>Oxidative trifluoromethylation and fluoroolefination of unactivated olefinsMetal-Free Direct Trifluoromethylation of Activated Alkenes with Langlois’ Reagent Leading to CF<sub>3</sub>-Containing OxindolesReactivity of an electrophilic hypervalent iodine trifluoromethylation reagent with hydrogen phosphates—A mechanistic studyProduct Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni ReagentPhotoinduced Diastereoselective Addition of Perfluoroalkyl Iodides to Acrylic Acid Derivatives for the Synthesis of Fluorinated Amino AcidsVisible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migrationControl of site selectivity in trifluoromethylation of alkenes bearing a pendant indolyl group: Synthesis of CF3-containing tetrahydrocarbazolesCopper(I)-Catalyzed Intramolecular Trifluoromethylation of MethylenecyclopropanesFluorine in Medicinal Chemistry and Chemical BiologyVisible-Light-Promoted Cascade Alkene Trifluoromethylation and Dearomatization of Indole Derivatives via Intermolecular Charge TransferOrgano[2-(hydroxymethyl)phenyl]dimethylsilanes as Mild and Reproducible Agents for Rhodium-Catalyzed 1,4-Addition ReactionsDetermination of rate constants for trifluoromethyl radical addition to various alkenes via a practical methodPhotoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flowCopper-catalyzed aminotrifluoromethylation of alkenes: a facile synthesis of CF<sub>3</sub>-containing lactamsMetal-Free Photocatalytic Radical Trifluoromethylation Utilizing Methylene Blue and Visible Light IrradiationZinc‐Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation ReagentsRhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine ReagentsVisible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of PhotocatalystsVisible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinateCopper(I)-promoted trifluoromethylation of indole derivates with concomitant C–C bond formation to access fused tricyclic indolesSynthesis of trifluoroalkyl or difluoroalkyl phenanthridine derivatives <i>via</i> cascade reaction using an intramolecular cyano group as a radical acceptor under photoredox catalysisPharmacokinetics of Hoasca alkaloids in healthy humansSelective C–H trifluoromethylation of benzimidazoles through photoredox catalysisIrreversible Cysteine‐Selective Protein Labeling Employing Modular Electrophilic Tetrafluoroethylation ReagentsDirect C2-trifluoromethylation of indole derivatives catalyzed by copper acetateCatalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl aminesChlorodifluoromethyl-substituted monosaccharide derivatives—radical activation of the carbon–chlorine-bondCopper-Catalyzed C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic TrifluoromethylationRate of single electron reduction of Togni’s reagentCopper-catalyzed synthesis of trifluoromethyl-substituted isoxazolinesRecent advances in photoinduced trifluoromethylation and difluoroalkylationA Facile Synthesis of Perfluoroalkyl Vinyl Iodides and Their Palladium-Mediated Cross-Coupling Reactions<sup>1</sup>Metal-catalyzed synthesis of heterocycles bearing a trifluoromethyl groupIntermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox CatalysisCopper‐Catalyzed Trifluoromethylation‐Initiated Radical 1,2‐Aryl Migration in α,α‐Diaryl Allylic AlcoholsVisible‐Light‐Induced Trifluoromethylation of <i>N</i>‐Aryl Acrylamides: A Convenient and Effective Method To Synthesize CF<sub>3</sub>‐Containing Oxindoles Bearing a Quaternary Carbon CenterHydroxytrifluoromethylation of Alkenes Using Fluoroform-Derived CuCF<sub>3</sub>Novel 10‐I‐3 Hypervalent Iodine‐Based Compounds for Electrophilic TrifluoromethylationCopper‐Catalyzed Diastereoselective Synthesis of Trifluoromethylated TetrahydrofuransLate Stage Azidation of Complex MoleculesRecent