記事
環状ニッケル化合物を反応中間体とする分子変換反応
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環状ニッケル化合物を反応中間体とする分子変換反応
- Material type
- 記事
- Author
- 生越 専介
- Publisher
- The Society of Synthetic Organic Chemistry, Japan
- Publication date
- 2013
- Material Format
- Digital
- Journal name
- 有合化 71 1
- Publication Page
- p.14-24
Detailed bibliographic record
Summary, etc.：
- Nickelacycles have been known as a key reaction intermediate. The β-hydrogen transfer reactions from nickelacycles allow us to synthesize acyclic orga...
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Digital
- Material Type
- 記事
- Author Heading
- Publication Date
- 2013
- Publication Date (W3CDTF)
- 2013
- Periodical title
- 有合化
- No. or year of volume/issue
- 71 1
- Volume
- 71
- Issue
- 1
- Pages
- 14-24
- Publication date of volume/issue (W3CDTF)
- 2013
- ISSN (Periodical Title)
- 00379980
- Publication (Periodical Title)
- The Society of Synthetic Organic Chemistry, Japan
- Text Language Code
- ja
- Subject Heading
- Target Audience
- 一般
- Standard No. (Other)
- COI : 1:CAS:528:DC%2BC3sXitFyqurw%3D
- DOI
- 10.5059/yukigoseikyokaishi.71.14
- Is Referenced By
- Nickel‐Catalyzed Synthesis of <i>N</i>‐Aryl‐1,2‐dihydropyridines by [2+2+2] Cycloaddition of Imines with Alkynes through T‐Shaped 14‐Electron Aza‐Nickelacycle Key IntermediatesNickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and EthyleneNickel(0)-Catalyzed [2 + 2 + 1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to γ-Lactams2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C–C Bond-Forming ReactionsAza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactionsVol. 90 Commemorative Account : Fascinating Molecules and Reactions : Award Account : The Chemical Society of Japan Award for Creative Work for 2013 : Highly Atom Economical Molecular Transformation via Hetero-Nickelacycle
- References
- Nickel-Catalyzed Intermolecular [2 + 2] Cycloaddition of Conjugated Enynes with AlkenesCatalytic Addition of Olefinic C–H Bonds to OlefinsNickel-catalyzed Reactions between Enone and Two EthylenesRecent Advances in the Synthesis of Pyridines by Transition-Metal-Catalyzed [2+2+2] CycloadditionFormation of an Aza‐nickelacycle by Reaction of an Imine and an Alkyne with Nickel(0): Oxidative Cyclization, Insertion, and Reductive EliminationNickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of α,β-Unsaturated Phenyl Esters with AlkynesNickel-Catalyzed Dehydrogenative [4 + 2] Cycloaddition of 1,3-Dienes with NitrilesTransition-Metal-Catalyzed Reactions in Heterocyclic SynthesisPalladium(0)‐Catalyzed [2σ + 2π] Cycloadditions Methylenecyclopropane to Alkenes[3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum ChlorideThe Tishchenko Reaction: A Classic and Practical Tool for Ester SynthesisVerbesserte Dimerisierung von Methylen-cyclopropan an modifizierten Nickel(0)-KatalysatorenSelective Cyclotrimerization of Enones and Alkynes by a Nickel and Aluminum Catalytic SystemRegioselective Cyclic Cotrimerization of α,β-Enones and Alkynes by a Nickel−Aluminum Catalyst SystemSynthesis of Five‐ and Six‐Membered Benzocyclic Ketones through Intramolecular Alkene Hydroacylation Catalyzed by Nickel(0)/N‐Heterocyclic CarbenesThe fascinating construction of pyridine ring systems by transition metal-catalysed [2 + 2 + 2] cycloaddition reactionsDimerization of Cyclopropyl Ketones and Crossed Reactions of Cyclopropyl Ketones with Enones as an Entry to Five-Membered Ringsα‐Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition ReactionsReaction of (η2-arylaldehyde)nickel(0) complexes with Me3SiX (X=OTf, Cl). Application to catalytic reductive homocoupling reaction of arylaldehydeNickel-Catalyzed Direct Conjugate Addition of Simple Alkenes to EnonesDirect Observation of Oxidative Cyclization of η<sup>2</sup>-Alkene and η<sup>2</sup>-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me<sub>3</sub>SiOTfReaktionen der Methylencyclopropane, VI <sup>1)</sup> Palladium(0)‐katalysierte [2σ + 2π]‐Cycloadditionen des 1‐Methylen‐2‐vinylcyclopropansCyclodimerization of Methylenecyclopropane on a Ni(0) CatalystCatalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistanceReversible Carbon−Carbon Bond Formation between 1,3-Dienes and Aldehyde or Ketone on Nickel(0)Recent Strategies for the Synthesis of Pyridine DerivativesNovel Chemoselectivity and Stereochemical Aspects of Nickel-Catalyzed [2 + 2 + 2] CycloadditionsAlMe<sub>3</sub>-Promoted Oxidative Cyclization of η<sup>2</sup>-Alkene and η<sup>2</sup>-Ketone on Nickel(0). Observation of Intermediate in Methyl Transfer ProcessA Study of the Mixed Tischtschenko ReactionNickel-Catalyzed [2 + 2 + 2] Cycloaddition of Two Enones and an AlkyneNickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complexSelective dimerization of aldehydes to esters catalyzed by zirconocene and hafnocene complexesSynthesis and Reactivity of Six‐Membered Oxa‐Nickelacycles: A Ring‐Opening Reaction of Cyclopropyl KetonesNickel-Catalyzed Selective Conversion of Two Different Aldehydes to Cross-Coupled EstersConstruction of Pyridine Rings by Metal-Mediated [2 + 2 + 2] Cycloaddition[3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient AlkylidenecyclopropanesTransition Metal Catalyzed Alkene and Alkyne HydroacylationModern Organonickel ChemistryActivation of C-H Bonds: Catalytic ReactionsNickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imineNickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehydeNickel(0)-catalyzed hydroacylation of alkynes with aldehydes to .alpha.,.beta.-enones[2+2+2] Cycloaddition Reactions Catalyzed by Transition Metal ComplexesElaboration of Conjugated Alkenes Initiated by Insertion into a Vinylic C-H BondTrimerisation von Methylencyclopropan an triorganophosphan‐modifizierten Nickel (o)‐KatalysatorenNickel(0)-Catalyzed Dimerization of Ethyl CyclopropylideneacetatesFormation of Nickeladihydropyran by Oxidative Addition of Cyclopropyl Ketone. Key Intermediate in Nickel-Catalyzed Cycloaddition触媒反応における鍵中間体としてのヘテロニッケラサイクルの研究ローダサイクル中間体を経由する新規環化反応とその応用
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- 10031148196