Advances in Radical Difunctionalization of Simple AlkenesA scalable and operationally simple radical trifluoromethylationRapid Trifluoromethylation of Indole DerivativesTriethylborane-induced stereoselective radical addition of perfluoroalkyl iodides to acetylenesDual Catalysis with Copper and Rhenium for Trifluoromethylation of Propargylic Alcohols: Efficient Synthesis of α‐Trifluoromethylated EnonesCopper-catalyzed trifluoromethylazidation and rearrangement of aniline-linked 1,7-enynes: access to CF<sub>3</sub>-substituted azaspirocyclic dihydroquinolin-2-ones and furoindolinesRecent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating ReagentsCopper-Promoted Intramolecular Aminotrifluoromethylation of Alkenes with Langlois Reagent as the Trifluoromethyl SourceCopper-Catalyzed Intramolecular Trifluoromethylation of <i>N</i>-Benzylacrylamides Coupled with Dearomatization: Access to CF<sub>3</sub>-Containing 2-Azaspiro[4.5]decanesCopper‐Catalyzed Three‐Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic AcidCatalytic Friedel–Crafts Reactions of Highly Electronically Deactivated Benzylic AlcoholsDifunctionalization of Alkenes via the Visible-Light-Induced Trifluoromethylarylation/1,4-Aryl Shift/Desulfonylation Cascade ReactionsPhotoredox-Induced Three-Component Azido- and Aminotrifluoromethylation of AlkenesCopper‐Catalyzed Trifluoromethylation–Cyclization of Enynes: Highly Regioselective Construction of Trifluoromethylated Carbocycles and HeterocyclesSynthetic uses of thioesters of trifluoromethylated acids. Part 2: Reactions with alkenesRecent Progress in Visible-Light Photoredox-Catalyzed Intermolecular 1,2-Difunctionalization of Double Bonds via an ATRA-Type MechanismSolvent-mediated selective single and double ring-opening of N-tosyl-activated aziridines using benzylamineB(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-Catalyzed Allylation of Secondary Benzyl Acetates with AllylsilanesStereoselective Synthesis of α‐Trifluoromethyl Enones by Au<sup>I</sup>/Cu<sup>I</sup>‐Co‐Catalyzed Tandem 1,3‐Acyloxy Migration/Trifluoromethylation Reaction of Propargyl AcetatesGeneral Reaction Mode of Hypervalent Iodine Trifluoromethylation Reagent: A Density Functional Theory StudySynthesis of 3-trifluoromethylpyrazoles via trifluoromethylation/cyclization of α,β-alkynic hydrazones using a hypervalent iodine reagentHighly shape- and regio-selective peroxy–trifluoromethylation of styrene by metal–organic framework Cu<sub>3</sub>(<b>BTC</b>)<sub>2</sub>Visible-light induced di- and trifluoromethylation of N-benzamides with fluorinated sulfones for the synthesis of CF<sub>2</sub>H/CF<sub>3</sub>-containing isoquinolinedionesOne-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic TrifluoromethylationVisible light-induced aryltrifluoromethylation of hydroxy alkenes <i>via</i> radical trifluoromethylation-triggered aryl and heteroaryl migrationTransition Metal‐Free Trifluoromethylation of <i>N</i>‐Allylamides with Sodium Trifluoromethanesulfinate: Synthesis of Trifluoromethyl‐Containing OxazolinesOrganic base-catalysed solvent-tuned chemoselective carbotrifluoromethylation and oxytrifluoromethylation of unactivated alkenesAddition of CF<sub>3</sub> across unsaturated moieties: a powerful functionalization toolVisible‐Light Photoredox‐Catalyzed Semipinacol‐Type Rearrangement: Trifluoromethylation/Ring Expansion by a Radical–Polar MechanismCarbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and HeteroarenesFluorous Substituent‐Based Enantiomer and Diastereomer Separation: Orthogonal Use of HPLC Columns for the Synthesis of Nonproteinogenic Polyfluoro Amino Acids and PeptidesCopper-Mediated α-Trifluoromethylation of <i>N</i>-Phenylcinnamamides Coupled with Dearomatization: Access to Trifluoromethylated 1-Azaspiro[4.5]decanesPhotoredox-Catalyzed Three-Component Tandem Process: An Assembly of Complex Trifluoromethylated Phthalans and IsoindolinesCopper-catalyzed trifluoromethylation of alkenes: synthesis of trifluoromethylated benzoxazinesRadical aryl migration enables diversity-oriented synthesis of structurally diverse medium/macro- or bridged-ringsFree Radical Chemistry Enabled by Visible Light-Induced Electron TransferTrifluoromethylation by bis(trifluoroacetyl) peroxide of polymers bearing benzene ringsRadical Chlorodifluoromethylation: Providing a Motif for (Hetero)arene DiversificationReactivity and properties of bis(chlorodifluoroacetyl) peroxide generated <i>in situ</i> from chlorodifluoroacetic anhydride for chlorodifluoromethylation reactionsCopper‐Catalyzed Trifluoromethylation of Acrylamides Coupled with Indole Dearomatization: Access to Trifluoromethyl‐Substituted Spiro[indole‐3,3′‐pyrrolidine] DerivativesTransition-metal complex catalyzed polyfluoroalkylation. I. Facile addition of polyfluoroalkyl halides to carbon-carbon multiple bondsIron‐Catalyzed Trifluoromethylation of EnamideVisible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterNew hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: synthesis, structure, and reactivityApplication of Langlois’ Reagent in Trifluoromethylation ReactionsA Ritter‐Type Reaction: Direct Electrophilic Trifluoromethylation at Nitrogen Atoms Using Hypervalent Iodine ReagentsCopper-Catalyzed Cascade Cyclization of 1,7-Enynes toward Trifluoromethyl-Substituted 1′<i>H</i>-Spiro[azirine-2,4′-quinolin]-2′(3′<i>H</i>)-onesCopper‐Catalyzed Trifluoromethylation and Cyclization of Aromatic‐Sulfonyl‐Group‐Tethered Alkenes for the Construction of 1,2‐Benzothiazinane Dioxide Type CompoundsRadical-mediated hydroxytrifluoromethylation of α,β-unsaturated estersSingle Electron Transfer in Radical Ion and Radical-Mediated Organic, Materials and Polymer SynthesisCopper-Promoted Sandmeyer Trifluoromethylation ReactionRecent Developments in the Trifluoromethylation of AlkynesPhotoredox Catalyzed Intramolecular Fluoroalkylarylation of Unactivated AlkenesCopper‐Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic AlcoholsMechanistic study on a unique SN2′-type reaction of allylic alcohols with organolithium reagent accelerated by a proximal trifluoromethyl groupEffect on Blood Lipids of Very High Intakes of Fiber in Diets Low in Saturated Fat and CholesterolPhotochemical Perfluoroalkylation with Pyridine N -Oxides: Mechanistic Insights and Performance on a Kilogram ScaleConvenient preparation of difluoromethylene-functionalized compounds from chlorodifluoroacetic acidAlkyl Sulfinates: Radical Precursors Enabling Drug DiscoveryReactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl EthersA Metal‐Free Route to CF<sub>3</sub>‐Containing Oxindoles by PhI(OAc)<sub>2</sub>‐Mediated Trifluoromethylation of <i>N</i>‐Arylacrylamides with TMSCF<sub>3</sub>Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF<sub>3</sub>–containing dihydronaphthalene derivativesA general strategy for the synthesis of difluoromethyl-containing pyrazoles, pyridines and pyrimidinesPreparation of (Phenyldifluoromethyl)- and (Phenoxydifluoromethyl)-silanes by Magnesium-Promoted Carbon-Chlorine Bond ActivationElectrochemical Oxy-trifluoromethylation of Butyl Acrylate.Perfluoroalkylation of Olefins by Electrooxidation of Perfluoroalkanoic Acids: Relations between Product-Selectivity and Current Density and Structures of Olefins
- References (URI)
- Data Provider (Database)
- 国立情報学研究所 : CiNii Research
- Original Data Provider (Database)
- 雑誌記事索引データベースCrossrefCiNii ArticlesCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossrefCrossref
- Bibliographic ID (NDL)
- 11537202
- NAID
- 130007679391